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Alcohol halogenated

Chlorine and bromine add vigorously, giving, with proper control, high yields of 1,2-dihaloethyl ethers (224). In the presence of an alcohol, halogens add as hypohaUtes, which give 2-haloacetals (225,226). With methanol and iodine this is used as a method of quantitative analysis, titrating unconsumed iodine with standard thiosulfate solution (227). [Pg.115]

Ethanol is both an inducer and substrate of CYP2E1. Indeed, CYP2E1 seems to be structurally geared to favor small volatile molecules such as ketones, aldehydes, alcohols, halogenated alkenes, and alkanes as substrates (36). Moreover, many of these same compounds, like ethanol, are inducers of the enzyme. A major mechanism by which this diverse group of compounds appears to initiate induction is by inhibiting normal enzyme degradation. [Pg.50]

Phenols aldehydes and Thiols and tertiary amines. Alcohols. Halogen derivatives Negatively substituted... [Pg.1202]

The halogen acids, of course, bear the same relation to the halogen aldehydes and the halogen alcohols (halogen hydrines) that unsubstituted acids do to the unsubstituled aldehydes and alcohols. That is, they are the direct oxidation products. [Pg.230]

Hazard Flammable, dangerous fire risk, ignites spontaneously in air. Reacts violently with water, acids, alcohols, halogens, and amines. Destructive to tissue. [Pg.1271]

Functional groups, such as cai bonyl, alcohol, halogen, and amine, yield fewer ions or none at all in a flame. In addition, the detector is insensitive toward noncombustible gases such as H2O, CO2, SO2, and NOf These properties make the flame ionization detector a most useful general detector for the analysis of most organic samples, including those that are contaminated with water and the oxides of nitrogen and sulfur. [Pg.953]

Halogen cations afford hypohalogen acids or X2 + H20, or 7V-halo compounds. The HO- is obtained from water, which must be present in sufficient amount.261 The corresponding halohydrin ethers are formed when the reaction is carried out in an alcohol. Halogens and the silver salts of carboxylic acids in CC14 give acyl hypohalites RCOOX, which are added as X+ and RCOO- to C=C bonds at low temperatures.262-265... [Pg.136]

Tri-p-anisylstibine oxide, (CH30.C6H4)3Sb0, formed by decomposing the dihalides with alkali, yields erystalhne crusts from alcohol, M.pt. 191° C., very soluble in benzene, ether or chloroform, less soluble m alcohol. Halogen acids convert it to dihalide. [Pg.207]

Acetylene, acids, alcohols, halogens, hydrazine, mercury, oxidizers, selenium, sulfur Acids, ammonia, combustible materials, fluorine, hydrocarbons, metals, organic materials, sugars... [Pg.394]

Ignites spontaneously in air ignites in CO2 ethereal solution also ignites spontaneously in air reacts explosively with water reactions with lower alcohols, halogenated hydrocarbons, ammonia, and oxidizing substances expected to be violent to explosive Ignites in air (slow oxidation) forms peroxide which explodes on friction (Davies 1961) reacts violently with water... [Pg.604]

It decomposes and detonates when combined with water. It reacts violently with lower alcohols, halogenated hydrocarbons, and oxidizing substances. Reactions with low-molecular-weight aldehydes, ketones and amides could be violent to explosive (especially upon warming or slight heating). [Pg.606]

Diethylberyllium ignites spontaneously in air, producing dense white fumes of beryllium oxide. Ether solution of this compound is also highly flammable, igniting spontaneously in air. It reacts explosively with water. Reactions with lower alcohols, halogens, halogenated hydrocarbons, ammonia, and oxidizers may proceed to explosive violence. [Pg.608]

Depending on the conductivity of the solutions the ohmic drop may vary considerably in organic solvents. Whereas in solutions of primary (waterlike) alcohols such as methanol, ethanol (EtOH) and propanol polarization curves with ohmic drop corrections can be obtained it is impossible to make similar measurements in non water-like solvents such as long chain alcohols, halogenated hydrocarbons and other aprotic solvents. [Pg.43]

Chiraldex B -TA Broad range, alkyl alcohols, halogen acid esters, amino alkanes, amino acids derivatives, halogenated cycloalkanes, certain lactones, diols, alkyl halides, furan and pyran derivatives. [Pg.445]

Lower boiling fractions from the primary distillation are also used in the production of solvents. Ethylene is used to produce ethylene dichloride, efliylene glycol, ethanol, and ethyl benzene. Propylene is used to produce isopropyl alcohol. Halogenation, hydrohalogenation, alkylation, and hydrolysis reactions are used in these conversions. [Pg.74]


See other pages where Alcohol halogenated is mentioned: [Pg.221]    [Pg.59]    [Pg.1110]    [Pg.311]    [Pg.555]    [Pg.210]    [Pg.221]    [Pg.1110]    [Pg.346]    [Pg.41]    [Pg.49]    [Pg.312]    [Pg.304]    [Pg.1110]    [Pg.257]    [Pg.261]    [Pg.1927]    [Pg.1029]    [Pg.304]    [Pg.57]    [Pg.642]    [Pg.723]    [Pg.70]    [Pg.604]    [Pg.604]    [Pg.607]    [Pg.607]    [Pg.60]   


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Acetylenic alcohols halogenation

Alcohols catalytic halogenation

Alcohols halogen-atom substituted

Alcohols halogenation

Alcohols halogenation

Alcohols, aromatic halogen derivatives

Alcohols, carbonylation halogenation

Alcohols, halogenating agents

Alkoxides Derived from Halogen Substituted Alcohols

Alkyl halides Compounds with halogen from alcohols

Alkyl halides from alcohols and triphenylphosphine-halogen adducts

Direct halogenation of alcohols

General Methods for the Direct Halogenation of Alcohols

Halogen acids, reaction with alcohols

Halogen compounds, reaction with alcoholic silver nitrate

Halogen compounds, reaction with alcoholic silver nitrate acetone

Halogenation activated alcohol displacements

Halogenation of an alcohol

Halogenation, of alcohols

Halogens DMSO oxidation of alcohols

Halogens alcohols

Halogens alcohols

Halogens, elemental alcohols

Halogens, with alcohols

Halogens, with alcohols dioxide

Mechanism, alcohol dehydration alkane halogenation

Primary alcohols reaction with halogen acids

Reaction Replacement of Halogen Atoms by Alcoholic Hydroxyl Groups

Replacement of alcoholic OH by halogen

Secondary alcohols reaction with halogen acids

Tertiary alcohols reaction with halogen acids

The interaction of an alcohol with a halogen compound under basic conditions

Triorganotin Alkoxides Derived from Halogen Substituted Alcohols

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