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Alkaloids and Amino Acids

There are very few alkaloids present in wood (75, 152), but they are, of course, found extensively in plants (143, 187, 188). There were many instances of toxic alkaloids in the ancient literature. The most infamous example was the use of coniine from poison hemlock, Conium maculatum, to kill the greatest philosopher of all, Socrates. The hemlock woods of commerce Tsuga spp.) are not related to this species, and they do not contain coniine. Nowadays, more poisoning of livestock, rather than people, occurs as a consequence of alkaloid ingestion. Keeler (93) recently reviewed the many plant toxins and their effects on livestock. Various alkaloids from Magnolia spp. have been shown (152) to possess cytotoxic and antibacterial effects. There are several toxic non-protein amino acids, but only mimosine has been extracted from wood. The effects of this compound have been reported by Keeler (93). The comparative toxicity of some non-protein amino acids has been reviewed (70, 151). [Pg.932]


Two general classes of alkaloids are distinguished in ergot amine alkaloids and amino acid alkaloids (table 5.9) (Peroutka 1996). While the amine alkaloids are selective for antagonist effects on serotonin receptors, the amino acid alkaloids are less selective and act upon other monoamine receptors. The constituents of interest for cognitive enhancement are predominantly the amine alkaloids. [Pg.193]

Occasional reports of alkaloids and amino acids have appeared with respect to species of Abies and Pinus, but the family is best known for its assortment of terpenoids. [Pg.168]

Catalytic hydrogenation of unsaturated nitrogen heterocycles plays an important role in the synthesis of nitrogen-containing natural products such as alkaloids and amino acids. [Pg.955]

One of the more important uses of sodium borohydride is the reduction of enamines, imines, and iminium salts, particularly useful in alkaloid and amino acid syntheses. Imine 98 was reduced to amine derivative 99 in... [Pg.326]

Fales and Pisano (1964) have discussed the gas chromatography of amines, alkaloids, and amino acids. Pollock and Kawauchi (1968) have resolved derivatives of serine, hydroxyproline, tyrosine, and cysteine, as well as racemic aspartic acid and tryptophan. VandenHeuvel and Horning (1964) have listed derivatives of steroids that can be separated. VandenHeuvel et al. (1960) first described the separation of bile acid methyl esters and Sjovall (1964) has extended the methods to bile acids. Gas liquid chromatography (GLC) is useful in the analysis of pesticides, herbicides, and pharmaceuticals (Burchfield and Storrs, 1962). Analysis of alkaloids, steroids, and mixtures of anesthetics and expired air are other examples of the application of this very useful technique. Beroza (1970) has discussed the use of gas chromatography for the determination of the chemical structure of organic compounds at the microgram level. [Pg.547]

Dimethylamino)ethanethiol DMAET-capped CdTe NPs were employed in the construction of aptamer-based biosensing system for proteins [109]. Highly efficient and sensitive determination of alkaloids and amino acids using CE in conjunction with sequential light-emitting diode-induced fluorescence (LEDIF) and ECL method was carried out. In the CE-LEDIF-ECL system, the ECL detector was located in the outlet of the capillary, while the LEDIF detector was positioned 12 cm from the outlet [110]. Ru(bpy)3 in MWCNTs/Nafion composite membrane was immobilized for an ECL method for reduced nicotinamide adenine dinucleotide (NADH) with a detection limit of 8.2 x 10 M [111]. [Pg.133]

Figure 19 Carbamate derivatives of cinchona alkaloids and amino acid derivatives studied as guests. Figure 19 Carbamate derivatives of cinchona alkaloids and amino acid derivatives studied as guests.
Amberlite IRC-50 3.5 1.25 Methacrylic acid-DVB. Selectivity adsorbs organic gases such as antibiotics, alkaloids, peptides, and amino acids. Use pH >5. [Pg.1112]

Organic aromatic molecules are usually sweet, bitter, a combination of these, or tasteless, probably owing to lack of water solubiUty. Most characteristic taste substances, especially salty and sweet, are nonvolatile compounds. Many different types of molecules produce the bitter taste, eg, divalent cations, alkaloids, some amino acids, and denatoirium (14,15). [Pg.11]

With the death of the bean, cellular structure is lost, allowing the mixing of water-soluble components that normally would not come into contact with each other. The complex chemistry that occurs during fermentation is not fully understood, but certain cocoa enzymes such as glycosidase, protease, and polyphenol oxidase are active. In general, proteins are hydrolyzed to smaller proteins and amino acids, complex glycosides are split, polyphenols are partially transformed, sugars are hydrolyzed, volatile acids are formed, and purine alkaloids diffuse into the bean shell. The chemical composition of both unfermented and fermented cocoa beans is compared in Table 1. [Pg.175]

Recent research deals with stereoselective 1,3-dipolar cycloadditions of nitrones for the syntheses of alkaloids and aza heterocycles asymmetric synthesis of biologically active compounds such as glycosidase inhibitors, sugar mimetics, /3-lactams, and amino acids synthesis of peptido-mimetics and peptides chemistry of spirocyclopropane heterocycles synthesis of organic materials for molecular recognition and photochemical applications. [Pg.407]

Colourless Substances e.g., alkaloids, steroids, amino acids and the like may be detected under short-wave UV-light or a long-wave UV-light. These substances may also be detected as brown/dark brown spots when exposed to I2-vapours in a closed dessicator. [Pg.423]

Alkaloids such as vinblastine and vincristine are known to bind to the microtubules of the spindle apparatus. They are active agents that influence DNA synthesis and amino acid metabolism. They are also known to reduce mitosis at metaphase. Vinblastine and vincristine also have some immunosuppressive activity. There are many applications of these alkaloids. They have been used in the treatment of Hodgkin s disease, cancers and blood disorders. Vincristine is a basis for the development of clinic agents used to treat cerebral and pulmonary disorders. Vinblastine and vincristine are well-known anficancer agents. [Pg.187]

X axis biogenetic class (A = alkaloids P = amino acids, peptides, peptides, polypeptides and proteins FA/PO = fatty acids and polyketides S = shikimates C = carbohydrates). [Pg.99]

It has been demonstrated that ILMs are suitable for qualitative and quantitative analyses of low-molecular weight compounds of biological interest, for example, carbohydrates, vitamins and amino acids [38], and glycolipids [40]. ILMs were further used for fhe direct analysis of alkaloids, anesthetics and antibiotics, separated by thin-layer chromatography (TLC) [46]. For this purpose, the ILM was spotted onto the fractions on the TLC-plates and the complete plate was measured in MALDI MS without the need for additional pretreatment of the TLC-samples. The mass deviation inherently caused by the inhomogeneous surface of fhe TLC-plafe was balanced by using the... [Pg.388]

The nitrogen In secondary compounds also appears to be readily mobile and metabolizable. When doubly-labeled nicotine ( C - N) was fed to tobacco (j. rustics), carbon was recovered In alkaloids, free amino acids, pigments, free organic acids and free sugars and nitrogen was recovered In proteins, alkaloids, free amino acids and pigments (17). [Pg.24]

Volutamides A-E (143-147), halogenated alkaloids of amino acid origin, have been isolated from the Atlantic bryozoan Amathia convoluta. Several of the volutamides deter feeding by potential predators and are toxic toward larvae of the co-occurring hydroid Eudendrium carneum, suggesting that these metabolites form the basis of an effective chemical defense. [114]. [Pg.786]

Alkaloids in the usual sense are not found, hut several genera yield tyramine derivatives and amino acids, some of which may be responsible for reports of alkaloids. Of 72 species, the following were positive in this study Aristea ecklonii, Ferraria anlherosa,... [Pg.108]

Legumes are able to fix atmospheric nitrogen via symbiotic Rhizobia in root nodules. Thus, nitrogen is easily available for secondary metabolism, and it is probably not surprising that nitrogen-containing SM (alkaloids, nonprotein amino acids [NPAAs], cyanogens, protease inhibitors, lectins) are a common theme in... [Pg.198]


See other pages where Alkaloids and Amino Acids is mentioned: [Pg.126]    [Pg.4]    [Pg.250]    [Pg.729]    [Pg.75]    [Pg.272]    [Pg.2908]    [Pg.932]    [Pg.127]    [Pg.126]    [Pg.4]    [Pg.250]    [Pg.729]    [Pg.75]    [Pg.272]    [Pg.2908]    [Pg.932]    [Pg.127]    [Pg.545]    [Pg.240]    [Pg.630]    [Pg.129]    [Pg.348]    [Pg.66]    [Pg.64]    [Pg.65]    [Pg.820]    [Pg.139]    [Pg.217]    [Pg.915]    [Pg.145]    [Pg.288]    [Pg.232]    [Pg.422]    [Pg.291]    [Pg.36]    [Pg.135]    [Pg.258]    [Pg.315]   


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