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Operators velocity

Note that the subscript on the a matrices refers to the particle, and a here includes all of the tlx, tty and components in eq. (8.4). The first correction term in the square brackets is called the Gaunt interaction, and the whole term in the square brackets is the Breit interaction. The Dirac matiices appear since they represent the velocity operators in a relativistic description. The Gaunt term is a magnetic interaction (spin) while the other term represents a retardation effect. Eq. (8.27) is more often written in the form... [Pg.210]

From the operating data in Table VIII the following are points of special interest in the experiment (a) period 4 represents performance at 2000/hr fresh gas space velocity and 3 1 CGR ratio when the catalyst is fresh (b) period 15 represents performance at 2000/hr space velocity before changes to 3000/hr (c) periods 17 and 26 represent the beginning and end of the 3000/hr space velocity operation (d) period 34 represents operation at 2000/hr space velocity and a high CGR ratio (9.59 1) (e) periods 37 and 62 represent the beginning and end of an operating period later in the experiment at 2000/hr space velocity and 3 1 CGR... [Pg.115]

For a single electron, the velocity operator in eq.(7) corresponds to the current operator j(Ro,B) = —ev, and hence to the following operator representing the magnetic field induced at a field point R... [Pg.196]

In order to calculate R from equation 3, we have to evaluate the integrals iin n and mj,. n, with the MO jr and jr given in equations 5a and 5b. We assume only nearest-neighbour interactions and equal -integrals in all the integrals for the pairs (1,2) and (3,4), as justified by symmetry. The electric dipole will be described by the velocity operator V, in order to ensure origin-independent results, and equation 6 follows ... [Pg.143]

Perhaps the simplest and most cost-effective way of treating relativistic contributions in an all-electron framework is the first-order perturbation theory of the one-electron Darwin and mass-velocity operators [46, 47]. For variational wavefunctions, these contributions can be evaluated very efficiently as expectation values of one-electron operators. [Pg.42]

The commutators of the relativistic and non-relativistic free-particle operators with orhital angular momentum look rather different, hut can he recast in the same mathematical form using the velocity operators of respective domains... [Pg.390]

The products (T I4 Tfp) are calculated from LMTO eigenstates by using a numerical derivation of the hamiltonian in the reciprocal space as explained in last section, diagonalization provides the components of eigentstates on the basis set Xthi k ). In this basis the velocity operator, Vx = [X,H], has the following matrix elements ... [Pg.541]

The narrow-bore column approach is a very effective and is the most popular way of increasing analysis speed. Substantial reductions in analysis times are achieved by exploiting two factors a shorter column length and the application of higher than optimum average linear velocities. Operating under optimum... [Pg.322]

The quantum mechanical expression for the charge-weighted current density is obtained from Eq. (26) when we replace the classical velocity r (f) by the Dirac velocity operator caL and evaluate its expectation value (21),... [Pg.185]

It comprises the non-relativistic Hamiltonian of the form pf/2me + V and the relativistic correction terms, such as the mass-velocity operator —pf/8m c2, the Darwin term proportional to Pi E and the spin-orbit coupling term proportional... [Pg.192]

The origin with respect to which the electric quadrupole and magnetic dipole operators are defined is indicated by the superscript. jiPp is the /3 component of the velocity operator. The connection between the quadrupole moment referred to or - for example the centre of nuclear masses - and the EQC is... [Pg.255]

Accelerated deactivation tests in hydrocracking have been reported (38), where a constant conversion mode was run at much higher space velocity (and hence temperature) than under actual operation conditions. Differences in deactivation were measured that were later substantiated in commercial operation (38). Although all these approaches aim at accelerating the catalyst deactivation reaction in Equation 7, such tests should obviously not be applied to catalyst systems that — at the high space velocity — operate at such high temperatures that very high polyaromatics concentrations prevail. [Pg.394]

Inside diameter Reactor height Operation temperature Fluidisation velocity Operation pressure Fuel feed rate (max.) Gasification agent MaximumThermal capacity... [Pg.216]


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See also in sourсe #XX -- [ Pg.120 , Pg.359 ]

See also in sourсe #XX -- [ Pg.132 , Pg.137 ]

See also in sourсe #XX -- [ Pg.42 ]




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Mass-velocity operator

Mass-velocity operator Cowan-Griffin

Nonrelativistic limit velocity operator

Operational velocity

Operational velocity

Relativistic corrections mass-velocity operator

Relativistic mass-velocity operator

Schrodinger velocity operator

Velocity Dirac operator

Velocity Verlet operator

Velocity dipole operator

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