Chlorination acetic acid

Alkene and alkyne Bromination, acetic acid Chlorination, acetic acid Acid-catalyzed hydration, water... 

Sodium cyanide, Glacial acetic acid, Chlorine gas, Carbon tetrachloride... 

Sodium cyanide, Glacial acetic acid, Chlorine gas. Carbon tetrachloride Benzene, Aluminum chloride, 2-Chloroacetyl chloride. Hydrochloric acid. Sodium hydroxide. Methylene chloride. Calcium chloride. Hexanes Methanol, MalononitrUe, o-Chlorobenzaldehyde, Piperdine Tetrahydrofuran, Hydrogen chloride, Chloropicrin, Powdered tin Benzene, Arsenic trichloride. Aluminum chloride. Hexanes Acetone, Sulfuric acid. Chlorine, Calcium chloride Isopropylamine, Glyoxal, Diethyl ether Benzene, Pyridine, Diphenylamine, Arsenic trichloride Tetraethyl lead. Arsenic trichloride... 

Properties Pale-yellow crystals containing not less than 28% nor more than 30% active chlorine. Chlorine odor stable when pure, decomposed slowly by air, rapidly by impurities, petrolatums, kerosene, olive oil, and alcohol. Soluble in glacial acetic acid, chlorinated paraffin hydrocarbons, eucalyptol, benzene, chloroform, and carbon tetrachloride almost insoluble in water mp 80C. 

In the iodometric determination in the presence of acetic acid, chlorine... 

The plant assembly may be arranged in the manner shown in Fig. 6-14. The acetic acid is stored in aluminum tanks of any suitable size. The acid is run into a scale tank prior to delivery to the chlorinator. The chlorinator is a large steam-jacketed enameled vessel. The top of the vessel is equipped with connections for acetic acid, chlorine, air, effluent gases, condensate. 

Methanesulfonylcarbonimidoyl dichloride ). To a solution of 19 g of S,S-dimethyl N-methanesulfonylcarbonimide in 180 ml of glacial acetic acid chlorine is added below 15°C with cooling for a period of one hr. Evaporation of the solvent and vacuum distillation of the residue yields 14 g (83%) of methanesulfonylcarbonimidoyl dichioride, m.p. 73-76°C (m.p. 79-80 C is listed in Reference 95 the b.p. can not be established because the compound sublimes under vacuum). 

Hydrazine sulfate catalyst, acetic acid chlorination Acetic anhydride catalyst, acetic acid prod. 

Monochlorination of acetic acid (chlorination of a-keto compounds)... 

Bromoacetanilide is slightly less reactive toward further electrophilic substitution than acetanilide, but it is still sufficiently reactive to be chlorinated under mild conditions without a strong Lewis acid catalyst. Thus, molecular chlorine dissolved in acetic acid chlorinates 4-bromoacetanilide to produce 4-bromo-2-chloroacetanilide (20) as shown in Equation 21.12. The formation of the 2- rather than the 3-chloro isomer demonstrates the more powerful directing effect of the acetamido group as compared to the bromo substituent. 

Acetic acid Chlorine Ferric phosphate 2-Nitro-butanol Potassium... 

Acetic Acid Chlorine Lactic Acid R Sodium Chloride R... 

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