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Annihilation force

Fig. 2.5. Possible applications of a coupling parameter, A, in free energy calculations, (a) and (b) correspond, respectively, to simple and coupled modifications of torsional degrees of freedom, involved in the study of conformational equilibria (c) represents an intramolecular, end-to-end reaction coordinate that may be used, for instance, to model the folding of a short peptide (d) symbolizes the alteration of selected nonbonded interactions to estimate relative free energies, in the spirit of site-directed mutagenesis experiments (e) is a simple distance separating chemical species that can be employed in potential of mean force (PMF) calculations and (f) corresponds to the annihilation of selected nonbonded interactions for the estimation of e.g., free energies of solvation. In the examples (a), (b), and (e), the coupling parameter, A, is not independent of the Cartesian coordinates, x. Appropriate metric tensor correction should be considered through a relevant transformation into generalized coordinates... Fig. 2.5. Possible applications of a coupling parameter, A, in free energy calculations, (a) and (b) correspond, respectively, to simple and coupled modifications of torsional degrees of freedom, involved in the study of conformational equilibria (c) represents an intramolecular, end-to-end reaction coordinate that may be used, for instance, to model the folding of a short peptide (d) symbolizes the alteration of selected nonbonded interactions to estimate relative free energies, in the spirit of site-directed mutagenesis experiments (e) is a simple distance separating chemical species that can be employed in potential of mean force (PMF) calculations and (f) corresponds to the annihilation of selected nonbonded interactions for the estimation of e.g., free energies of solvation. In the examples (a), (b), and (e), the coupling parameter, A, is not independent of the Cartesian coordinates, x. Appropriate metric tensor correction should be considered through a relevant transformation into generalized coordinates...
Here /(R) and pflX) denote the shift and generalized momentum for the molecular vibration of the low frequency a>9 and reduced mass m, at the Rth site of the adsorbate lattice bi+(K) and K) are creation and annihilation operators for the collectivized mode of the adsorbate that is characterized by the squared frequency /2(K) = ml + d>, a,(K)/m , with O / iat(K) representing the Fourier component of the force constant function /jat(R). Shifts i//(R) for all molecules are assumed to be oriented in the same arbitrary direction specified by the unit vector e they are related to the corresponding normal coordinates, ue (K), and secondary quantization operators ... [Pg.81]

Table 7 compares free energies of hydration125 produced by the two types of solvent models that have been presented discrete molecular and continuum. The discrete molecular involved classical force field molecular dynamics (MD) and a free energy perturbation (FEP) technique whereby the solute molecule is annihilated to dummy atoms, so that absolute AGhydration are obtained the continuum were SCRF/PCM calculations, with Claverie-Pierotti Gcavilatlon and Floris-Tomasi Gvdw. The... [Pg.54]

The central axis, Shushumna, is the channel for the Quintessence— the concealed Glory, all-pervading Akasha. But do not hold too rigidly to the idea that the Shushumna is confined to the subtle equivalent of the spinal column. Sometimes in meditation, the Shushumna can appear as fine as a hair and, at other times, so wide that the entire body becomes one stream of force, a fire of highest inspiration, annihilating all limits, and growing until it fills the whole universe. [Pg.72]

The decreased work capacity of the in-farcted myocardium leads to a reduction in stroke volume (SV) and hence cardiac output (CO). The fall in blood pressure (RR) triggers reflex activation of the sympathetic system. The resultant stimulation of cardiac 3-adreno-ceptors elicits an increase in both heart rate and force of systolic contraction, which, in conjunction with an a-adren-oceptor-mediated increase in peripheral resistance, leads to a compensatory rise in blood pressure. In ATP-depleted cells in the infarct border zone, resting membrane potential declines with a concomitant increase in excitability that may be further exacerbated by activation of p-adrenoceptors. Together, both processes promote the risk of fatal ventricular arrhythmias. As a consequence of local ischemia, extracellular concentrations of H+ and K+ rise in the affected region, leading to excitation of nociceptive nerve fibers. The resultant sensation of pain, typically experienced by the patient as annihilating, reinforces sympathetic activation. [Pg.310]

The second step consists of preventing the readhesion of the just-liberated particles by annihilating the electrostatic attraction forces between the substrate (scrubbing brushes when used) and the particles or even better by obtaining a repulsion force. [Pg.197]

A periodically forced system may be considered as an open-loop control system. The intermediate and high amplitude forced responses can be used in model discrimination procedures (Bennett, 1981 Cutlip etal., 1983). Alternate choices of the forcing variable and observations of the relations and lags between various oscillating components of the response will yield information regarding intermediate steps in a reaction mechanism. Even some unstable phase plane components of the unforced system will become apparent through their role in observable effects (such as the codimension two bifurcations described above where they collide and annihilate stable, observable responses). [Pg.247]

E = V x C. This implies an interesting interpretation of the Hopf index n, since that helicity is equal to the classical expression of the difference between the numbers of right-handed and left-handed photons contained in the field Nr — Nr (defined by substituting Fourier transform functions for creation and annihilation operators in the quantum expression). In other words, n = Nr — Nr- This establishes a relation between the wave and the particle understanding of the idea of helicity, that is, between the curling of the force lines to one another and the difference between right- and left-handed photons contained in the field. [Pg.201]

Bom in early nineteenth century Homeopathy has its own concept about the etiology of a disease. It believes that a spiritual power or vital force animates the healthy organism and keeps it in a harmonious order. During illness the vital force is overwhelmed by a disease force. An artificial disease force, applied through the use of the right remedy, annihilates the original affection and restores health. Sometimes patients do not respond to well selected remedies due to their inherent conditions called miasms. The concept of miasms introduced by Hahnemann has been discussed in Chapter IV. [Pg.2]

It is now considered that this type of behaviour is caused by the selftrapping of ortho-positronium in bubbles in the low temperature gas. The bubbles are thought to form because the ortho-positronium-atom interaction at low energies is dominated by repulsive exchange forces, and this effect results in a lowering of the annihilation rate the bubble is so rarified in some cases that (q)p approaches zero. [Pg.340]

An electron-atom or electron-molecule collision system consists of particles that never annihilate and that interact each other only via Coulomb forces. [Pg.169]

Fig. 3. First successful observation of laser resonance of antiprotonic helium, now attributed to the (n, l) = (39,35) —> (38,34) transition. (Left) Observed time spectra of delayed annihilation of antiprotons with laser irradiation of various vacuum wavelengths near 597.2nm. Spikes due to forced annihilation through the resonance transitions are seen. (Upper right) Enlarged time profile of the resonance spike. (Lower right) Normalized peak count versus vacuum wavelength in the resonance region. From Morita et al. [11]... Fig. 3. First successful observation of laser resonance of antiprotonic helium, now attributed to the (n, l) = (39,35) —> (38,34) transition. (Left) Observed time spectra of delayed annihilation of antiprotons with laser irradiation of various vacuum wavelengths near 597.2nm. Spikes due to forced annihilation through the resonance transitions are seen. (Upper right) Enlarged time profile of the resonance spike. (Lower right) Normalized peak count versus vacuum wavelength in the resonance region. From Morita et al. [11]...
Once an antiproton and positron have combined, electrical confinement forces cease and the antihydrogen atom will escape, hit an electrode, and annihilate. During the early stages of the experiment no attempt will be made to trap the produced antihydrogen and the annihilation signature will be one of the most important diagnostics tools. [Pg.475]

Section IV is devoted to excitons in a disordered lattice. In the first subsection, restricted to the 2D radiant exciton, we study how the coherent emission is hampered by such disorder as thermal fluctuation, static disorder, or surface annihilation by surface-molecule photodimerization. A sharp transition is shown to take place between coherent emission at low temperature (or weak extended disorder) and incoherent emission of small excitonic coherence domains at high temperature (strong extended disorder). Whereas a mean-field theory correctly deals with the long-range forces involved in emission, these approximations are reviewed and tested on a simple model case the nondipolar triplet naphthalene exciton. The very strong disorder then makes the inclusion of aggregates in the theory compulsory. From all this study, our conclusion is that an effective-medium theory needs an effective interaction as well as an effective potential, as shown by the comparison of our theoretical results with exact numerical calculations, with very satisfactory agreement at all concentrations. Lastly, the 3D case of a dipolar exciton with disorder is discussed qualitatively. [Pg.7]


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See also in sourсe #XX -- [ Pg.76 , Pg.81 ]




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