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Alkane carbonylation

Reduction to Alkanes. Carbonyl groups can be reductively deoxygenated to methylene functions if both of the two steps represented by Eqs. 1 and 2 proceed to completion. With aldehydes, this process leads to the transformation of the CHO group into a CH3 group. [Pg.69]

This chapter presents a series of case studies to illustrate the VOC profiles and C02 concentration levels in a tropical climate, Singapore. These studies have been conducted over a period of five years with buildings that use different ventilation systems. Emission rates of alkanes, aromatics, alcohols, cyclic alkanes, carbonyls and other VOCs were determined, and compared with similar studies conducted in Europe and North America. The sensory and health effects of these levels of VOCs are briefly described. Cluster analyses were performed yielding plausible sources which are human or building material and building operation related. [Pg.215]

Reactions that combine C-H activation with a C-C bond-forming event are invaluable synthetic tools, allowing concise construction of carbon frameworks. Rhodium(i) catalysts have been shown to catalyze alkane carbonylation [21]. Recently, Sakakura and co-workers succeeded in subjecting methane to a catalytic acetaldehyde synthesis [22], They found that, in dense carbon dioxide, the complex [RhCl(PMe3)3] catalyzed the carbonylation of methane with 77 turnovers. [Pg.42]

Trioxan gives a protected aldehyde as product. For example, the cross-dimer from trioxan and cyclohexane gives C6HuCHO on hydrolysis. The overall process is equivalent to an alkane carbonylation. Likewise, a protected form of prolinal is formed from trioxan and pyrrolidine. [Pg.556]

Alkane carbonylation has also proved possible with RhCI(PMe3)2(CO), an endothermic process driven by light absorption (Eq. 2.39) [I2I]. [Pg.94]

Photochemical alkane carbonylation with RhCl(CO)(PMe3)2 is also possible. This seems to operate by initial photoextrusion of CO from the catalyst, oxidative addition of the alkane C—H bond, addition of CO to the metal, followed by insertion, and then reductive elimination as shown in Figure 3. Preferential reaction at the 1 ° or 2° C—H bond is found. Here the initial product does not seem to isomerize, but Norrish type II photoreactions tend to degrade the aldehyde product. Moving to longer wavelengths minimizes the Norrish degradation problem, but the selectivity of the catalytic system then falls off No more than 30 turnovers have been observed to date (e.g. equation 24)... [Pg.667]

Goldman [13b] has shown that aromatic ketones, such as Ph2CO, known to abstract H atoms from alkanes on irradiation, can give alkane carbonylation if a suitable metal carbonyl, such as IrCl(CO)2(PMe3)2 or Ru(CO)3(dmpe) (dmpe = Mc2PCH2CH2PMe2), is present to trap the resulting alkyl radical. The sequence proposed is shown in eq. 20-24. [Pg.399]

Untter irradiation, RhCI(CO)(PMe3>2 gives catalytic alkane carbonylation, in whidi the usual alkyl hydride intefmediate undergoes CO insertion, followed by reductive elimination of RCHO. Once again, terminal selectivity is seen in linear alkanes. [Pg.368]

With ketones the e ending of an alkane is replaced by one in the longest con tinuous chain containing the carbonyl group The chain is numbered in the direction that provides the lower number for this group The carbonyl carbon of a cyclic ketone is C 1 and the number does not appear m the name... [Pg.705]

Methyl ketones such as 2 butanone m Figure 17 18 are characterized by sharp singlets near 8 2 for the protons of CH3C=0 Similarly the deshieldmg effect of the carbonyl causes the protons of CH2C=0 to appear at lower field (8 2 4) fhan m a CH2 group of an alkane... [Pg.738]

Section 17 1 The substitutive lUPAC names of aldehydes and ketones are developed by identifying the longest continuous chain that contains the carbonyl group and replacing the final e of the corresponding alkane by al for aldehydes and one for ketones The chain is numbered m the direction that gives the lowest locant to the carbon of the carbonyl group... [Pg.741]

In general, peroxomonosulfates have fewer uses in organic chemistry than peroxodisulfates. However, the triple salt is used for oxidizing ketones (qv) to dioxiranes (7) (71,72), which in turn are useful oxidants in organic chemistry. Acetone in water is oxidized by triple salt to dimethyldioxirane, which in turn oxidizes alkenes to epoxides, polycycHc aromatic hydrocarbons to oxides and diones, amines to nitro compounds, sulfides to sulfoxides, phosphines to phosphine oxides, and alkanes to alcohols or carbonyl compounds. [Pg.95]

L = P(CH3)3 or CO, oxidatively add arene and alkane carbon—hydrogen bonds (181,182). Catalytic dehydrogenation of alkanes (183) and carbonylation of bensene (184) has also been observed. Iridium compounds have also been shown to catalyse hydrogenation (185) and isomerisation of unsaturated alkanes (186), hydrogen-transfer reactions, and enantioselective hydrogenation of ketones (187) and imines (188). [Pg.182]

Polyfluoroalkyl- andperfluoroalkyl-substituted CO and CN multiple bonds as dipolarophiles. Dmzo alkanes are well known to react with carbonyl compounds, usually under very mild conditions, to give oxiranes and ketones The reaction has been interpreted as a nucleophilic attack of the diazo alkane on the carbonyl group to yield diazonium betaines or 1,2,3 oxadiazol 2 ines as reaction intermediates, which generally are too unstable to be isolated Aromatic diazo compounds react readily with partially fluorinated and perfluorinated ketones to give l,3,4-oxadiazol-3-ines m high yield At 25 °C and above, the aryloxa-diazolines lose nitrogen to give epoxides [111]... [Pg.860]

The conversion of a primary or secondary nitro alkane 1 to a carbonyl compound 3 via an intermediate nitronate 2 is called the Nef reaction. Since carbonyl compounds are of great importance in organic synthesis, and nitro alkanes can on the other hand be easily prepared, the Nef reaction is an important tool in organic chemistry. [Pg.210]

Alkenes are reduced by addition of H2 in the presence of a catalyst such as platinum or palladium to yield alkanes, a process called catalytic hydrogenation. Alkenes are also oxidized by reaction with a peroxyacid to give epoxides, which can be converted into lTans-l,2-diols by acid-catalyzed epoxide hydrolysis. The corresponding cis-l,2-diols can be made directly from alkenes by hydroxylation with 0s04. Alkenes can also be cleaved to produce carbonyl compounds by reaction with ozone, followed by reduction with zinc metal. [Pg.246]

Ketones are named by replacing the terminal -e of the corresponding alkane name with -one. The parent chain is the longest one that contains the ketone group, and the numbering begins at the end nearer the carbonyl carbon. As with alkenes (Section 6.3) and alcohols (Section 17.1), the locant is placed before the parent name in older rules but before the suffix in newer IUPAC recommendations. For example ... [Pg.697]


See other pages where Alkane carbonylation is mentioned: [Pg.102]    [Pg.117]    [Pg.84]    [Pg.102]    [Pg.102]    [Pg.1042]    [Pg.168]    [Pg.102]    [Pg.664]    [Pg.826]    [Pg.839]    [Pg.399]    [Pg.416]    [Pg.102]    [Pg.102]    [Pg.117]    [Pg.84]    [Pg.102]    [Pg.102]    [Pg.1042]    [Pg.168]    [Pg.102]    [Pg.664]    [Pg.826]    [Pg.839]    [Pg.399]    [Pg.416]    [Pg.102]    [Pg.339]    [Pg.127]    [Pg.195]    [Pg.41]    [Pg.413]    [Pg.200]    [Pg.166]    [Pg.179]    [Pg.210]    [Pg.210]    [Pg.580]    [Pg.609]    [Pg.736]    [Pg.774]    [Pg.850]   
See also in sourсe #XX -- [ Pg.1230 ]




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