University of Groningen

BIOSON Research Institute and Dept of Biophysical Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, the Netherlands... 

Filling of these cavities with a nonpolar molecules is enthalpy driven. See Diederich, F. Smithrud, D. B. Sanford, E. M. Wyman, T. B. Ferguson, S. B. Carcanague, D. R. Chao, I. Houk, K. N. Acta Chem. Scand. 1992, 46, 205 and references cited therein See (a) Blokzijl, W. Ph. D. Thesis, University of Groningen, 1991 (b) Streefland, L. Ph. D. TTzewis, University of Gronirigen, 1998 and references cited therein. 

WE van Gunsteren, HJC Berendsen. GROMOS 86 Groningen Molecular Simulation Pi o-gram Package. University of Groningen, The Netherlands, 1986. 

Department of Chemical Engineering The University of Groningen Groningen, The Netherlands... 

Department of Polymer Chemistry and Materials Science Centre University of Groningen Nijenborgh 4 NL-9747 AG Groningen The Netherlands... 

VasUeios, K., "Physical Properties of Grafted Polymer Mono-layers Studied by Scanning Force Microscopy Morphology, Friction, Elasticity, Dissertations, University of Groningen, Denmark, 1997. 

University of Groningen, 106 University of Houston, 200 University of Keele, 69 University of Minnesota, 1,35,176,257,353 Yale University, 404... 

We thank Ir. Gerard Kwant, DSM Research, Chiara Tarabiono and Prof. Dr. Dick B. Janssen, University of Groningen for helpful discussions. This work was funded by the Dutch IBOS program, which contributions from DSM, Organon, the Dutch Ministry of Economic Affairs, the University of Groningen and the Dutch Science Foundation. 

---