Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Anodic loop

The sequence of polarisation steps is shown in Figure 19.20b. The surface is first polarised anodically from the corrosion potential to -l-3(X)mV (S.C.E.) at a rate of 1-67 mV s . As soon as this potential is reached, the scanning direction is reversed and the potential is decreased at the same rate to the corrosion potential. The ratio of the maximum current in the reactivation loop, to that in the larger anodic loop, is used as a measure of the degree of sensitisation. [Pg.1044]

FC anode loop fuel cell anode loop (control)... [Pg.528]

A schematic representation of downscan polarization curves using the EPR procedure is shown in Fig. 7.65 (Ref 93). A sensitized stainless steel will result in an anodic loop with size depending on the degree of sensitization. With the specified rapid downscan rate, the passive film... [Pg.360]

CO2 separation from the anode loop is another challenge in liqttid-fed DMFC operation. Fuel and water losses are to be expected from the CO2 separator and have to be dealt with by the system. [Pg.128]

In 1990, Bushey and Jorgenson developed the first automated system that eoupled HPLC with CZE (19). This orthogonal separation teehnique used differenees in hydrophobieity in the first dimension and moleeular eharge in the seeond dimension for the analysis of peptide mixtures. The LC separation employed a gradient at 20 p.L/min volumetrie flow rate, with a eolumn of 1.0 mm ID. The effluent from the ehromatographie eolumn filled a 10 p.L loop on a eomputer-eontrolled, six-port miero valve. At fixed intervals, the loop material was flushed over the anode end of the CZE eapillary, allowing eleetrokinetie injeetions to be made into the seeond dimension from the first. [Pg.204]

It is worth emphasising too, that the position of those lines representing equilibria with the dissolved species, M, depend critically on the solubility of the ion, which is a continuous function of pH. For example, iron in moderately alkaline solution is expected to be very passive and so it is in borate solutions (in the absence of aggressive ions). However, the anodic polarization curve still shows a small active loop at low potential. [Pg.135]

Reactivation Ratio EPR Test (Fig. 19.20c) This is a simpler and more rapid method than the single or double loop tests, and depends on the fact that the value of determined during the anodic scan of a double loop test (which produces general dissolution without intergranular attack on sensitised material) is essentially the same for all AlSl Type 304 and 304L steels. [Pg.1044]

Active Loop the region of an anodic polarisation curve of a metal comprising the active region and the active-passive transition. [Pg.1363]

Nitrogen Compounds. Compounds such as NH3 and HCN do not appear to harm to MCFCs (70,79) in small amounts. However, if NOx is produced by combustion of the anode effluent in the cell burner loop, it could react irreversibly with the electrolyte in the cathode compartment to form nitrate salts. The projection by Gillis (84) for the NH3 tolerance level of MCFCs was 0.1 ppm, but Table 6-3 indicates that the level could be increased to 1 vol% (47). [Pg.156]

Figure 7.6 is the EIS of pyrite under different potential conditions in NaOH solution. The relationship between polarization resistance and potential can be further demonstrated by Fig. 7.7. It can be seen from Fig. 7.6 and Fig. 7.7 that when the anodic polarization potential is between 50 and 330 mV, all the curves appear as a single capacitive reactance loop. But when the potential is between 50 and 250 mV, the capacitive reactance loop radius increased with the... Figure 7.6 is the EIS of pyrite under different potential conditions in NaOH solution. The relationship between polarization resistance and potential can be further demonstrated by Fig. 7.7. It can be seen from Fig. 7.6 and Fig. 7.7 that when the anodic polarization potential is between 50 and 330 mV, all the curves appear as a single capacitive reactance loop. But when the potential is between 50 and 250 mV, the capacitive reactance loop radius increased with the...
Figure 7.14 illustrates that in the initial stage of polarization of the pyrite electrode in xanthate solution at about 120 mV, the radius of high value capacitive reactance loop increases with the increase of the polarization potential and reaches the maximum at 320 mV, indicating that the oxidation of xanthate increases gradually and collector film on pyrite surface becomes thicker. It increases the conduction resistance and the growth of collector film is the controlled step resulting in pyrite surface hydrophobic. When the polarization potential increases from 320 mV to 400 mV, the capacitive reactance loop radius decreases, indicating the decrease of transferring conduction resistance as can be seen in Fig. 7.15. It belongs to the step of film dissolution. Capacitive reactance loop radius decreases obviously when the potential is larger than 400 mV, at where the collector film falls off and the anodic dissolution of pyrite occurs. The controlled step is the anodic dissolution of pyrite and the surface becomes... Figure 7.14 illustrates that in the initial stage of polarization of the pyrite electrode in xanthate solution at about 120 mV, the radius of high value capacitive reactance loop increases with the increase of the polarization potential and reaches the maximum at 320 mV, indicating that the oxidation of xanthate increases gradually and collector film on pyrite surface becomes thicker. It increases the conduction resistance and the growth of collector film is the controlled step resulting in pyrite surface hydrophobic. When the polarization potential increases from 320 mV to 400 mV, the capacitive reactance loop radius decreases, indicating the decrease of transferring conduction resistance as can be seen in Fig. 7.15. It belongs to the step of film dissolution. Capacitive reactance loop radius decreases obviously when the potential is larger than 400 mV, at where the collector film falls off and the anodic dissolution of pyrite occurs. The controlled step is the anodic dissolution of pyrite and the surface becomes...
To measure the current distribution in a hydrogen PEFC, Brown et al. ° and Cleghorn et al. ° employed the printed circuit board approach using a segmented current collector, anode catalyst, and anode GDL. This approach was further refined by Bender et al. ° to improve ease of use and quality of information measured. Weiser et al. ° developed a technique utilizing a magnetic loop array embedded in the current collector plate and showed that cell compression can drastically affect the local current density. Stumper et al."° demonstrated three methods for the determination of current density distribution of a hydrogen PEFC. First, the partial membrane elec-... [Pg.508]

The electrochemical reaction rate for the anodic etching of Si in HF was very rapid. This is confirmed by the electrochemical impedance diagram of Fig. 7 that shows a real component equal to 150 cm, and is the result of the high reactivity of the transient bare —Si sites that appear under anodic current. The detailed mechanism of the transformation was investigated by FIS, which revealed quite an unusual inductive loop, which is shown in Fig. 7. Such a diagram was obtained by modeling the reaction kinetics based... [Pg.318]

The plate cell was assembled from a flat platinum anode (18.5 x 5 cm) and a Monel cathode (18.5 x 5 cm) separated by a 0.5-2 mm thick Teflon gasket of the same size with an excision of 17 x 3 cm. The electrolyte was circulated through the cell and ail open reservoir at a rate of about 50 mL min 1 using a peristaltic pump. The minimum holdup of the loop was 7 mL. The electrolysis was carried out at rt (20 25 C) and 192.9 kC mol . Concentrations of the substrate varied from 25-250 g L Current density was maintained constant (3-6mA cm-2) using a potentiostat. After electrolysis. H,0 (200 mL) and CH2CI2 (100 mL) were added. The mixture was neutralized to pH 9 with K2CO,. The organic layer was filtered over silica gel. [Pg.309]

Figure 6.20 illustrates a circuit that has been widely used. SW1 affords choice of anodic or cathodic current, SW2 initiates the experiment, and then SW1 may be used for current reversal. OA-3 is available for differentiating E with respect to t. A more advanced circuit (Fig. 6.21) incorporates an additional feedback loop and a comparator to perform cyclic chronopotentiometry with automatic switching. Operation of this circuit is perfectly analogous to the cyclic voltammetry circuit discussed in Section II.E. [Pg.189]


See other pages where Anodic loop is mentioned: [Pg.527]    [Pg.528]    [Pg.653]    [Pg.107]    [Pg.407]    [Pg.298]    [Pg.330]    [Pg.361]    [Pg.752]    [Pg.3125]    [Pg.257]    [Pg.508]    [Pg.527]    [Pg.528]    [Pg.653]    [Pg.107]    [Pg.407]    [Pg.298]    [Pg.330]    [Pg.361]    [Pg.752]    [Pg.3125]    [Pg.257]    [Pg.508]    [Pg.161]    [Pg.413]    [Pg.436]    [Pg.121]    [Pg.135]    [Pg.143]    [Pg.532]    [Pg.403]    [Pg.504]    [Pg.212]    [Pg.371]    [Pg.88]    [Pg.92]    [Pg.125]    [Pg.183]    [Pg.481]    [Pg.563]    [Pg.259]    [Pg.65]    [Pg.179]    [Pg.180]   
See also in sourсe #XX -- [ Pg.360 , Pg.361 ]




SEARCH



© 2024 chempedia.info