Aluminum impregnation

In contrast to titanium(IV) tetrachloride, which causes polymerization of a,3-unsaturated esters, aluminum triflate88 or aluminum-impregnated montmorillonite87b are excellent promoters of silyl ketene acetal additions to a,(3-unsaturated esters (Scheme 35). Similarly, the addition of silyl ketene acetals and enol silyl ethers to nitroalkenes, followed by Nef-type work-up, affords y-keto esters (216) and y-di-ketones (218), respectively (Scheme 35).89a>89b Mechanistically, the y-diketones (218) arise from Nef-type hydrolysis of an initial nitronate ester (217).89e 89d Mukaiyama reports that SbCls-Sn(OTf)2 catalyzes diastereoselective anti additions of silyl ketene acetals, silyl thioketene acetals and enol silyl ethers to a,(3-unsaturated thioesters (219).90... 

In an effort to solve the problem of carbon fonna-tion without resorting to the use of high cost stainless steels, a sample of chrome-moly steel ws subjected to the alonizing process (aluminum impregnation). Table VII demonstrates the successful pacification of the surface ... 

Aluminum chloride hexahydrate, AIQ 6H20, manufactured from aluminum hydroxide and hydrochloric acid [7647-01-0], HQ, is used in pharmaceuticals and cosmetics as a flocculant and for impregnating textiles. Conversion of solutions of hydrated aluminum chloride with aluminum to the aluminum chlorohydroxy complexes serve as the basis of the most widely used antiperspirant ingredients (20). 

Sodium alumiaate is widely used in the preparation of alumina-based catalysts. Aluminosilicate [1327-36-2] can be prepared by impregnating siHca gel with alumiaa obtained from sodium alumiaate and aluminum sulfate (41,42). Reaction of sodium alumiaate with siHca or siHcates has produced porous crystalline alumiaosiHcates which are useful as adsorbents and catalyst support materials, ie, molecular sieves (qv) (43,44). 

Aluminizing-a process for impregnating a metal s surface with aluminum to provide protection against oxidation and corrosion. 

Rotary compressors are positive-displacement machines. Figure iO-7 shows a typical vane compressor. The operation is similar to that of a vane pump shown schematically in Figure 10-10 of Volume 1, 2nd Edition (Figure 10-9 in 1st Edition). A number of vanes, typically from 8 to 20, fit into slots in a rotating shaft. The vanes slide into and out of the slots as the shaft rotates and the volume contained between two adjacent vanes and the wall of the compressor cylinder decreases. Vanes can be cloth impregnated with a phenolic resin, bronze, or aluminum. The more vanes the compressor has, the smaller the pressure differential across the vanes. Thus, high-ratio vane compressors tend to have more vanes than low-ratio compressors. 

Vanes are usually asbestos or cotton cloth impregnated with a phenolic resin. Bronze or aluminum also may be... 

The aluminum is incorporated in a tetrahedral way into the mesoporous structure, given place to Bronsted acidic sites which are corroborated by FTIR using pyridine as probe molecule. The presence of aluminum reduces the quantity of amorphous carbon produced in the synthesis of carbon nanotubes which does not happen for mesoporous silica impregnated only with iron. It was observed a decrease in thermal stability of MWCNTs due to the presence of more metal particles which help to their earlier oxidation process. 

Mesoporous silica was prepared using sodium silicate as silica source and cetyltrimethylammoniumbromide (CTMABr) as template as elsewhere [7]. The aluminosilicates were prepared with a similar procedure by using sodium aluminate as aluminum source, which was dissolved in the surfactant solution as described before [3]. Si/Al molar ratios were of 6, 10, 30 and 80, the impregnated iron amount was 6 wt. 

Except for some exotic surface-mount technology (SMT/SMD) aluminum electrolytic capacitor types with solid electrolyte systems, in general, an aluminum electrolytic capacitor contains a wound capacitor element (the coil), impregnated with liquid electrolyte, connected to terminals, and sealed in a can (with a rubber plug at the end). The aluminum in the name,... 

Figure 3.3 XPS spectrum of an Rh/Al203 model catalyst prepared by impregnating a thin film of A120( on aluminum with a solution of RhCl, in water (courtesy of L.C.A. van den Oetelaar, Eindhoven).

Catalysts A, prepared from aluminum isopropoxide and calcined at 700° for 4 hours A—Na, contained 1 % by weight of sodium by impregnation with sodium carbonate A—H, purchased from Harshaw Chemical Company it contained 0.35% of sodium. HLSV = hourly liquid space velocity, grams of alcohol per gram of catalyst per hour. 

A—Alumina made from aluminum isopropoxide and calcined at 700° for 4 hours. B—Alumina A impregnated with sodium carbonate contained 1% Na ". 

Aluminum oxide pellets impregnated with potassium permanganate. 

Liquid membrane enrichment coupled on-line with ion chromatography. Low molecular mass carboxylic acids in low concentrations in air or soil samples can be determined by ion chromatography coupled on-line to a selective enrichment system consisting of a supported liquid membrane, impregnated with tri- -octylphosphine oxide in di-n-hexyl ether [97-98]. The system allows the determination of these carboxylic acids at micromolar levels in the presence of interfering ions such as nitrite, chloride, sulfate, iron, and aluminum. 

High yields (76-81%) of alcohols are also obtained by adding solutions of acyl chlorides in anhydrous dioxane or diethyl carbitol to a suspension of sodium borohydride in dioxane and brief heating of the mixtures on the steam bath [751], by stirring solutions of acyl chlorides in ether for 2-4 hours at room temperature with aluminum oxide (activity I) impregnated with a 50% aqueous solution of sodium borohydride (Alox) (yields 80-90%) [1014], by refluxing acyl chlorides with ether solutions of sodium trimethoxyborohydride [99], or by treatment of acyl chlorides in dichloromethane solutions with tetrabutylammonium borohydride at —78° [771]. A 94% yield of neopentyl alcohol was achieved by the reaction of trimethylacetyl chloride with tert-butylmagnesium chloride [324]. 

Ten of the resin-impregnated papers are stacked on top of each other.This stack is laid between two aluminum foils 05x15 cm) and pressed in a hydraulic press at 135 °C... 

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