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Actinides half-lives

Actinide Half-Lives as Standards for Nuclear Data Measurements... [Pg.102]

Actinide half-lives, as standards for nuclear data measurements, 95-96 Actinide-nuclide decay data,... [Pg.504]

Dmitri Mendeleev) Mendelevium, the ninth transuranium element of the actinide series discovered, was first identified by Ghiorso, Harvey, Choppin, Thompson, and Seaborg in early in 1955 during the bombardment of the isotope 253Es with helium ions in the Berkeley 60-inch cyclotron. The isotope produced was 256Md, which has a half-life of 76 min. This first identification was notable in that 256Md was synthesized on a one-atom-at-a-time basis. [Pg.214]

Ernest O. Lawrence, inventor of the cyclotron) This member of the 5f transition elements (actinide series) was discovered in March 1961 by A. Ghiorso, T. Sikkeland, A.E. Larsh, and R.M. Latimer. A 3-Mg californium target, consisting of a mixture of isotopes of mass number 249, 250, 251, and 252, was bombarded with either lOB or IIB. The electrically charged transmutation nuclei recoiled with an atmosphere of helium and were collected on a thin copper conveyor tape which was then moved to place collected atoms in front of a series of solid-state detectors. The isotope of element 103 produced in this way decayed by emitting an 8.6 MeV alpha particle with a half-life of 8 s. [Pg.215]

Each of the elements has a number of isotopes (2,4), all radioactive and some of which can be obtained in isotopicaHy pure form. More than 200 in number and mosdy synthetic in origin, they are produced by neutron or charged-particle induced transmutations (2,4). The known radioactive isotopes are distributed among the 15 elements approximately as follows actinium and thorium, 25 each protactinium, 20 uranium, neptunium, plutonium, americium, curium, californium, einsteinium, and fermium, 15 each herkelium, mendelevium, nobehum, and lawrencium, 10 each. There is frequently a need for values to be assigned for the atomic weights of the actinide elements. Any precise experimental work would require a value for the isotope or isotopic mixture being used, but where there is a purely formal demand for atomic weights, mass numbers that are chosen on the basis of half-life and availabiUty have customarily been used. A Hst of these is provided in Table 1. [Pg.212]

Because the sequence of neutron captures inevitably leads to looFrn which has a fission half-life of only a few seconds, the remaining three actinides, loiMd, 102N0 and losLr, can only be prepared by bombardment of heavy nuclei with the light atoms jHe to foNe. This raises the mass number in multiple units and allows the f Fm barrier to be avoided even so, yields are minute and are measured in terms of the number of individual atoms produced. [Pg.1262]

The other actinides have been synthesized in the laboratory by nuclear reactions. Their stability decreases rapidly with increasing atomic number. The longest lived isotope of nobelium (102N0) has a half-life of about 3 minutes that is, in 3 minutes half of the sample decomposes. Nobelium and the preceding element, mendelevium (ioiMd), were identified in samples containing one to three atoms of No or Md. [Pg.147]

The actinoid elements (or actinides An) constitute a series of 14 elements which are formed by the progressive filling of the 5/ electron shell and follow actinium in the periodic table (atomic numbers 90-103). All of the isotopes of the actinide elements are radioactive and only four of the primordial isotopes, Th, and " " Pu, have a sufficient long half-life for there to be any of these left in nature. [Pg.31]

The element was generated by bombardment of californium with boron in a linear accelerator. The priority is debated. Isotopes of the elements were observed both by the group of Glenn T. Seaborg and by that of G. N. Flerov in Dubna. IUPAC proposed that the priority be shared. The longest-lived isotope has a half-life of 200 minutes. Lawrencium ends the series of actinides, as the 5f level is fully occupied with 14 electrons. [Pg.86]

We have considered typical examples of lanthanide and actinide solvent extraction by chelate formation, involving complexes with citric acid and with TTA, to prove that the labelling of a stable element by one of its radioactive isotopes can help to produce accurate data on the stability constants for complex formation. The method is applicable to elements with radioisotopes having a half-life allowing an ion concentration of 10 6m or less. Other methods of partition such as radiopolarography and radio-coulometry also result in accurate thermodynamical data when the same procedure of labelling is used (29). [Pg.19]

Often the products of nuclear reactions have very short half-lives. This is especially true for the heaviest elements obtained by bombardment of heavy targets with heavy ions. To identify and characterize such short-lived nuclides, fast separations are required solvent extraction techniques are well suited to provide the required fast separations. For example, the SISAK method [68] has been successfully used in conjunction with in-line gas jet separators at heavy ion accelerators to identify short half-life actinide isotopes produced by collision of heavy atoms. The Sisak method involves use of centrifugal contactors, with phase residence times as low as tenths of a second, in conjunction with in-line radiometric detection equipment. [Pg.541]

Actinium is the last (bottom) member of group 3 (IIIB) of elements in the periodic table and the first of the actinide series of metallic elements that share similar chemical and physical characteristics. Actinium is also closely related in its characteristics to the element lanthanum, which is located just above it in group 3. The elements in this series range from atomic number 89 (actinium) through 103 (lawrencium). Actiniums most stable isotope is actinium-227, with a half-life of about 22 years. It decays into Fr-223 by alpha decay and Th-227 through beta decay, and both of these isotopes are decay products from uranium-235. [Pg.308]

Curium is a synthetic (not natural) transuranic element of the actinide series. It was determined that curiums major valence and oxidation state was +3, similar to other elements of this series. The most stable isotope of curium is curium-247, with a half-life of 1.56xl0 years. [Pg.323]

Californium is a synthetic radioactive transuranic element of the actinide series. The pure metal form is not found in nature and has not been artificially produced in particle accelerators. However, a few compounds consisting of cahfornium and nonmetals have been formed by nuclear reactions. The most important isotope of cahfornium is Cf-252, which fissions spontaneously while emitting free neutrons. This makes it of some use as a portable neutron source since there are few elements that produce neutrons all by themselves. Most transuranic elements must be placed in a nuclear reactor, must go through a series of decay processes, or must be mixed with other elements in order to give off neutrons. Cf-252 has a half-life of 2.65 years, and just one microgram (0.000001 grams) of the element produces over 170 mhhon neutrons per minute. [Pg.327]

Californium is a transuranic element of the actinide series that is homologous with dysprosium (gjDy), just above it in the rare-earth lanthanide series. Cf-245 was the first isotope of californium that was artificially produced. It has a half-life of just 44 minutes. Isotopes of californium are made by subjecting berkelium to high-energy neutrons within nuclear reactors, as follows + (neutrons and A, gamma rays) — °Bk — °Cf + (3- (beta particle... [Pg.327]

Although in a strict sense not a member of the actinide series, actinium is included here for completeness as lanthanum is frequently included in the lanthanide series. The longest lived isotope of actinium is with a half-life of 21.8 years. It occurs in nature from the decay... [Pg.16]

Symbol Cf atomic number 98 atomic weight 251 (the principal isotope) californium is a transuranium radioactive actinide element electron configuration [Rn]5/i°7s2 valence state +3 most stable isotope Cf, half-life 800 years isotope properties are presented below ... [Pg.179]

Symbol Lr atomic number 103 atomic weight 262 a transuranium inner-transition actinide series element a synthetic radioactive element electron configuration [RnjTs b/ Sdi valence +3 six isotopes of masses 255 to 260 have been synthesized longest-lived known isotope Lr-260 has half-life of 3 minutes. [Pg.453]

Leach rates for elements other than those listed in Table II can also be determined by this method. In fact, any element in the periodic table that is solid at room temperature and has an activation product with a half-life sufficiently long to allow leach testing can be studied with this technique. This method can also be applied to the study of the leach rates of alpha emitting actinides present in waste. In this case, standard carrier-free radiochemical procedures, coupled with low background alpha counting, would be invoked. [Pg.125]

CURIUM. CAS 7440-51-9], Chemical element- symbol Cm. at. no. 96, at. wt. 247 (mass number of the most stable isotope i, radioactive metal of the Actinide series, also one of Ihe Transuranium elements, mp estimated 1350 50 C. l7CTn has a half-life of 1.64 x It)7 years, Olher long-lived isotopes arc J,Cm (ti j =9320 years), 4, Cm = 54X0 years I. "Cm... [Pg.463]

NEPTUNIUM. [CAS 7439-99-8]. Chemical element, symbol Np, at. no, 93, at. wt, 237,0482 (predominant isotope), radioactive metal of the Actinide series, also one of the Transuranium elements. Neptunium was the first of [he Transuranium elements [o be discovered and was first produced by McMillan and Abelson (1940) at the University of California at Berkeley. This was accomplished by bombarding uranium with neutrons. Neptunium is produced as a by-pruduct from nuclear reactors. 237Np is the most stable isotope, with a half-life of 2.20 x 106 years, The only other very long-lived isotope is that of mass number 236. with a half-life of 5 x 10- years. [Pg.1064]

PROTACTINIUM. [CAS 7440-13-13], Chemical element, symbol Pa, at. no. 91, at. wt, 231.036, radioactive metal of the Actinide Series, mp is estimated at less than 1600°C, All isotopes arc radioactive. The most stable isotope is 23IPa with a half-life of 3,43 v 104 years, The latter is a second-generation daughter of a5U and a member of the actinium (2n + 3) decay series, See also Radioactivity, Electronic configuration... [Pg.1370]

As an exercise, let us compare the spontaneous fission half-lives of two nuclei with barrier heights of 5 and 6 MeV, respectively, and barrier curvatures of 0.5 MeV. One quickly calculates that the spontaneous fission half-lives of these two nuclei differ by a factor of 3 x 105. The barrier heights and curvatures in this example are relevant for the actinides and illustrate the difficulty that a 1-MeV uncertainty in the fission barrier height corresponds to a factor of 105 in the spontaneous fission half-life. [Pg.307]

Lanthanides are coextracted with actinides and then separated from actinides, which are forecasted to be sent to a repository. The lanthanide elements comprise a unique series of metals in the periodic table. These metals are distinctive in terms of size, valence orbitals, electrophilicity, and magnetic and electronic properties, such that some members of the series are currently the best metals for certain applications. Increased use of the lanthanides in the future is likely, because their unusual combination of physical properties can be exploited to accomplish new types of chemical transformations. These elements coextracted with actinides and then separated from the latter, could in the future be recovered and used (among the lanthanides, only 151Sm is a long-lived isotope (half-life 90 years)).4... [Pg.200]

In this paper, we discuss several categories of decay data which have contributed to low-energy nuclear physics, indicate some of the ways they are useful in solving problems in other areas and identify needs for further measurements. Illustrations include half-life and emission-probability data of actinide nuclides important for reactor technology and useful as reference standards for nuclear-data measurements. Decay data of highly neutron-rich fission-product nuclides are important in such diverse areas as astrophysics and reactor-safety research. Some of these data needs and experimental approaches suitable for satisfying them are presented. [Pg.101]

In recognition of these needs, a list of recommended half-life values for a number of actinide nuclides useful as standards for nuclear-data measurements was prepared several years ago [VAN83]. This list included both total and partial half-life data for 11 such nuclides - the important isotopes of U, Np and Pu, as well as 252Cf. Subsequently, these data were revised [REI85a] to incorporate the results of new measurements, some of them from the work of the CRP. These data are given in a recent paper [REI85b], as well as in the final report of the IAEA CRP. [Pg.103]


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