Lithium aluminum hydride-Cobalt chloride

Related Reagents. Lithium Aluminum Hydride-(2,2 -Bipy-ridyl)(l,5-cyclooctadiene)nickel Lithium Aluminum Hydride-Bis(cyclopentadienyl)nickel Lithium Aluminum Hydride-Boron Trifluoride Etherate Lithium Aluminum Hydride-Cerium(III) Chloride Lithium Aluminum Hydride-2,2 -Dihydroxy-l, E-binaphthyl Lithium Aluminum Hydride-Chromium(III) Chloride Lithium Aluminum Hydride-Cobalt(II) Chloride Lithium Aluminum Hydride-Copper(I) Iodide Lithium Aluminum Hydride-Diphosphoms Tetraiodide Lithium Aluminum Hydride-Nickel(II) Chloride Lithium Aluminum Hydride-Titanium(IV) Chloride Titanium(III) Chloride-Lithium Aluminum Hydride. [Pg.215]

The azidohydrins obtained by azide ion opening of epoxides, except for those possessing a tertiary hydroxy group, can be readily converted to azido mesylates on treatment with pyridine/methanesulfonyl chloride. Reduction and subsequent aziridine formation results upon reaction with hydrazine/ Raney nickel, lithium aluminum hydride, or sodium borohydride/cobalt(II)... [Pg.27]

REDUCTION, REAGENTS Aluminum amalgam. Borane-Dimethyl sulfide. Borane-Tetrahydrofurane. t-Butylaminoborane. /-Butyl-9-borabicyclo[3.3.1]nonane. Cobalt boride— f-Butylamineborane. Diisobutylaluminum hydride. Diisopropylamine-Borane. Diphenylamine-Borane. Diphenyltin dihydride. NB-Enantrane. NB-Enantride. Erbium chloride. Hydrazine, lodotrimethylsilane. Lithium-Ammonia. Lithium aluminum hydride. Lithium borohydride. Lithium bronze. Lithium n-butylborohydride. Lithium 9,9-di-n-butyl-9-borabicyclo[3.3.11nonate. Lithium diisobutyl-f-butylaluminum hydride. Lithium tris[(3-ethyl-3pentylK>xy)aluminum hydride. Nickel-Graphite. Potassium tri-sec-butylborohydride. Samarium(II) iodide. Sodium-Ammonia. Sodium bis(2-mcthoxyethoxy)aluminum hydride. [Pg.311]

Lithium aluminum hydride under moderate conditions does not cleave benzyl ethers. Allerton and Fletcher treated 1,4 3,6-dianhydro-2,5-di-0-benzyl-D-mannitol with an excess of lithium aluminum hydride in boiling tetrahydrofuran for six hours, and recovered the starting material in 82 % yield. The stability of the benzyloxy group to this reagent had previously been reported. Some caution should be exercised if vigorous conditions are employed. In the presence of cobaltous chloride, benzyl phenyl ether is hydrogenolyzed to a small extent by lithium aluminum hydride. Zinc dust-acetic acid is reported as not reacting with benzyl ethers. ... [Pg.153]

Many methods of reduction from azide to amine are available hydrogen with various metal catalysts, lithium aluminum hydride, or cobalt(II) chloride/sodium borohydride. [Pg.349]