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Tris phosphite, ruthenium

Bis(trimethylsilyl) peroxide, (CH3)3SiOOSi(CH3)3, is prepared from trimethylsilyl chloride, l,4-diaza[2,2,2]bicyclooctane, and Dabco s complex with 2 mol of hydrogen peroxide [127]. It is used alone [228] or in the presence of catalysts such as pyridinium dichromate [236] trimethylsilyl trifluoromethanesulfonate, CF3S03Si(CH3)3 [228, 237] or tris-(triphenylphosphine)ruthenium dichloride, [(C6H5)3P]3RuCl2 [236]. This reagent oxidizes primary alcohols to aldehydes (in preference to the oxidation of secondary alcohols to ketones [236]), ketones to esters or lactones Baeyer-Villiger reaction) [238], and nucleoside phosphites to phosphates [228]. All these oxidations require anhydrous conditions. [Pg.10]

Triphosphenium salts, 27 253 1W-1,2,3-Triphospholium, 3,3,4,5-tefrahy-dro-1,1,3,3-tetraphenyl-, hexachloro-stannaie(2-)(2 l), 27 255 Tris(4-methylphenyl) phosphite, ruthenium complex, 26 277... [Pg.370]

QiHjiOjP, Tris(4-methylphenyl) phosphite ruthenium complex, 26 277, 278 C2 H3,PSi, Phosphine, (2,4,6-tri-tert-butyl-phenyl)(trimethylsilyl)-, 27 238 QsHaiNOP, Benzamide, 2-(diphenylphos-phino)-W-phenyl-, 27 324... [Pg.380]

OjNdC4,Hw, Neodymium, tris(2,6-di-rm-butyl-4-methylphenoxo)-, 27 167 OjPCihHu, Triphenyl phosphite, ruthenium complex, 26 178... [Pg.406]

O3PC21H21, Tris(4-methylphenyl)phosphite, ruthenium complex, 26 277, 278 03P2RhC2iH45, Rhodium(I), (acetato)car-bonylbis(triisopropylphosphine)-, 27 292... [Pg.406]

PO.1C21H21, Tris(4-methylphenyl)phosphite, ruthenium complex, 26 277, 278... [Pg.416]

PC sH,g, Triphenyl phosphite, cobalt complex, 29 178 iron complexes, 28 171,29 159 nickel complex, 28 101 ruthenium complex, 26 178 03PC2 H2, Tris(4-methylphenyl) phosphite, ruthenium complex, 26 277,278,28 227 03P2RhC2,H45, Rhodium(I), (acetato)car-bonylbis(triisopropylphosphine)-, 27 292... [Pg.392]

TRI- AND TETRANUCLEAR CARBONYL-RUTHENIUM CLUSTER COMPLEXES CONTAINING ISOCYANIDE, TERTIARY PHOSPHINE, AND PHOSPHITE LIGANDS. RADICAL ION-INITIATED SUBSTITUTION OF METAL CLUSTER CARBONYL COMPLEXES UNDER MILD CONDITIONS... [Pg.271]

H40 2Ru4C]2, Ruthenium, dodecacarbonyl-tetra-p.-hydrido-tetra-, 26 262 H40,jP,Ru4C3,H32, Ruthenium, deca-carbonyl(dimethylphenylphosphine)-tetrahydrido[tris(4-methylphenyl)-phosphite]tetra-, 26 278 H40 4PRu4C32H,i, Ruthenium,... [Pg.422]

P2Ru4CwH36, Ruthenium, decacarbonyl-(dimethylphenylphosphine)-tetra-hydrido[tris(4-methylphenyl)-phosphite]tetra-, 26 278... [Pg.433]

PRu4C12H25, Ruthenium, undecacar-bonyl-tetrahydrido[tris(4-methyl-phenyl)phosphite]tetra-, 26 277 OijP2Ru CjIHij, Ruthenate(2-), prcar-bido-tetradecacarbonylpenta-bis[p,-nitrido-bis(triphenylphosphorus)-(1+)], 26 284... [Pg.434]

PO]4Ru4C32H25, Ruthenium, undecacar-bonyl-tetrahydrido-[tris(4-methyl-phenyl)-phosphite]tetra-, 26 277 POsSC5 H47, Osmium(II), dihydrido(thio-carbonyl)tris(triphenylphosphine), 26 186... [Pg.437]

Potassium permanganate. Dimethyl sulfide-Chlorine. Dimethyl sulfoxide. Dimethyl sulfoxide-Chlorine. Dimethylsulf-oxide Sulfur trioxide. Dipyridine chro-mium(VI) oxide. Iodine. Iodine-Potassium iodide. Iodine tris(trifluoroacetate). Iodosobenzene diacetate. Isoamyl nitrite. Lead tetraacetate. Manganese dioxide. Mercuric acetate. Mercuric oxide. Osmium tetroxide—Potassium chlorate. Ozone. Periodic acid. Pertrifluoroacetic acid. Potassium ferrate. Potassium ferricyanide. Potassium nitrosodisulfonate. Ruthenium tetroxide. Selenium dioxide. Silver carbonate. Silver carbonate-Celite. Silver nitrate. Silver oxide. Silver(II) oxide. Sodium hypochlorite. Sulfur trioxide. Thalli-um(III) nitrate. Thallium sulfate. Thalli-um(III) trifluoroacetate. Triphenyl phosphite ozonide. Triphenylphosphine dibromide. Trityl fluoroborate. [Pg.297]

T riphenylphosphine—Diethyl azodi-carboxylate, 280, 645 Triphenylphosphine dibiomide, 645-646 Triphenylphosphine dichloride, 646-647 Triphenylphosphine dihaiides, 647-648 Triphenylphosphine diiodide, 648 Triphenylphosphine ditriflate, 648 Triphenylphosphite methiodide, 649 Triphenyl phosphite ozonide, 435 Triphenyl(prop-2-ynyl)phosphonium bromide, 494 Triphenylsilanol, 655, 656 Triphenylstannane, 649 Triphenyltin hydride, 649 Triphenylvinylsilane, 637 Triphosphopyridine nucleotide, 36-37 Tri- -propyl orthovanadate, 655 Tris-annelation, 410 Ttis(aquo)hexa-fi-acetato-p,-oxotri-ruthenium acetate, 425-426,650 Tris(dimethoxyboryl)methane, 328, 329 Tris(dimethylamino)borane, 554 Trishomocubanone, 108 Tris(neomenthyldiphenylphosphine)-chlororhodium, 416... [Pg.384]

H4O14PRU4C32H31, Ruthenium, undecacar-bonyltetrahydrido[tris(4-methyl-phenyl)phosphite]tetra-, 26 277,... [Pg.369]

See other pages where Tris phosphite, ruthenium is mentioned: [Pg.416]    [Pg.430]    [Pg.436]    [Pg.353]    [Pg.404]    [Pg.416]    [Pg.416]    [Pg.430]    [Pg.436]    [Pg.422]    [Pg.57]    [Pg.586]    [Pg.203]    [Pg.515]    [Pg.398]    [Pg.179]   


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