Wastewater treatment, inorganic chemicals

Miscellaneous. Hydrochloric acid is used for the recovery of semiprecious metals from used catalysts, as a catalyst in synthesis, for catalyst regeneration (see Catalysts, regeneration), and for pH control (see Hydrogen-ION activity), regeneration of ion-exchange (qv) resins used in wastewater treatment, electric utiUties, and for neutralization of alkaline products or waste materials. In addition, hydrochloric acid is also utilized in many production processes for organic and inorganic chemicals. 

This section describes the major industrial processes of individual inorganic chemicals under the 11 subcategories and the related wastewater generated. It contains the sources of wastewater and typical treatment processes. 

Related to chemical pollution - referring to all kind of contamination (mineral and organic) - there is a clear distinction between point-source pollution and diffuse pollution. It appears that it is easier to take measures for point-source pollution, for instance, the improvement of the wastewater treatment plants, even if the treatments for specific compounds (pesticides, emerging compounds, etc.) still need further research. Measures for diffuse pollution can be more complex because some of them require real political decisions, for instance to interfere on agricultural practices to reduce inorganic and organic fertilisers. 

Oxidation of organic and inorganic species in aqueous solutions can find applications in fine chemical processes and wastewater treatment. Here, the oxidant, often either air or pure oxygen, must undergo all the mass transfer steps mentioned above in order for the reaction to proceed. During the last decade, increased environmental constraints have resulted in the application of novel processes to the treatment of waste streams. An example of such a process is wet air oxidation. Here, the simplest reactor design is the cocurrent bubble column. However, the presence of suspended organic and inert solids makes the use of monolith reactors favorable. 

The range of available membrane materials used in water and wastewater treatment is quite broad, but most of them are synthetic membranes. Synthetic membranes can be organic or inorganic however, the most important class of membrane materials is organic or polymer membrane. The choice of a given polymer as a membrane material is not arbitrary (13). Inorganic materials generally possess superior chemical and thermal stability relative to polymeric materials. However, both types of membranes have different applications. A list of common membranes is shown in Table 2. 

AC materials as porous materials with very high surface areas and large pore volume have been widely used in deodorization, decolorization, purification of drinking water, treatment of wastewater, and adsorption and separation of various organic and inorganic chemicals. Recently, some carbon materials have been reported for adsorptive desulfurization of liquid hydrocarbon fuels. 

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