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Acrylic acid catalysts

Coons R. Arkema finds glycerol-to-acrylic acid catalysts, demo-scale plant possible. Chem Week. 2009 171 36. [Pg.107]

The oxidation states of antimony, vanadium, and molybdenum in a "MoVSbNbO" propane-to-acrylic acid catalyst were probed by XANES... [Pg.426]

Acrylic acid catalyst, based on Mo/V mixed oxide copper lowers reaction temperature... [Pg.29]

Aminoplast (DMDHEU) + fluorocarbon water repellent (FC-208) -f- soil-release polymer (ethyl acrylate-acrylic acid) + catalyst [Zn(N03)2]... [Pg.623]

Asymmetric hydrogenation has been achieved with dissolved Wilkinson type catalysts (A. J. Birch, 1976 D. Valentine, Jr., 1978 H.B. Kagan, 1978). The (R)- and (S)-[l,l -binaph-thalene]-2,2 -diylblsCdiphenylphosphine] (= binap ) complexes of ruthenium (A. Miyashita, 1980) and rhodium (A. Miyashita, 1984 R. Noyori, 1987) have been prepared as pure atrop-isomers and used for the stereoselective Noyori hydrogenation of a-(acylamino) acrylic acids and, more significantly, -keto carboxylic esters. In the latter reaction enantiomeric excesses of more than 99% are often achieved (see also M. Nakatsuka, 1990, p. 5586). [Pg.102]

Esters. Most acryhc acid is used in the form of its methyl, ethyl, and butyl esters. Specialty monomeric esters with a hydroxyl, amino, or other functional group are used to provide adhesion, latent cross-linking capabihty, or different solubihty characteristics. The principal routes to esters are direct esterification with alcohols in the presence of a strong acid catalyst such as sulfuric acid, a soluble sulfonic acid, or sulfonic acid resins addition to alkylene oxides to give hydroxyalkyl acryhc esters and addition to the double bond of olefins in the presence of strong acid catalyst (19,20) to give ethyl or secondary alkyl acrylates. [Pg.150]

The addition of alcohols to form the 3-alkoxypropionates is readily carried out with strongly basic catalyst (25). If the alcohol groups are different, ester interchange gives a mixture of products. Anionic polymerization to oligomeric acrylate esters can be obtained with appropriate control of reaction conditions. The 3-aIkoxypropionates can be cleaved in the presence of acid catalysts to generate acrylates (26). Development of transition-metal catalysts for carbonylation of olefins provides routes to both 3-aIkoxypropionates and 3-acryl-oxypropionates (27,28). Hence these are potential intermediates to acrylates from ethylene and carbon monoxide. [Pg.151]

AUyl acetate can be obtained by the vapoi-phase reaction of propylene and acetic acid over a supported Pd catalyst (eq. 20) (110). Reaction of acrylic acid and propylene yields isopropyl acrylate (eq. 21), and catalytic reaction with acetic acid produces isopropyl acetate (eq. 22) (110). [Pg.130]

Acetic acid (qv) can be produced synthetically (methanol carbonylation, acetaldehyde oxidation, butane/naphtha oxidation) or from natural sources (5). Oxygen is added to propylene to make acrolein, which is further oxidized to acryHc acid (see Acrylic acid and derivatives). An alternative method adds carbon monoxide and/or water to acetylene (6). Benzoic acid (qv) is made by oxidizing toluene in the presence of a cobalt catalyst (7). [Pg.94]

Acrylic Esters. A procedure has been described for preparation of higher esters from methyl acrylate that illustrates the use of an acid catalyst together with the removal of one of the products by azeotropic distillation (112). Another procedure for the preparation of butyl acrylate, secondary alkyl acrylates, and hydroxyalkyl acrylates using -toluenesulfonic acid as a catalyst has been described (113). Alurninumisopropoxide catalyzes the reaction of amino alcohols with methyl acrylate and methyl methacrylate. A review of the synthesis of acryhc esters by transesterification is given in Reference 114 (see... [Pg.383]

These processes have supplanted the condensation reaction of ethanol, carbon monoxide, and acetylene as the principal method of generating ethyl acrylate [140-88-5] (333). Acidic catalysts, particularly sulfuric acid (334—338), are generally effective in increasing the rates of the esterification reactions. Care is taken to avoid excessive polymerisation losses of both acryflc acid and the esters, which are accentuated by the presence of strong acid catalysts. A synthesis for acryflc esters from vinyl chloride (339) has also been examined. [Pg.415]

Attenlion should be drawn to ihe use of tin oxide systems as heterogeneous catalysts. The oldest and mosi extensively patented systems are the mixed lin-vanadium oxide catalysis for the oxidation of aromatic compounds such as benzene, toluene, xylenes and naphthalene in the. synthesis of organic acids and acid anhydride.s. More recenily mixed lin-aniimony oxides have been applied lo the selective oxidaiion and ammoxidaiion of propylene to acrolein, acrylic acid and acrylonilrile. [Pg.385]

No single examples have been reported so far for the catalyzed asymmetric diazoalkane cydoadditions. Based on the kinetic data on the relative reaction rates observed by Huisgen in the competitive diazomethane cydoadditions between 1-alkene and acrylic ester (Scheme 7.32), it is found that diazomethane is most nu-deophilic of all the 1,3-dipoles examined (kaciyiate/fci-aikene = 250000) [78]. Accordingly, the cydoadditions of diazoalkanes to electron-defident alkenes must be most efficient when catalyzed by a Lewis acid catalyst. The author s group has become aware of this possibility and started to study the catalyzed enantioselective diazoalkane cydoadditions of 3-(2-alkenoyl)-2-oxazolidinones. [Pg.278]

Dupont et al. were able to obtain up to 80 % ee in the conversion of 2-phenyl-acrylic acid into (S)-2-phenylpropionic acid with the chiral [RuCl2(S)-BINAP]2NEt3 complex as catalyst in [BMIM][Bp4] melts (Scheme 5.2-9) [54]. [Pg.231]

Reactive compatibilization of engineering thermoplastic PET with PP through functionalization has been reported by Xanthos et al. [57]. Acrylic acid modified PP was used for compatibilization. Additives such as magnesium acetate and p-toluene sulfonic acid were evaluated as the catalyst for the potential interchange or esterification reaction that could occur in the melt. The blend characterization through scanning electron microscopy, IR spectroscopy, differential scanning calorimetry, and... [Pg.673]

The liquid phase reaction of ethylene with carbon monoxide and oxygen over a Pd VCu " catalyst system produces acrylic acid. The yield based on ethylene is about 85%. Reaction conditions are approximately 140°C and 75 atmospheres ... [Pg.201]

Transition metal oxides or their combinations with metal oxides from the lower row 5 a elements were found to be effective catalysts for the oxidation of propene to acrolein. Examples of commercially used catalysts are supported CuO (used in the Shell process) and Bi203/Mo03 (used in the Sohio process). In both processes, the reaction is carried out at temperature and pressure ranges of 300-360°C and 1-2 atmospheres. In the Sohio process, a mixture of propylene, air, and steam is introduced to the reactor. The hot effluent is quenched to cool the product mixture and to remove the gases. Acrylic acid, a by-product from the oxidation reaction, is separated in a stripping tower where the acrolein-acetaldehyde mixture enters as an overhead stream. Acrolein is then separated from acetaldehyde in a solvent extraction tower. Finally, acrolein is distilled and the solvent recycled. [Pg.215]

The main use of acrolein is to produce acrylic acid and its esters. Acrolein is also an intermediate in the synthesis of pharmaceuticals and herhicides. It may also he used to produce glycerol hy reaction with isopropanol (discussed later in this chapter). 2-Hexanedial, which could he a precursor for adipic acid and hexamethylene-diamine, may he prepared from acrolein Tail to tail dimenization of acrolein using ruthenium catalyst produces trans-2-hexanedial. The trimer, trans-6-hydroxy-5-formyl-2,7-octadienal is coproduced. Acrolein, may also he a precursor for 1,3-propanediol. Hydrolysis of acrolein produces 3-hydroxypropionalde-hyde which could he hydrogenated to 1,3-propanediol. ... [Pg.217]

There are several ways to produce acrylic acid. Currently, the main process is the direct oxidation of acrolein over a combination molybdenum-vanadium oxide catalyst system. In many acrolein processes, acrylic acid is made the main product by adding a second reactor that oxidizes acrolein to the acid. The reactor temperature is approximately 250°C ... [Pg.217]

Acrylic acid is usually esterified to acrylic esters by adding an esterification reactor. The reaction occurs in the liquid phase over an ion exchange resin catalyst. [Pg.217]

Much like the oxidation of propylene, which produces acrolein and acrylic acid, the direct oxidation of isobutylene produces methacrolein and methacrylic acid. The catalyzed oxidation reaction occurs in two steps due to the different oxidation characteristics of isobutylene (an olefin) and methacrolein (an unsaturated aldehyde). In the first step, isobutylene is oxidized to methacrolein over a molybdenum oxide-based catalyst in a temperature range of 350-400°C. Pressures are a little above atmospheric ... [Pg.250]

Coating materials may be based on short or medium-oil alkyds (e.g. primers for door and window frames) nitrocellulose or thermoplastic acrylics (e.g. lacquers for paper or furniture finishes) amino resin-alkyd coatings, with or without nitrocellulose inclusions, but with a strong acid catalyst to promote low temperature cure (furniture finishes) two-pack polyurethanes (furniture, flat boards) unsaturated polyester resins in styrene with free-radical cure initiated by peroxides (furniture) or unsaturated acrylic oligomers and monomers cured by u.v. radiation or electron beams (coatings for record sleeves paperback covers, knock-down furniture or flush interior doors). [Pg.634]

Acrylic Acid, CH2CHCOOH Free Radical Formers such as OH Ion Acrylic Acid Vapor 6000 kg/cm2 >75 Inhibitor—Methyl Ether of Hydroquinone-200ppm Storage in a cool, well ventilated area 18.5 429 Heterogeneous Free-Radical with a catalyst such as Azodiisobutyro-nitrile... [Pg.821]

Good yields and high diastereoselectivities were obtained by using zeolites in combination with Lewis-acid catalyst [21]. Table 4.7 illustrates some examples of Diels-Alder reactions of cyclopentadiene, cyclohexadiene and furan with methyl acrylate. Na-Y and Ce-Y zeolites gave excellent results for the cycloadditions of carbocyclic dienes, and combining these zeolites with anhydrous ZnBr2 further enhanced the endo diastereoselectivity of the reaction. An exception is the cycloaddition of furan that occurred considerably faster and with better yield, in comparison with the classic procedure [22], when performed in the presence of sole zeolites. [Pg.148]

The much more stable MIL-lOO(Cr) lattice can also be impregnated with Pd(acac)2 via incipient wetness impregnation the loaded catalyst is active for the hydrogenation of styrene and the hydrogenation of acetylene and acetylene-ethene mixtures to ethane [58]. MIL-lOl(Cr) has been loaded with Pd using a complex multistep procedure involving an addition of ethylene diamine on the open Cr sites of the framework. The Pd-loaded MIL-lOl(Cr) is an active heterogeneous Heck catalyst for the reaction of acrylic acid with iodobenzene [73]. [Pg.85]

Partial oxidation of propylene results in acrolein, H2C=CHCHO, an important intermediate for acrylic acid, H2C=CHCOOH, or in the presence of NH3, in acrylonitrile, H2C=CHCN, the monomer for acrylic fibers. Mixed metal oxides are used as the catalysts [B.C. Gates, Catalytic Chemistry (1992), Wiley, New York]. [Pg.372]

Acrolein, in turn, can be oxidized further to acrylic acid. The catalyst for this step is a mixed vanadium-molybdenum oxide. [Pg.373]

The surface transformations of propylene, allyl alcohol and acrylic acid in the presence or absence of NHs over V-antimonate catalysts were studied by IR spectroscopy. The results show the existence of various possible pathways of surface transformation in the mechanism of propane ammoxidation, depending on the reaction condition and the surface coverage with chemisorbed NH3. A surface reaction network is proposed and used to explain the catalytic behavior observed in flow reactor conditions. [Pg.277]

Allyl alcohol + NHs- The coadsorption experiments were made by first putting the catalyst into contact with NH3 at 200°C followed by removal of gaseous NH3 at r.t. and then putting the catalyst with the chemisorbed ammonia into contact with the allyl alcohol at r.t. Using procedures for the coadsorption tests like those used for propylene + NH3, less resolved spectra were obtained. The more remarkable differences in comparison with the analogous spectra for propylene + NH3 (Fig. 3) or acrylic acid + NH3 coadsorption (see below) are that (i) the band in-... [Pg.282]


See other pages where Acrylic acid catalysts is mentioned: [Pg.290]    [Pg.290]    [Pg.420]    [Pg.102]    [Pg.470]    [Pg.14]    [Pg.355]    [Pg.76]    [Pg.233]    [Pg.689]    [Pg.309]    [Pg.15]    [Pg.947]    [Pg.76]    [Pg.76]    [Pg.31]    [Pg.110]    [Pg.434]    [Pg.106]    [Pg.146]    [Pg.159]    [Pg.284]   
See also in sourсe #XX -- [ Pg.1026 ]




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Acrylic acid Catalyst carriers

Acrylic acid Catalyst characterization

Acrylic acid Catalyst deactivation

Acrylic acid Catalyst dispersion

Acrylic acid Catalyst materials

Acrylic acid Catalyst metals

Acrylic acid Catalyst preparation

Acrylic acid Catalyst regeneration

Acrylic acid Catalyst types

Acrylic acid catalysts, iridium complexes

Acrylic acid homogeneous catalysts

Acrylic acid, mixed oxide catalysts

Acrylic catalyst

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