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As characteristics

Figure X-9 shows plots of cos 6 versus 7l for various series of liquids on Teflon (polytetrafluoroethylene) [78]. Each line extrapolates to zero at a certain 7l value, which Zisman has called the critical surface tension 7 since various series extrapolated to about the same value, he proposed that 7 was a quantity characteristic of a given solid. For Teflon, the representative 7 was taken to be about 18 and was regarded as characteristic of a surface consisting of —CF2 — groups. Figure X-9 shows plots of cos 6 versus 7l for various series of liquids on Teflon (polytetrafluoroethylene) [78]. Each line extrapolates to zero at a certain 7l value, which Zisman has called the critical surface tension 7 since various series extrapolated to about the same value, he proposed that 7 was a quantity characteristic of a given solid. For Teflon, the representative 7 was taken to be about 18 and was regarded as characteristic of a surface consisting of —CF2 — groups.
Figure Bl.25.2 shows the XPS spectra of two organoplatinum complexes which contain different amounts of chlorine. The spectrum shows the peaks of all elements expected from the compounds, the Pt 4f and 4d doublets (the 4f doublet is iimesolved due to the low energy resolution employed for broad energy range scans). Cl 2p and Cl 2s, N Is and C Is. Flowever, the C Is caimot be taken as characteristic for the complex only. All surfaces that have not been cleaned by sputtermg or oxidation in the XPS spectrometer contain carbon. The reason is that adsorbed hydrocarbons from the atmosphere give the optimum lowering of the surface free energy and hence, all surfaces are covered by hydrocarbon fragments [9]. Figure Bl.25.2 shows the XPS spectra of two organoplatinum complexes which contain different amounts of chlorine. The spectrum shows the peaks of all elements expected from the compounds, the Pt 4f and 4d doublets (the 4f doublet is iimesolved due to the low energy resolution employed for broad energy range scans). Cl 2p and Cl 2s, N Is and C Is. Flowever, the C Is caimot be taken as characteristic for the complex only. All surfaces that have not been cleaned by sputtermg or oxidation in the XPS spectrometer contain carbon. The reason is that adsorbed hydrocarbons from the atmosphere give the optimum lowering of the surface free energy and hence, all surfaces are covered by hydrocarbon fragments [9].
The dielectric constants of amino acid solutions are very high. Thek ionic dipolar structures confer special vibrational spectra (Raman, k), as well as characteristic properties (specific volumes, specific heats, electrostriction) (34). [Pg.274]

Ir Spectroscopy. Significant absorptions can be identified as characteristic of particular substitutions within families of thiophene derivatives. The most widely studied in this connection are probably the halothiophenes, where absorption bands have been characterized. This is usehil for qualitative analysis, but has also been used quantitatively in association with the standard spectmm of materials of known purity. [Pg.19]

There are many laboratory methods for testing the relative merits of one defoamer against another. It is a simple matter to measure foam height as a function of time to compare the performance of various foam surfactants and defoamers. Unfortunately, this simplicity has led to a wide variety of methods and conditions used with no standard procedure that would make the measurement of foaminess as characteristic of a solution as its surface tension or viscosity. It has been suggested that the time an average bubble remains entrapped ia the foam is such a quantity (49), but very few workers ia the defoamer iadustry have adopted this proposal. Ia practice, a wide variety of methods are used that geaerally fall iato oae of five maia categories ... [Pg.467]

In conclusion RAIRS, which affords high spectral resolution, is a very versatile nondestructive optical technique which does not depend on a vacuum environment. Vibrational spectra also serve as characteristic fingerprints for adsorbate molecules, adsorption configurations, and structures on metallic and dielectric substrates. Extension to include dielectric substrates opened new fields of application in polymer and biochemical research. [Pg.253]

Hie shortest possible. Value to be specified as characteristic of the measuring instrument... [Pg.393]

Reactions of isoxazole derivatives that take place with the cleavage of the heterocyclic nucleus are as characteristic in this series as the substitution reactions. They are due to the cleavage of the bond... [Pg.397]

The mass spectra of free carbohydrates and their glycosides, obtained by ionization upon electron impact, are limited in their usefulness for structural studies. Peaks corresponding to molecular ions are generally not observed due to extensive fragmentation to ions of low m/e (4,9,11, 24, 26). In contrast, positive ions produced by field ionization do not give fragment spectra as characteristic as do those produced by electron impact, but the molecular ion peaks are intense, often the most intense in the spectra (3). [Pg.212]

When the contact angle is close to r/2 (for example, for the system water/steel 0 0.45 r), the ratio H/ro is small, we estimate the order of magnitude of the terms in Eqs. (9.2-9.4) and conditions (9.5-9.7). Choosing the meniscus as characteristic scales of length in the longimdinal and transversal directions H and ro, respectively, we obtain... [Pg.383]

Assuming steady state in Eqs. (10.8-10.10) and (10.18-10.20), we obtain the system of equations, which determines steady regimes of the flow in the heated miero-channel. We introduce values of density p = pp.o, velocity , length = L, temperature r = Ti 0, pressure AP = Pl,o - Pg,oo and enthalpy /Jlg as characteristic scales. The dimensionless variables are defined as follows ... [Pg.408]

This chapter defines qnality as meeting consumer or customer requirements a product as such has no qnality, but it has physical properties reflected in attributes that can be perceived as qnality after consumption or use. Quality attributes can be defined as characteristics of a product or production process that are observable (by... [Pg.552]

Differentiation of ulcerative colitis and Crohn s disease is based on signs and symptoms as well as characteristic endoscopic findings including the extent, pattern, and depth of inflammation. [Pg.281]

Correia, A. M. N. G., Leitao, M. C. A., Clifford, M. N., Caffeoyl-tyrosine and Angola II as characteristic markers for Angolan Robusta coffees, Food Chem., 53(3), 309, 1995. (CA123 8347x)... [Pg.162]

Tertiary publications, as described by Sewell [52] in Guide to Drug Information, are those publications that are the furthest removed from the literature of original research. The tertiary literature is a distillation and evaluation of data and information first presented in such primary literature sources as research reports, meeting presentations, and journal articles. Being furthest removed from the primary report, the tertiary literature characteristically is the least current and the most vulnerable to misinterpretations, biases, and inaccuracies. But just as characteristic, the tertiary literature is the most accessible, easiest to use, and perhaps the most used of all information resources. Information searches generally start with a perusal of... [Pg.769]

The fact is that, on the one hand, a significant field strength, E9 is needed to provide significant current. On the other hand, once in the practical current density range between 0.1 and 10 mA/cm2, a relative insensitivity of the field to the current density is found. In fact, an inverse field of 1.3 to 1.8 nm/V is accepted in the literature as characteristic of the oxide growth, without mention of the current density used. [Pg.425]


See other pages where As characteristics is mentioned: [Pg.131]    [Pg.448]    [Pg.371]    [Pg.324]    [Pg.616]    [Pg.249]    [Pg.23]    [Pg.264]    [Pg.21]    [Pg.393]    [Pg.393]    [Pg.1178]    [Pg.18]    [Pg.32]    [Pg.1089]    [Pg.232]    [Pg.257]    [Pg.350]    [Pg.110]    [Pg.40]    [Pg.26]    [Pg.460]    [Pg.109]    [Pg.254]    [Pg.11]    [Pg.467]    [Pg.219]    [Pg.266]    [Pg.279]    [Pg.157]    [Pg.355]    [Pg.263]    [Pg.133]   
See also in sourсe #XX -- [ Pg.18 , Pg.172 ]




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