Ammonium nitrate general

Polymer-based rocket propellants are generally referred to as composite propellants, and often identified by the elastomer used, eg, urethane propellants or carboxy- (CTPB) or hydroxy- (HTPB) terrninated polybutadiene propellants. The cross-linked polymers act as a viscoelastic matrix to provide mechanical strength, and as a fuel to react with the oxidizers present. Ammonium perchlorate and ammonium nitrate are the most common oxidizers used nitramines such as HMX or RDX may be added to react with the fuels and increase the impulse produced. Many other substances may be added including metallic fuels, plasticizers, stabilizers, catalysts, ballistic modifiers, and bonding agents. Typical components are Hsted in Table 1. 

Petrochemicals are those chemicals produced from petroleum or natural gas and can be generally divided into three groups (/) aliphatics, such as butane and butene (2) cycloaliphatics, such as cyclohexane, cyclohexane derivatives, and aromatics (eg, ben2ene, toluene, xylene, and naphthalene) and (J) inorganics, such as sulfur, ammonia, ammonium sulfate, ammonium nitrate, and nitric acid. 

Decomposition and Detonation Hazard. Ammonium nitrate is considered a very stable salt, even though ammonium salts of strong acids generally lose ammonia and become slightly acidic on storage. For ammonium nitrate, endothermic dissociation from lowering pH occurs above 169°C. 

Although ammonium nitrate does not itself bum, it is a strong oxidizer capable of supporting the combustion of numerous substances when heated. It can support and intensify a fire even when air is excluded. Fires involving ammonium nitrate also present a toxic hazard from the release of nitrogen oxides, even though the soHd itself is generally considered not to be toxic. 

Ceric ammonium nitrate, MeOH, 0°, 15 min, 82-95% yield. Dioxolanes and some THP ethers are not affected, but in general, with extended reaction times, THP ethers are cleaved. 

Explosives, General Bombs, Aircraft. Aluminized and Ammonium Nitrate Composition Explosives in Aircraft Bombs , BritQrdnBoardProc Q7Q87 BritO rdnBoardlnvestigation 1089 2038 (Nov 1951) 58) Anon, High Explo-... 

First, it is thought that the CHETAH approach generally overestimates instability risk. Indeed, if these compounds are analysed, they are all, apart from nitroaniline and ammonium nitrate, known as not being dangerous but they are all mentioned as medium risk at least once. 

TNT contains insufficient oxygen to give complete combustion of the carbon on detonation. It can, therefore, usefully be mixed with ammonium nitrate, which has an excess of oxygen. The resulting explosives, known as amatols, are more powerful and cheaper than TNT itself, but in general have a lower velocity of detonation. A proportion of 60% ammonium nitrate is perhaps the commonest of these compositions. 

Before nitrates and particularly ammonium nitrate were readily available commercially, explosives were developed based on chlorates and perchlorates. These also are still used in some countries. In general perchlorates are considered less dangerous than chlorates and therefore preferred. They are easily sensitised, so that in addition to explosives of this type based on nitroglycerine, others have been based on various organic liquids, particularly nitrobodies. History shows that chlorates and perchlorates must be regarded as temperamental substances, liable in bulk to lead to inexplicable accidents. Particularly when mixtures of chlorates and oxidising materials are allowed to become wet and then dry out, conditions can arise in which there is an appreciable sensitiveness to friction and impact. Explosives of this type have an unfortunate record of accidents. They are used, therefore, to a limited extent only, now that safer compositions are available. 

In general, improvised explosives are too complicated to prepare or too weak for steel cutting and most other sabotage tasks. However, if the problem is to get a quantity of lower velocity explosive for cratering or moving a large volume of earth or rock, a good simple one can be prepared from ammonium nitrate fertilizer. 

Prior to our original report7 on this method, acceptable and general preparative routes to a-iodocycloalkenones had not been described. Treatment of a p-substituted cycloalkenone with trimethylsilyl azide and a mixture of iodine and pyridine sequentially in dichloromethane has now been reported as a method for the preparation of p-substituted-a-iodocycloalkenones.8 The combination of iodine and pyridinium dichromate has also been reported to provide a-iodoenones from enones as well as from ethynyl carbinols.9 10 Some successes have also been achieved with enones and iodine azide (IN3)11 and iodine/ceric ammonium nitrate.12-14 The submitters first variant5 of the present procedure used carbon tetrachloride as a solvent. In this procedure this solvent has been replaced with the more benign diethyl ether. 

Ceric ammonium nitrate (hexanitratoammonium cerate, G. Frederick Smith Chemical Co.) was made up by weighing in 1.0N HNO3 and was standardized against Fe11. Solutions were generally 0.2-0.8N. 

An informal intercomparison of these two CIMS methods with a filter pack method shows generally excellent agreement between the mass spectrometric approaches and often, but not uniformly, good agreement with the filter pack method (Fehsenfeld et al., 1998). The latter was often high, which was attributed to interference from decomposition of ammonium nitrate to HNO-, + NH3 on the Teflon particle prefilter, followed by absorption of the HNO-, by the nylon filter. 

In 2000, Tanino and his co-workers developed the novel [5- -2]-cycloaddition reaction of a propargyiic cation equivalent bearing allylic silane 17 with enol silane 18 to give the corresponding cycloheptyne complexes 19 in good yields with an excellent diastereoselectivity (Scheme 3). While ceric ammonium nitrate (CAN) is generally used to... 

In addition to the general tests listed above a number of studies tests for specific ingredients have been published. These data for propellants, NC and for ammonium nitrate (AN) are summarized below ... 

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