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Aromatic hydrocarbon-polar group

Aromatic hydrocarbon-polar group interaction in microemulsions, effect of aromatic compounds, 41,4 /... [Pg.354]

When pure water vapour is used as the mobile phase, the components of a mixture can be separated according to the functional groups present. For example, below 130°C, on the crystallohydrate Mg(N03)2 -bHiO (m.p. 85°C) the retention order is aliphatic saturated and unsaturated hydrocarbons < aromatic hydrocarbons < polar compounds. The elution order of ketones, ethers, esters, alcohols and acids is dependent on their polarity. The elution order of the n-alcohols is pentanoK butanoK propanoK ethanol < methanol this unexpected order probably results from hydrogen bond formation between the water of crystallization and the molecules of the compounds to be separated. [Pg.199]

The gas-barrier properties of nanostructiued polymer blends based on POSS are very much influenced by the presence of aromatic moieties, polar groups such as hydroxyl groups and the degree of cross linking. The gas-barrier properties of cross-Unked polyethylene are superior to those of a similar non cross-linked polyethylene [32], Aliphatic hydrocarbon chains provide a low gas barrier. However, the non-polar aliphatic hydrocarbon moieties are connected to the POSS backbone by polar amide bonds. Amide bonds are known to increase the gas-barrier properties of a material significantly, which leads to a significantly lower transmission of oxygen or helium in polyamides compared to polyethylene. This shows that different structural elanents can exhibit different influence on the gas-barrier properties of the POSS material. [Pg.250]

The carbonate groups are polar but separated by aromatic hydrocarbon groups. [Pg.561]

Both the chemical solubility and the electrical properties are consistent with those expected of a lightly polar polymer, whilst reactivity is consistent with that of a polymer containing hydrolysable carbonate ester linkages partially protected by aromatic hydrocarbon groupings. The influence of these factors on specific properties is amplified in subsequent sections. [Pg.563]

Silica gel, per se, is not so frequently used in LC as the reversed phases or the bonded phases, because silica separates substances largely by polar interactions with the silanol groups on the silica surface. In contrast, the reversed and bonded phases separate material largely by interactions with the dispersive components of the solute. As the dispersive character of substances, in general, vary more subtly than does their polar character, the reversed and bonded phases are usually preferred. In addition, silica has a significant solubility in many solvents, particularly aqueous solvents and, thus, silica columns can be less stable than those packed with bonded phases. The analytical procedure can be a little more complex and costly with silica gel columns as, in general, a wider variety of more expensive solvents are required. Reversed and bonded phases utilize blended solvents such as hexane/ethanol, methanol/water or acetonitrile/water mixtures as the mobile phase and, consequently, are considerably more economical. Nevertheless, silica gel has certain areas of application for which it is particularly useful and is very effective for separating polarizable substances such as the polynuclear aromatic hydrocarbons and substances... [Pg.93]

The yield increased with increasing the ratio of alumina-supported copper(II) bromide to alkoxybenzenes. The size of alkoxy group did not influence significantly the yield and the ratio of p/o. Nonpolar solvents such as benzene and hexane were better than polar solvent. Polar solvents such as chloroform and tetrahydrofiiran decreased the yield. It is suggested that these polar solvents may be strongly adsorbed on the surface of the reagent. The reaction did not proceed in ethanol to be due to the elution of copper(II) bromide from the alumina to the solution. It is known that the reaction of aromatic hydrocarbons with copper(II) halides in nonpolar solvents proceeds between aromatic hydrocarbons and solid copper(II) halides and not between hydrocarbons and dissolved copper(II) halides (ref. 6). [Pg.22]

Phthalate esters C(H (COOR)2 are well-characterised, aoderately polar liquid phases [8]. As might be expected, the polarity of the phases declines as the alkyl (R) group increases in size, while their volatility decreases. Hi volatility compared to other available liquid phases has reduced their importance in recent years. Tetraunsaturated hydrocarbons and aromatic hydrocarbons (electron-donor solutes) Iqf... [Pg.581]

Dzido, T.H., Kossowski, T.E., Matosiuk, D. (2002). Comparison of retention of aromatic hydrocarbons with polar groups in binary reversed-phase high-performance liquid chromatography systems. J. Chromatogr. A 947, 167-183. [Pg.172]

Thus, the question is whether such classes of molecules were present on the young Earth. The only witnesses capable of giving an answer to this question are meteorites (Deamer, 1988). The group of David Deamer studied Murchison material after extraction and hydropyrolysis (at 370-570 K, with reaction times of several hours or days). GC and MS analyses showed the presence of a series of organic compounds, including significant amounts of amphiphilic molecules such as octanoic (C ) and nonanoic acids (C9) as well as polar aromatic hydrocarbons. [Pg.268]

Dow Chemicals group and coworkers [276,350] synthesized similar triarylamine-fluorene copolymers 251 and 252, possessing carboxylic acid substituents, via hydrolysis of the corresponding ethyl ester polymers, prepared by Suzuki polymerization. Due to the very polar substituents, the copolymers 251 and 252 are only soluble in polar solvents such as DMF but not in aromatic hydrocarbons as toluene or xylene, which allowed simple fabrication of multilayer PLEDs by solution processes (Chart 2.65). [Pg.149]

J. Flieger, H. Szumilo, M. Tatarczak and D. Matosiuk, Effect of impregnation of silica gel with different zinc salts on the TLC behavior of aromatic hydrocarbons with polar groups. J. Planar Chromatogr.-Mod. TLC 17 (2004) 65-71. [Pg.58]

Polar interactions between molecules arise from permanent or Induced dipoles existing in the molecules and do not result from permanent charges as in the case of Ionic interactions. Examples of polar substances having permanent dipoles would be alcohols, ketones, aldehydes etc. Examples of polarizable substances would be aromatic hydrocarbons such as benzene or toluene. It is considered that, when a molecule carrying a permanent dipole comes Into close proximity to a polarizable molecule, the field from the molecule with the permanent dipole induces a dipole in the polarizable molecule and thus electrical interaction can occur. It follows that to selectively retain a polar solute, then the stationary phase must also be polar and contain, perhaps, hydroxyl groups. If the solutes to be separated are strongly polar, then perhaps a polarizable substance such as an aromatic hydrocarbon could be employed as the stationary phase. However, to maintain strong polar interactions with the stationary phase (as opposed to the mobile phase) the mobile phase must be relatively non-polar or dispersive in nature. [Pg.6]

Finally, binuclear lanthanide(III)-silver(I) shift reagents are noteworthy. These form complexes with olefins, aromatic rings, halogenated saturated hydrocarbons, and phosphines. Due to the lack of polar groups, these functionalities do not give significant LIS with common mononuclear LSR. Applications of this binuclear technique have been reviewed261 for example, the Z- and E-isomers of 2-octene can be differentiated. [Pg.318]

The incorporation of polar groups in unvulcanized polymers reduces their solubility in benzene. Thus the copolymer of acrylonitrile and butadiene (NBR), polychlorobutadiene (Neoprene), and fluorinated EP (the copolymer of ethylene and propylene) are less soluble in benzene and lubricating oils than the previously cited elastomers. Likewise, silicones and phosphazene elastomers, as well as elastomeric polyfluorocarbons, are insoluble in many oils and aromatic hydrocarbons because of their extremely low solubility parameters (silicons 7-8 H polytetrafluoroethylene 6.2 benzene 9.2 toluene 8.9 pine oil P.6). [Pg.208]

Local anesthetic activity is usually demonstrated by compounds which possess both an aromatic and an amine moiety separated by a lipophilic hydrocarbon chain and a polar group. In the clinically useful agents (Table 2) the polar group is an ester or an amide. Activity may be maintained, however, when the polar function is an etlier, lliiuelher, ketone, or tliioester. [Pg.100]


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Aromatic groups

Group polarization

Hydrocarbons polarity

Polar Hydrocarbons

Polar aromatics

Polar groups

Polarizing groups

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