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Figure 1. Photoelectron circular dichroism angular distribution [/icp(0) - /rcp(6)] for the hv = 10.3-eV photoionization of (/ )-camphor, as imaged with the photon beam propagating along the X axis. The x,y axis scales are the physical pixel coordinates of the detector. Figure 1. Photoelectron circular dichroism angular distribution [/icp(0) - /rcp(6)] for the hv = 10.3-eV photoionization of (/ )-camphor, as imaged with the photon beam propagating along the X axis. The x,y axis scales are the physical pixel coordinates of the detector.
When the proton acceptor molecule contains an atom like O or S, a second lone pair is pre-,sent that makes prediction of the equilibrium geometry less obvious. If one assumes an sp hybridization, the two lone pairs are disposed as in Fig. 2.3A, which would yield an angle P, between the HYH bisector and the X--Y axis, in the vicinity of 125°. The alternate type of hybridization, sp, leaves one of the lone pairs in a p-orbital, oriented 90° from the other lone pair. This arrangement would lead to a 180° p angle. Geometry B is also favored by certain electrostatic arguments. Specifically, it would permit the dipole moment of YH2, collinear with the HYH bisector, to align itself with the dipole of the X—H molecule. [Pg.61]

Another factor has to do with the linearity of the H-bond itself. The symmetry of Fig. 2.3B would place the bridging hydrogen directly along the X--Y axis, but it is plain that the forces above and below this axis in Fig. 2.3A are not equal. It should therefore not be surprising to see the proton deviate from the H-bond axis in such cases, with nonzero values of a. It is likely the proton would be above the line as drawn, based on the direction of the YH2 dipole moment in this configuration. [Pg.62]

Extraction is the vertical movement of water. On an X-Y axis, this is the Y component and it represents lift. Extracting water from a well and pumping water up a hill are examples of extraction. [Pg.12]

Transport is the horizontal movement of water. On an X-Y axis, this... [Pg.12]

Thus, the principal axes of A make angles of 16, 16, and 4 2° with the x, y, and z axes of D, respectively. [In this respect, our results differ significantly from those of Hochstrasser et al. (1973,1978), who concluded on the basis of near zf ENDOR results that the principal axes of A and D are essentially coincident. We believe this to be a consequence of the fact that at (or near) zf, the electron spins remain locked to the fine-structure frame and do not reflect the local symmetry of the hyperfine tensor. Thus, some caution should be exercised in the interpretation of (near) zf data, particularly in cases where symmetry does not require the coincidence of principal axes.] The fact that t is nearly axially symmetric about x" suggests that two-center contributions can be safely neglected. In that event, the x" and y" axes should be parallel to the x and y symmetry axes of the carbonyl fragment. Since the angle between x" [y") and a (b) is the same (within experimental error of +2°) as that between the host x (y) axis and... [Pg.187]

Kevlar Trademark for a group of DuPont aromatic polyimides that are frequently used as fibers in reinforced plastics and composites. Major characteristics are low thermal expansion, light weight, and good electrical properties, coupled with stiffness in laminated form. One special application area is in high-performance circuit boards requiring low x-y axis thermal expansion. [Pg.1105]

Y direction. And the sphere particles translation in Z direction and rotation around the X, Y axis are limited. The rock block clumps translation in Z direction as well as the rotation around the X, Y, Z axis are denied to achieve two-dimensional simulation of biaxial compression. [Pg.753]

Drying (origin, plate, after first dimension) at 1 cm, 1 cm x-, y-axis cold dryer. [Pg.931]

Conductive anodic filament (CAP) resistance test X-Y axis ... [Pg.616]

Coefficient Of Thermal Expansion (CTE). The CTE of a laminate is comprised of values for x-y axis, or in-plane expansion, and z-axis, or vertical expansion (which is further comprised of the percent expansion below and above the glass transition temperature).The data are reported in ppm/°C a typical plot is shown in Fig. 27.3. [Pg.622]

An example of the low overall CTE that can be obtained using a CIC core is shown in Fig. 57.20. Unfortunately, the constrained x-y axis expansion results in increased z-axis expansion that can reduce PTH reliability to dangerously low levels, especially in an environment in which the full mil-spec thermal cycle of -55 to +125°C is imposed. Consequently, use of poly-imide is recommended with CIC cores. Because of its high Tg and low CTE below Tg, poly-imide imposes much lower strains on the PTH for a given thermal cycle than other dielectrics. [Pg.1345]

The similarities between the labyrinth of a maze and of porosity in a carbon are quite remarkable although it is necessary to mention some limitations, initially. There are four limitations of importance. First, this maze, of course, is in two dimensions second, the lines of the maze are too orientated relative to an x-y axis. Such parallelism is unlikely to exist within a porous carbon third, this labyrinth is best suited to a microporous carbon, only and not to micro-porous carbon fibers. Fourth, in such a model, rates of diffusion are likely to be too slow and hence there is a need to consider the location of mesoporosity. The inclusion of mesoporos-ity is another matter. Mesoporosity has to promote enhanced adsorption to the interior of the fiber. As a matter of scaling, although the models of Figure 3.28(a-c) provide an impressive number of adsorption locations, it will require about 10 of such models, as shown in Figure 3.28(c), to describe 1 g of carbon. The human mind cannot cope with this necessity. [Pg.136]


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See also in sourсe #XX -- [ Pg.607 ]




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