Active polymer waveguides applications

Acceptor species concentrations, equations, 400-401 Acentric materials biomimetic design, 454-455 synthesis approaches, 446 Ar-(2-Acetamido-4-nitrophenyl)pyrrolidene control of crystal polymorphism with assistance of auxiliary, 480-482 packing arrangements, 480,481-482/ Acetylenes, second- and third-order optical nonlinearities, 605-606 N-Acetyltyrosine, phase-matching loci for doubling, 355,356/, t Acid dimers, orientations, 454 Active polymer waveguides, applications, 111... 

All of the applications involving waveguides discussed in the previous section may be considered passive . The polymer serves some structural, protective, or guiding function but is not integral to the functioning of a device. A number of photonic device applications are available, however, where polymers may be useful as active elements. These applications require some type of nonlinear optical response when the material is irradiated with light of very high intensity, usually from a laser. 

Nonlinear Optically Active Polymers for Waveguide Application... 

In this chapter, the application of this technique to the thin film processing of electroactive polymers is discussed. The fabrication of controlled molecular assemblies of electroactive polymers provides a unique opportunity to investigate the structure-property and structure-function relationships of multilayer thin films containing electrically conductive, optically nonlinear and redox active polymers. These assemblies can also be coupled to appropriate solid supports for application in such molecular electronic devices as ultrathin electrodes and transistors, opticd waveguides and switches, and chemical and biochemical microelectronic sensors. 

Being able to produce poled polymers with stable second order nonlinearities, it is possible to construct prototype devices in which the polymer is the active component . As mentioned above major applications are foreseen in light modulation and frequency-doubled diode lasers. Despite the high nonlinearities obtained, fruitful use of these nonlinearities is only possible when an appropriate interactionlength is used, hence waveguide structures are necessary. An example is given in figure 19. 

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