Aluminum Surface Area

The sample consisted of a pure aluminum/pure copper couple. A cylinder of pure aluminum (99.999 wt%), provided by Alfa/Aesar, was drilled in its center and a cylinder of pure copper (99.9 wt%), provided by Goodfellow, was then introduced by force into the hole. The assembly of the two materials gave a perfectly joined interface avoiding any crevice corrosion due to surface defects. The diameters of the two cylinders were chosen to obtain an aluminum surface area to copper surface area ratio of 10 (external diameters were equal to 10 and 3.15 mm for the aluminum and copper bars, respectively). The electrode was then embedded in an epoxy resin so that a disk electrode was obtained at the extremity. Before immersion in the electrolyte, the disk electrode was mechanically polished with SiC papers up to 4,000 grade, ultrasonically cleaned with ethanol, then with distilled water. The electrolyte was a 10 MNa2SO4 solution prepared with analytical-grade chemicals in contact with an air atmosphere and at room temperature. 

Traditional adsorbents such as sihca [7631 -86-9] Si02 activated alumina [1318-23-6] AI2O2 and activated carbon [7440-44-0], C, exhibit large surface areas and micropore volumes. The surface chemical properties of these adsorbents make them potentially useful for separations by molecular class. However, the micropore size distribution is fairly broad for these materials (45). This characteristic makes them unsuitable for use in separations in which steric hindrance can potentially be exploited (see Aluminum compounds, aluminum oxide (ALUMINA) Silicon compounds, synthetic inorganic silicates). 

The large majority of activated alumina products are derived from activation of aluminum hydroxide, rehydrated alumina, or pseudoboehmite gel. Other commerical methods to produce specialty activated aluminas are roasting of aluminum chloride [7446-70-0], AIQ calcination of precursors such as ammonium alum [7784-25-0], AlH2NOgS2. Processing is tailored to optimize one or more of the product properties such as surface area, purity, pore size distribution, particle size, shape, or strength. 

Rehydration Bonded Alumina. Rehydration bonded aluminas are agglomerates of activated alumina, which derive their strength from the rehydration bonding mechanism. Because more processing steps are involved in the manufacture, they are generally more expensive than activated aluminum hydroxides. On the other hand, rehydration bonded aluminas can be produced in a wider range of particle shape, surface area, and pore size distribution. 

Hydrolysis of aluminum alkoxides is also used commercially to produce precursor gels. This approach avoids the introduction of undesirable anions or cations so that the need for extensive washing is reduced. Although gels having surface area over 800 m /g can be produced by this approach, the commercial products are mosdy pseudoboehmite powders in the 200 —300 m /g range (28). The forming processes already described are used to convert these powders into activated alumina shapes. 

Table 1 Hsts a number of common inorganic coagulants. Typical iron and aluminum coagulants are acid salts that lower the pH of the treated water by hydrolysis. Depending on initial raw water alkalinity and pH, an alkah such as lime or caustic must be added to counteract the pH depression of the primary coagulant. Iron and aluminum hydrolysis products play a significant role in the coagulation process, especially in cases in which low turbidity influent waters benefit from the presence of additional colHsion surface areas.

The predominate role of the 2inc and aluminum oxides in the ICI catalyst is to reduce the rate of sintering and loss of metallic copper surface area, which, in addition to poisoning, is one of the modes of activity loss with time for this catalyst. 

The small (10 -lm) coating particles are typically aluminum oxide [1344-28-1/, Al O. These particles can have BET surface areas of 100 to 300 m /g. The thermal and physical properties of alumina crystalline phases vary according to the starting phase (aluminum hydroxide or hydrate) and thermal treatment (see ALUMINUM COMPOUNDS, ALUMINUM OXIDE). 

Six caustic soda evaporators were anodically protected against stress corrosion in the aluminum industry in Germany in 1965 [27]. Each evaporator had an internal surface area of 2400 m. The transformer-rectifier had a capacity of 300 AJ 5 V and was operated intermittently for many years. Automatic switching on of the protection current only took place in case of need when the drop in potential reached... 

In recent years, a number of protective installations have come into operation, especially where new installations must be maintained, or where older and already damaged installations have to be saved and operating costs have to be lowered. Worldwide, equipment, tanks and evaporators in the aluminum industry and industries using caustic alkalis with a capacity of 60,000 m and a surface area of 47,000 m are being anodically protected. Equipment for electrochemical protection has been installed with a total rating of 125 kW and 12 kA. 

An alternate form of catalyst is pellets. The pellets are available in various diameters or extruded forms. The pellets can have an aluminum oxide coating with a noble metal deposited as the catalyst. The beads are placed in a tray or bed and have a depth of anywhere from 6 to 10 inches. The larger the bead (1/4 inch versus 1/8 inch) the less the pressure drop through the catalyst bed. However, the larger the bead, the less surface area is present in the same volume which translates to less destruction efficiency. Higher pressure drop translates into higher horsepower required for the oxidation system. The noble metal monoliths have a relatively low pressure drop and are typically more expensive than the pellets for the same application. 

The metal surface area at the inlet end of the catalyst bed in experiment HGR-12 was smaller than that at the outlet end this indicates that a decrease in nickel metal sites is part of the deactivation process. Sintering of the nickel is one possible mechanism, but carbon and carbide formation are suspected major causes. Loss of active Raney nickel sites could also conceivably result from diffusion of residual free aluminum from unleached catalyst and subsequent alloying with the free nickel to form an inactive material. 

Aluminum foam can be used as a porous medium in the model of a heat sink with inner heat generation (Hetsroni et al. 2006a). Open-cell metal foam has a good effective thermal conductivity and a high specific solid-fluid interfacial surface area. 

Depending on the metal foam configuration, its specific surface area varies from 500 for original foam to 10,000 m /m for compressed foam. Aluminum foam of 40 pores per inch (ppi) was studied. The structure of the porous material is presented in Fig. 2.77. 

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