Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Vectors three-dimensional

The strategy for representing this differential equation geometrically is to expand both H and p in tenns of the tln-ee Pauli spin matrices, 02 and and then view the coefficients of these matrices as time-dependent vectors in three-dimensional space. We begin by writing die the two-level system Hamiltonian in the following general fomi. [Pg.230]

One starts with the Hamiltonian for a molecule H r, R) written out in terms of the electronic coordinates (r) and the nuclear displacement coordinates (R, this being a vector whose dimensionality is three times the number of nuclei) and containing the interaction potential V(r, R). Then, following the BO scheme, one can write the combined wave function [ (r, R) as a sum of an infinite number of terms... [Pg.145]

Iditional importance is that the vibrational modes are dependent upon the reciprocal e vector k. As with calculations of the electronic structure of periodic lattices these cal-ions are usually performed by selecting a suitable set of points from within the Brillouin. For periodic solids it is necessary to take this periodicity into account the effect on the id-derivative matrix is that each element x] needs to be multiplied by the phase factor k-r y). A phonon dispersion curve indicates how the phonon frequencies vary over tlie luin zone, an example being shown in Figure 5.37. The phonon density of states is ariation in the number of frequencies as a function of frequency. A purely transverse ition is one where the displacement of the atoms is perpendicular to the direction of on of the wave in a pmely longitudinal vibration tlie atomic displacements are in the ition of the wave motion. Such motions can be observed in simple systems (e.g. those contain just one or two atoms per unit cell) but for general three-dimensional lattices of the vibrations are a mixture of transverse and longitudinal motions, the exceptions... [Pg.312]

Let jP be a vector whose components are functions of a scalar variable (e.g. time-dependent position vector of a point F in a three-dimensional domain)... [Pg.255]

The only limitation on the function expressed is that it has to be a function that has the same boundary properties and depends on the same variables as the basis. You would not want to use Fourier series to express a function that is not periodic, nor would you want to express a three-dimensional vector using a two-dimensional or four-dimensional basis. [Pg.555]

One technique for high dimensional data is to reduce the number of dimensions being plotted. For example, one slice of a three-dimensional data set can be plotted with a two-dimensional technique. Another example is plotting the magnitude of vectors rather than the vectors themselves. [Pg.118]

Because the electrons do not penetrate into the crystal bulk far enough to experience its three-dimensional periodicity, the diffraction pattern is determined by the two-dimensional surface periodicity described by the lattice vectors ai and ai, which are parallel to the surface plane. A general lattice point within the surface is an integer multiple of these lattice vectors ... [Pg.74]

Forces are vector quantities and the potential energy t/ is a scalar quantity. For a three-dimensional problem, the link between the force F and the potential U can be found exactly as above. We have... [Pg.12]

The state of any particle at any instant is given by its position vector q and its linear momentum vector p, and we say that the state of a particle can be described by giving its location in phase space. For a system of N atoms, this space has 6iV dimensions three components of p and the three components of q for each atom. If we use the symbol F to denote a particular point in this six-dimensional phase space (just as we would use the vector r to denote a point in three-dimensional coordinate space) then the value of a particular property A (such as the mutual potential energy, the pressure and so on) will be a function of r and is often written as A(F). As the system evolves in time then F will change and so will A(F). [Pg.59]

The border between two three-dimensional atomic basins is a two-dimensional surface. Points on such dividing surfaces have the property that the gradient of the electron density is perpendicular to the normal vector of the surface, i.e. the radial part of the derivative of the electron density (the electronic flux ) is zero. [Pg.223]

We begin our discus.sion with the top-down approach. Let F be a two or three dimensional region filled with a fluid, and let v x,t) be the velocity of a particle of fluid moving through the point x = ( r, y, z) at time t. Note that v x, t) is a vector-valued field on F, and is to be identified with a macroscopic fluid cell. The fact that we can make this so-called continuum assumption - namely that we can simultaneously speak of a velocity of a particle of fluid and think of a particle of fluid as a macroscopic cell - is not at all obvious, of course, and deserves some attention. [Pg.464]

It transforms an ordinary three-dimensional vector A into BA = A, i.e.,... [Pg.394]

If a basis is found that does not satisfy this condition, an orthonormal set can be constructed from it by the Schmidt process analogous to the familiar device in three-dimensional vector analysis.8... [Pg.430]

Thus consider first the one-photon amplitude T kx) i = 1,2,3. To this three dimensional vector amplitude, which is transverse, i.e. [Pg.573]

The results of the three-dimensional random walk, based on the freely-jointed chain, has permitted the derivation of the equilibrium statistical distribution function of the end-to-end vector of the chain (the underscript eq denotes the equilibrium configuration) [24] ... [Pg.80]

Force and velocity are however both vector quantities and in applying the momentum balance equation, the balance should strictly sum all the effects in three dimensional space. This however is outside the scope of this text and the reader is referred to more standard works in fluid dynamics. [Pg.46]

The position of any point in three-dimensional cartesian space is denoted by the vector r with components v, y, z, so that... [Pg.57]

Equivalently, expectation values of three-dimensional dynamical quantities may be evaluated for each dimension and then combined, if appropriate, into vector notation. For example, the two Ehrenfest theorems in three dimensions are... [Pg.59]

The wave function for this system is a function of the N position vectors (ri, r2,. .., r v, i). Thus, although the N particles are moving in three-dimensional space, the wave function is 3iV-dimensional. The physical interpretation of the wave function is analogous to that for the three-dimensional case. The quantity... [Pg.60]

A set of complete orthonormal functions ipfx) of a single variable x may be regarded as the basis vectors of a linear vector space of either finite or infinite dimensions, depending on whether the complete set contains a finite or infinite number of members. The situation is analogous to three-dimensional cartesian space formed by three orthogonal unit vectors. In quantum mechanics we usually (see Section 7.2 for an exception) encounter complete sets with an infinite number of members and, therefore, are usually concerned with linear vector spaces of infinite dimensionality. Such a linear vector space is called a Hilbert space. The functions ffx) used as the basis vectors may constitute a discrete set or a continuous set. While a vector space composed of a discrete set of basis vectors is easier to visualize (even if the space is of infinite dimensionality) than one composed of a continuous set, there is no mathematical reason to exclude continuous basis vectors from the concept of Hilbert space. In Dirac notation, the basis vectors in Hilbert space are called ket vectors or just kets and are represented by the symbol tpi) or sometimes simply by /). These ket vectors determine a ket space. [Pg.80]

The Dirac delta function may be readily generalized to three-dimensional space. If r represents the position vector with components x, y, and z, then the three-dimensional delta function is... [Pg.294]

A vector x in three-dimensional cartesian space may be represented as a column matrix... [Pg.337]

Velocity maps of simple or complex liquids, emulsions, suspensions and other mixtures in various geometries provide valuable information about macroscopic and molecular properties of materials in motion. Two- and three-dimensional spin echo velocity imaging methods are used, where one or two dimensions contain spatial information and the remaining dimension or the image intensity contains the information of the displacement of the spins during an observation time. This information is used to calculate the velocity vectors and the dispersion at each position in the spatially resolved dimensions with the help of post-processing software. The range of observable velocities depends mainly on the time the spins... [Pg.59]

Figure 2. Orthogonal decomposition of a three-dimensional Hilbert space case of two collinear vectors in the two-dimensional subspace. Figure 2. Orthogonal decomposition of a three-dimensional Hilbert space case of two collinear vectors in the two-dimensional subspace.
Using the valence profiles of the 10 measured directions per sample it is now possible to reconstruct as a first step the Ml three-dimensional momentum space density. According to the Fourier Bessel method [8] one starts with the calculation of the Fourier transform of the Compton profiles which is the reciprocal form factor B(z) in the direction of the scattering vector q. The Ml B(r) function is then expanded in terms of cubic lattice harmonics up to the 12th order, which is to take into account the first 6 terms in the series expansion. These expansion coefficients can be determined by a least square fit to the 10 experimental B(z) curves. Then the inverse Fourier transform of the expanded B(r) function corresponds to a series expansion of the momentum density, whose coefficients can be calculated from the coefficients of the B(r) expansion. [Pg.317]

The general case of a three-dimensional body enclosed by a surface 5 will be treated using vector analysis. The time change in the amount M is given by the relationship... [Pg.93]

When n > 3 in Eq. (58), the space cannot be visualized. However, (he analogy with three-dimensional space is clear. Thus an n-dimensional coordinate system consists of n mutually perpendicular axes. A point requires n coordinates for its location and, which is equivalent, a vector is described by its n components. [Pg.87]


See other pages where Vectors three-dimensional is mentioned: [Pg.132]    [Pg.1365]    [Pg.530]    [Pg.101]    [Pg.65]    [Pg.121]    [Pg.678]    [Pg.479]    [Pg.690]    [Pg.441]    [Pg.552]    [Pg.771]    [Pg.62]    [Pg.238]    [Pg.570]    [Pg.410]    [Pg.173]    [Pg.60]    [Pg.76]    [Pg.149]    [Pg.61]    [Pg.207]    [Pg.408]   
See also in sourсe #XX -- [ Pg.3 ]

See also in sourсe #XX -- [ Pg.39 ]




SEARCH



Three-Dimensional Vector Algebra

© 2024 chempedia.info