Trifluorochloroethylene

A. 0. Pozdnyakov, B. M. Ginzburg, 0. F. Pozdnyakov, B. P. Redkov, Desorption of fullerene C60 from a mixture with a copolymer of trifluorochloroethylene and vinylidene fluoride, Technical Physics Letters, vol. 2, pp. 51-53,1997. 

Numerous S -fluoroaryl or S -fluoroalkyl derivatives of cysteine have been described. Thus, fluorination of S -benzyl cysteine has been performed with XeFa- The photochemical trifluoromethylation of cysteine, or of its disulfide, affords optically pure S -trifluoromethyl cysteine. Some electrophilic halogenated compounds (such as trifluorochloroethylene) are able to achieve the 5-fluoroalkylation of cysteine. 

Nucleophilic fluoroalkylation in the anomeric position has been performed with trifluorochloroethylene, or with perfluorovinyl ethers." The compound obtained with trifluorochloroethylene is an irreversible inhibitor of a-glycosidases (Figure 6.44). " Trifluoromethylzinc bromide can be used to perform the difluor-omethylation of hydroxyls in various positions, probably through a carbenic mechanism. 

Trifluorochloroethylene. See 2-Chloro-1,1,2-trifluoroethylene and its polymer, Fluorothene, in this Section... 

Synonym Gamma-Chloropropylene Oxide 3-Chloro-1,2-Propylene Oxide Chlorosulfonic Acid Chlorothene Chiorotoluene, Alpha Alpha-Chlorotoluene Omega-Chlorotoluene Chlorotrifluoroethylene Chlorotrimethylsilane Chlorsulfonic Acid Clilorylen Clip Chromic Acid Chromic Anhydride Chromic Oxide Chromium (VI) Dioxychloride Chromium Oxychloride Chromium Trioxide Chromyl Chloride Cianurina Citric Acid Citric Acid, Diammonium Salt Clarified Oil Clorox Cc Ral Coal Tar Oil Cobalt Acetate Cobalt Acetate Tetrahydrate Cobalt (II) Acetate Cobalt Chloride Cobalt (II) Chloride Cobaltous Acetate Cobaltous Chloride Cobaltous Chloride Dihydrate Cobaltous Chloride Hexahydrate Cobaltous Nitrate Cobaltous Nitrate Hexahydrate Cobaltous Sulfate Heptahydrate Cobalt Nitrate Cobalt (II) Nitrate Cobalt Sulfate Compound Name Epichlorohydrin Epichlorohydrin Chlorosulfonic Acid Trichloroethane Benzyl Chloride Benzyl Chloride Benzyl Chloride Trifluorochloroethylene Trimethylchlorosilane Chlorosulfonic Acid Trichloroethylene Cumene Hydroperoxide Chromic Anhydride Chromic Anhydride Chromic Anhydride Chromyl Chloride Chromyl Chloride Chromic Anhydride Chromyl Chloride Mercuric Cyanide Citric Acid Ammonium Citrate Oil Clarified Sodium Hypochlorite Coumaphos Oil Coal Tar Cobalt Acetate Cobalt Acetate Cobalt Acetate Cobalt Chloride Cobalt Chloride Cobalt Acetate Cobalt Chloride Cobalt Chloride Cobalt Chloride Cobalt Nitrate Cobalt Nitrate Cobalt Sulfate Cobalt Nitrate Cobalt Nitrate Cobalt Sulfate... 

Fluorocarbon elastomers represent the largest group of fluoroelastomers. They have carbon-to-carbon linkages in the polymer backbone and a varied amount of fluorine in the molecule. In general, they may consist of several types of monomers poly-vinylidene fluoride (VDF), hexafluoropropylene (HFP), trifluorochloroethylene (CTFE), polytetrafluoroethylene (TFE), perfluoromethylvinyl ether (PMVE), ethylene or propylene.212 Other types may contain other comonomers, e.g., 1,2,3,3,3-pentafluropropylene instead of HFP.213 Fluorocarbon elastomers exhibit good chemical and thermal stability and good resistance to oxidation. 

If trifluorochloroethylene propagation is governed by a single a, then, regardless of temperature ... 

Poly(vinyl fluoride) Poly(vinyl chloride) Poly(trifluorochloroethylene) Poly(vinylidene fluoride)... 

TRIFLLXXOACETIC ACID TRIFLUOROBROHOHETHANE TRIFLUOROCHLOROETHYLENE TRIFLUOROETHANE TRIFLUORONETHANE... 

Tetrachloroethane (1,1,2,2-) Acetylene Tetrachloride Tetrachloroethane Chlorotrifluoroethylene Trifluorochloroethylene Trifluorovinylch bride Methacrylic Acid Methyl Acrylic Acid Dichloroacetic Acid Nitropropane (2-) Cam phene Hexene Noryl GFN3 Cumene Hydroperoxide Bromobutyric Acid (2-) Methyl Methacrylate Cedar Wood Oil Lavender Oil Terpineol Eucalyptus Oil Tung Oil Sunflower Oil Soybean Oil Linseed Oil Cottonseed Oil Corn Oil Coconut Oil Benzalkonium Chloride Zephiran Chloride Creosote Cod Liver Oil Ceresin Castor Oil Bone Oil Pine Oil Rapeseed Oil Spermaceti Sperm Oil Tall Oil Cocoa Butter Red Oil Turkey Red Oil Neats Foot Oil Johnsons V fex 111 Palm Oil Vidden D Dowtherm Dowtherm A Lanolin Sassafras Oil Sandalwood Oil Santal Oil Rose Oil Nutmeg Butter Nutmeg Oil Cedar Leaf Oil Terpinyl Acetate Coal Tar Tar... 

The increased solubility of vinyl polymers in solvents at elevated temperatures enables very high solids to be obtained for application techniques like hot airless spraying or curtain coating. Figure 33 illustrates this property with a vinyl chloride-trifluorochloroethylene copolymer at 25° to 95°C. Since the solubility of the resin improves with... 

Rempp and Franta [3] described the synthesis of macromonomers either by using redox catalysis with halogenated monomers (vinyl chloride, vinyl dichloride, or even trifluorochloroethylene) or by using a radical initiation with (meth)acrylates. In the latter case, thiol compounds were used as transfer agents (Scheme 46) [251] ... 

The high chemical reactivity of tetrafluoroethylene and also that of the safer trifluorochloroethylene permits smooth thermal biradical [2 + 2] cyclodimerisation or cycloadditions to C-C double or triple bonds. Useful fluorinated reagents are obtained, such as the trifluorochloro-cyclobutene esters arising from more facile... 

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