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Transition metal ligands

As mentioned in Sect. 2.3, cleavage of the P-B bond is required prior to com-plexation with a transition-metal. The following section provides an example for the preparation of two rhodium complexes. Such synthesis, however, may be generalized to almost any other transition-metal/ligand complexes. [Pg.27]

Transition Metal-Ligand Complex Formation - Co(ll) Complexes... [Pg.563]

Armentrout, R B., Kickel, B. L., 1996, Gas-Phase Thermochemistry of Transition Metal Ligand Systems Reassessment of Values and Periodic Trends in Organometallic Ion Chemistry, Freiser, B. S. (ed.), Kluwer, Amsterdam. [Pg.279]

The electronic spectra of these materials recorded in chloroform solution appear to be dominated by intense bands originating from internal ligand transitions, metal-ligand and ligand-metal charge-transfer bands, whose intensities change markedly with changes in the population of the two spin states [7]. [Pg.284]

The determination of the heat capacity of a substance as a function of the temperature is by itself a very important application of DSC, because it may lead to values of the thermodynamic functions S%, //-" — //q, and Gy, mentioned in chapter 2. An example is the study of C6o carried out by Wunderlich and co-workers [271], The application of DSC in the area of molecular thermochemistry has been particularly important to investigate trends in transition metal-ligand bond dissociation enthalpies. The typical approach used in these studies, and its limitations, can be illustrated through the analysis of the reaction 12.27, carried out by Mortimer and co-workers [272] ... [Pg.183]

D. Brunei, N. Bellocq, P. Sutra, A. Cauvel, M. Lasperas, P. Moreau, F. Di Renzo, A. Galarneau, and F. Fajula, Transition-metal ligands bound onto the micelle-templated silica surface. Coord. Chem. Rev. 180, 1085-1108 (1998). [Pg.217]

Orgel, L. E., An Introduction to Transition Metal Ligand Field Theory, Methuen, London, 1960. [Pg.141]

The Met+—L bond dissociation energies were measured for some Zn-containing gas phase cations using different methods ". Armentrout reviewed guided ion beam studies of transition metal-ligand thermochemistry and reported the following... [Pg.180]

Compounds of transition metal complexes possessing a nonbonding electron pair with boranes (BX3) can be regarded classically as boron complexes with a transition metal ligand. In a broader sense, however, boranes can be classified as acceptor ligands.154,155 Thus, coordination of a borane results in a decrease of the electron density on the metal atom. In the case of carbonyl complexes this effect is reflected in the increase, by 20-100 cm-1, of the CO stretching frequency.154-156 It follows from the foregoing that stable coordination of boranes is... [Pg.100]

Trefoil Knots as Transition Metal Ligands -Specific Kinetic, Electrochemical, and Photochemical Properties... [Pg.129]

Atom transfer radical polymerization (ATRP) [52-55]. Active species are produced by a reversible redox reaction, catalyzed by a transition metal/ligand complex (Mtn-Y/Lx). This catalyst is oxidized via the halogen atom transfer from the dormant species (Pn-X) to form an active species (Pn ) and the complex at a higher oxidation state (X-Mtn+1-Y/Lx). [Pg.12]

Zhang, K., Gonzalez, A. A., Mukerjee, S. L., Chou, S.-J., Hoff, C. D., Kubat-Martin, K. A., Barnhar, D. and Kubas, G. J. (1991). Solution calorimetric and stopped-flow kinetic study of ligand substitution for the complexes M(CO)3(PCy)2(L) (M = Cr, Mo, W). Comparison of first-, second- and third-row transition-metal-ligand bonds at sterically-crowded metal centres, J. Am. Chem. Soc. 113, 9170. [Pg.442]


See other pages where Transition metal ligands is mentioned: [Pg.162]    [Pg.51]    [Pg.122]    [Pg.412]    [Pg.347]    [Pg.235]    [Pg.280]    [Pg.175]    [Pg.25]    [Pg.31]    [Pg.37]    [Pg.651]    [Pg.129]    [Pg.131]    [Pg.133]    [Pg.219]    [Pg.425]    [Pg.92]    [Pg.71]    [Pg.87]    [Pg.112]    [Pg.67]    [Pg.67]    [Pg.207]    [Pg.84]    [Pg.420]   
See also in sourсe #XX -- [ Pg.39 , Pg.124 , Pg.125 , Pg.126 , Pg.127 ]

See also in sourсe #XX -- [ Pg.144 ]




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2,6-Diacetylpyridine, transition metal ligands

About C Ligands in Transition Metal Complexes

Al-Heterocyclic Carbenes (NHCs) as Ligands in Transition-Metal-Catalyzed Hydroformylation

Bidentate ligands transition metals

Boron Heterocycles as Ligands in Transition-Metal Chemistry

Catenated Nitrogen Ligands Part Transition Metal Derivatives

Crown ether ligands, containing bipyridyl transition metal recognition

Crown ether ligands, containing bipyridyl transition metal recognition sites

Diazenido ligands, transition metal

Direct ligand addition, transition metal

Dynamic Behavior of d Transition Metal Complexes with n-Donor Two-Center Ligands

Germanium ligands transition metal complexes

Imido ligands transition metal complexes with

Isocyanides ligands, transition metal

Jafarpour. Laleh. and Nolan, Steven P Transition-Metal Systems Bearing a Nucleophilic Carbene Ancillary Ligand from Thermochemistry to Catalysis

Labile transition-metal ions, ligand

Labile transition-metal ions, ligand substitution

Laporte-allowed ligand-metal transitions

Ligand Effects for Transition Metal Oxides

Ligand Substitution in Transition Metal ir-Complexes

Ligand Substitution in Transition Metal w-Complexes

Ligand Substitution on Labile Transition-Metal Ions

Ligand substitution reactions transition metal complexes

Ligand-metal charge transfer LMCT) transitions

Ligand-to-metal charge transfer transitions LMCT)

Ligand-to-metal charge-transfer transition

Ligands in transition metal complexes

Ligands transition metal catalysis

Ligands with transition metals

Ligands, transition-metal oxidation

Macrocyclic ligands transition metal complexes

Mercury complexes transition metal ligands

Metal-ligand charge transfer transition MLCT)

Metal-ligand charge transfer transitions

Metal-to-ligand charge-transfer transition MLCT)

Mixed-ligand complexes, transition metal

Mixed-ligand complexes, transition metal chromium

Mixed-ligand complexes, transition metal group

Mixed-ligand complexes, transition metal structural studies

Monodentate ligands, transition metal

Monodentate ligands, transition metal mono

Monodentate ligands, transition metal structural studies

Multifunctional Transition Metal Ligands

Nitrogen ligands, transition metal

Nitrogen ligands, transition metal characterization

Nitrogen ligands, transition metal dithiocarbamate complexes

Organic ligand transfer between transition metals

Organic ligand transfer from transition metals to main group element

Oxygen insertion into transition metal-ligand bonds

Phosphine/phosphite ligands, transition metal

Polymeric ligands, transition metal polymer complexes

Self-Assembled Ligands in Transition Metal Catalysis

Silicon ligands transition metal complexes

Silicon-based ligands for transition metal

Silicon-based ligands for transition metal coordination

Site-Specific Internal Functionalization of Nucleic Acids with Transition-Metal Ligands and Other Moieties

Substitution of Ligands at the Transition Metal

The bonding of 1-electron ligands to transition metals

The bonding of 4-eIectron ligands to transition metals

The bonding of one-electron ligands to transition metals

Transition Metal Catalysts with Phosphine Ligands

Transition Metal Complexes Containing Anionic or Cationic Ligands

Transition Metal Complexes Containing Bidentate Phosphine Ligands

Transition Metal Complexes of Cyclopentadienyl Ligands

Transition Metal Complexes of Polydentate Amido Ligands

Transition Metal Complexes with CO, N2, NO and O2 Ligands

Transition Metal Compounds and Organic Ligands as Catalysts

Transition Metal Hydrocarbyl Ligands

Transition Metal Ions and their Complexes Ligand Field Theory

Transition ligand

Transition metal alkoxide complexes ligands

Transition metal catalyst ligands

Transition metal catalyst ligands 1,10-phenanthroline

Transition metal clusters of interstitial ligand

Transition metal clusters of terminal ligand

Transition metal clusters size of hydride ligand

Transition metal complexes bearing a phosphenium ligand

Transition metal complexes bridging ligands

Transition metal complexes carbonyl ligands stretching modes

Transition metal complexes containing all-carbon ligands

Transition metal complexes ligand electronic structure

Transition metal complexes ligand electrons

Transition metal complexes ligand site preferences

Transition metal ions ligand substitution

Transition metal ions ligand substitution reactions

Transition metal ligand contributions, electron counts

Transition metal ligands binds

Transition metal-ligand bond dissociation

Transition metal-ligand complex

Transition metal-ligand complex formation

Transition metal/ligand binding

Transition metals bispidine ligands

Transition metals elements ligands

Transition metals ligand activation

Transition metals ligand addition-dissociation reactions

Transition metals ligand bending

Transition metals ligand field stabilization energy

Transition metals ligand types

Transition metals ligands and

Transition metals salen ligands

Transition metals with organic ligands

Transition-metal coordination mechanisms anionic ligands

Transition-metal coordination mechanisms ligand field stabilization

Trefoil Knots as Transition Metal Ligands - Specific Kinetic, Electrochemical, and Photochemical Properties

Weak-field ligands, transition metal

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