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Apolar molecules

The formation of clusters of hydrogen-bonded water molecules around different sizes of apolar molecules... [Pg.179]

Inclusion Compounds Without Specific Binding Contacts Between Host and Guest Apolar Molecules as Guest Species... [Pg.108]

The Coulomb interaction is long-range, which necessitates use of special numerical methods for efficient simulation.30 When one tries to understand the glass transition in a chemically realistic model, these long-range Coulomb interactions add further numerical overhead so that the most extensive glass transition simulations of realistic models were done for apolar molecules. [Pg.9]

Phase i reactions (interconversion reactions). Type 1 reactions introduce functional groups into inert, apolar molecules or alter functional groups that are already present. In many cases, this is what first makes it possible for foreign substances to conjugate with polar molecules via phase 11 reactions (see below). Phase 1 reactions usually reduce the biological activity or toxicity of a substance ( detoxification ). However, some substances only become biologically active as a result of the interconversion reaction (see, for example, benzo[a]pyrene, p. 256) or become more toxic after interconversion than the initial substance ( toxification ). [Pg.316]

Attractive forces (sometimes also referred to as dispersion forces) between apolar molecules arising from the mutual polarizability of the interacting molecules. London forces also contribute to the interactive forces between polar molecules. See also van der Waals Forces Noncovalent Interactions... [Pg.430]

FIGURE 3.17 Micelle structure (A) (inner part = liquid paraffin-like outer polar part) (B) solubilization of apolar molecule (C) binding of counterion to the polar part (schematic). [Pg.64]

Of particular interest is the influence of the size and/or shape of the SA molecules to be resolved and the possibility of separating enantiomers of totally apolar molecules, although for chiral discrimination it seems to be advantageous if the molecule contains aromatic and/or aliphatic rings. [Pg.198]

Several additional features of the model are noteworthy. First, it is possible to build it without straining chemical bonds or causing unfavorable steric interactions. The polyamine chain is sufficiently long to reach around a cluster, but it is not so long or so bulky as to cause excessive crowding near the surface of the cluster. The spaces at this surface between the polyamine chains (Fig. 11) are likely binding sites for small apolar molecules, since such molecules can be bound at the interface or partially penetrate into the domain of the hydrocarbon sphere in response to favorable apolar interactions. In the model shown in Fig. 11, three bound p-nitrophenyl caproate molecules have also been included to illustrate possible modes of binding. An arrow points to one of these small molecules. [Pg.134]

Molecular Volume-Kow Relationships Relationships between Kow and different volume parameters have been reported. Leo et al. [41] compare correlations with Bondi and with CPK volume for two classes of apolar molecules (1) alkanes and alkylsilanes, and (2) perhalogenated alkanes and aromatic and haloaromatic compounds. Further, these authors discuss analogous correlations for alkanols and alkylphenols. [Pg.155]

FIGURE 3.3 Stereographic view of water molecules cluster alignment by a dissolved apolar molecule (large circles) from Monte Carlo computer simulation studies. Top figure shown with lines connecting water. (Reproduced from Swaminathan, S., Harrison, S.W., Beveridge, D.L., J. Am. Chem. Soc., 100, 5705 (1978). With permission from the American Chemical Society.)... [Pg.122]

A carbon dioxide molecule does have dipole bonds, but is an apolar molecule (the vectors cancel out)... [Pg.34]

Also, in the 1930 s London (9) indicated the quantum mechanical origin of dispersion forces between apolar molecules and in subsequent work extended these ideas to interaction between particles (10). It was shown that whereas the force between molecules varied inversely as the seventh power of the separation distance, that between thick flat plates varied inversely as the third power of the distance of surface separation. These ideas lead directly to the concept of a "long range van der Waals attractive force. A similar relationship was found for interaction between spheres (10). [Pg.38]

The model of a dipole in a spherical cavity can only provide qualitative insights into the behaviour of real molecules moreover, it cannot explain the effect of electrostatic interactions in the case of apolar molecules. More accurate predictions require a more detailed representation of the molecular charge distribution and of the cavity shape this is enabled by the theoretical and computational tools nowadays available. In the following, the application of these tools to anisotropic liquids will be presented. First, the theoretical background will be briefly recalled, stressing those issues which are peculiar to anisotropic fluids. Since most of the developments for liquid crystals have been worked out in the classical context, explicit reference to classical methods will be made however, translation into the quantum mechanical framework can easily be performed. Then, the main results obtained for nematics will be summarized, with some illustrative... [Pg.267]

The physical adsorption is characterized by weak intermolecular forces of the van der Waals type. The adsorbed particle must get close to the solid surface, since the van der Waals energy is proportional to the sixth power of reciprocal distance. The main feature of this interaction is its non-specificity, a considerable velocity and reversibility. An example of the physical adsorption is the adsorption of apolar molecules on an apolar surface resulting form disperse forces. Beside these forces the dipol-dipol interactions occur when molecules of the adsorbent or adsorbate can form permanent or induced dipoles (adsorption of gases or dipol liquids on apolar surfaces). [Pg.107]

It is interesting to study the structural properties of the neat hydrogen-bonded liquid without the perturbing influence of apolar molecules in mixtures. As an example in this direction the dynamics of ethanol in the isotopic mixture are investigated. Data will be presented on ethanol-d6 samples containing 1 vol% (diluted) or 50 vol% (concentrated) of protonic ethanol (88). In contrast to the apolar CCU environment, additional H bonds between the ethanol molecules and their environment can be formed representing new species with modified properties. [Pg.65]

London forces (or "dispersion forces") — are forces attracting apolar molecules due to their mutual polarizability. London forces are also components of the forces between polar molecules. The London equation approximately describes respective energy of interactions, Vi = -C/r6, where C is constant dependent on energy of ionization and polarizabilities of both molecules and r is the distance between the molecules. See also - van der Waals forces, and - Casimirforce. [Pg.410]

Figure 1-3 Crytalline Apolar Polyhedrons Forming a Large Lattice. The space within the polyhedrons may enclose apolar molecules. Source-. From I.M. Klotz, Role of Water Structure in Macromolecules, Federation Proceedings, Vol. 24, Suppl. 15, pp. S24-S33,1965. Figure 1-3 Crytalline Apolar Polyhedrons Forming a Large Lattice. The space within the polyhedrons may enclose apolar molecules. Source-. From I.M. Klotz, Role of Water Structure in Macromolecules, Federation Proceedings, Vol. 24, Suppl. 15, pp. S24-S33,1965.
Passive Transport. Transport by simple diffusion This mode of transport is available for apolar molecules. Permeation is predominantly governed by partitioning of the substrate between the lipid and water. The membrane simply acts as a permeability barrier small molecules pass more easily than large ones. The transport is explained in terms of a simple diffusion model involving three steps passage of the substrate from the exterior into the membrane, diffusion through the membrane, and passage out of the membrane. [Pg.88]


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See also in sourсe #XX -- [ Pg.28 ]

See also in sourсe #XX -- [ Pg.518 , Pg.546 , Pg.554 , Pg.555 , Pg.556 , Pg.557 , Pg.558 , Pg.559 ]




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