A preferential

Many appHcations use screws with constant pitch to feed material from a slotted opening. The configuration shown in Figure 9a shows a constant pitch and constant diameter causing a preferential flow channel to form at the back (over the first flight) of the screw. This type of flow destroys the mass flow pattern and potentially allows some or all of the problems discussed about fiinnel flow. 

Fig. 13. (a) Preferential flow through rotary valve and (b) correction from installation of a vertical spool piece. 

Dezincification is explained by two theories. The first is that the alloy dissolves, with a preferential redeposition of copper. The other proposes a selective leaching of the zinc, leaving the copper behind. There is evidence that both mechanisms may operate, depending on the specific environment. 

Experimentally, this technique is very similar to the TDI technique described above. A laser beam is incident normally on a diffraction grating or a preferentially scratched mirror deposited on the surface to obtain the normally reflected beam and the diffracted beams as described above. Instead of recombining the two beams that are located symmetrically from the normally reflected beam, each individual beam at an angle d is monitored by a VISAR. Fringes Fg produced in the interferometers are proportional to a linear combination of both the longitudinal U(t) and shear components F(t) of the free surface velocity (Chhabildas et al., 1979), and are given by... 

Extractive Stripping of Inert-Rich Hydrocarbon Gases with a Preferential Physical Solvent. U.S. Patent 4,680.042, Jul. 14, 1987. 

Another convenient method for the preparation of tertiary enamines involves the dehydrogenation of saturated bases with mercuric acetate (111-116). A trans-1,2 elimination occurs, which requires an antiperi-planar position of the nitrogen-free electron pair and the eliminated atom. A preferential elimination of the hydrogen atom from the tertiary carbon atom is supposed. Overoxidation can be avoided by adding disodium ethyl-enediaminotetraacetate to the reaction mixture (117). 

Stereoselective conversion of a thiane 57 to the corresponding tmns-thiane-l-oxide 58 was achieved by bromonium ion mediated electrooxidation while a preferential formation of the cis-sulphoxide 58 was observed under acidic electrolysis123 (equation 38). 

Electrochemical oxidation of 4-aryl-substituted thiane in aqueous organic solvents containing various halide salts as electrolytes gave selectively the trans-sulfoxide (lOe). Under acidic conditions a preferential formation of the cis-sulfoxide was attained328. The stereoselective potential of this method for the oxidation of cyclic sulfides139,329 is apparent (equation 123). 

From the foregoing it is clear that indentation anisotropy is a consequence of high molecular orientation within highly oriented fibrils and microfibrils coupled with a preferential local elastic recovery of these rigid structures. We wish to show next that the influence of crystal thickness on AMH is negligible. The latter quantity is independent on 1 and is only correlated to the number of tie molecules and inter-crystalline bridges of the oriented molecular network. 

For Hg, the temperature coefficient of Ea=0 was determined by Randies and Whiteley78 and found to be equal to 0.57 mV K l.On the basis of a simple up-and-down molecular model for water,79 this positive value has been taken to indicate a preferential orientation, with the negative end of the molecular dipole (oxygen) toward the metal surface. While this may well be the case, the above discussion shows that the analysis of the experimental value is far more complex. 

To some degree the ratio of additive monomer to additive dimer can be infiuenced by the current density. High current densities favor the formation of additive monomers, low ones these of additive dimers (Table 8, Nos. 4, 5). This result can be rationalized according to Eq. 9 At high current densities, which corresponds to a high radical concentration in front of the electrode, the olefin can trap only part of the Kolbe radicals formed. This leads to a preferred coupling to the Kolbe dimer and a combination of the Kolbe radical with the primary adduct to the additive monomer. At low current densities the majority of the Kolbe radicals are scavenged by the olefin, which leads to a preferential formation of the additive dimer. 

In solvents that strongly resist anodic oxidation as MeCN, CH2CI2/CF3CO2H, or T SOjH CH-bonds in the alkyl chain can be oxidized. In acetonitrile a preferential acetamidation in the (co-2)- and ((B-l)-position occurs (Eq. 43) [352]. 

This expansion will require a major commitment of resources on the part of universities, government, private foundations, and industry. Can such a preferential commitment to one discipline be justified, particularly at a time of severe budgetary austerity Each agency responsible for funding chemical engineering research will have to answer this question for itself, but the committee believes that the following... 

The important yet unexpected result is that in NR-s-SBR (solution) blends, carbon black preferably locates in the interphase, especially when the rubber-filler interaction is similar for both polymers. In this case, the carbon black volume fraction is 0.6 for the interphase, 0.24 for s-SBR phase, and only 0.09 in the NR phase. The higher amount in SBR phase could be due to the presence of aromatic structure both in the black and the rubber. Further, carbon black is less compatible with NR-cE-1,4 BR blend than NR-s-SBR blend because of the crystallization tendency of the former blend. There is a preferential partition of carbon black in favor of cis-1,4 BR, a significant lower partition coefficient compared to NR-s-SBR. Further, it was observed that the partition coefficient decreases with increased filler loading. In the EPDM-BR blend, the partition coefficient is as large as 3 in favor of BR. 

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