Organic ligand transfer from transition metals to main group element

4 Organic ligand transfer from transition metals to main group element 

Alkylation of the Co complex by means of trimethylaluminum produces a cationic methylcobalt complex with an AlMeJ counterion (Eq. 5.36) [142]. 

The above reaction, which involves conversion of AlMea into AlMe, is attributed 

The organic ligand transfer from transition metal to main group metal is involved in stoichiometric and catalytic reactions shown below. A cuprate containing 2-(tributylstannyl)methoxyphenyl ligand is easily converted into 2-ethoxy-1-tributylstannylbenzene (Eq. 5.37) [143], 

The reactions of allylic compounds with aldehydes catalyzed by the Pd complex in the presence of main group metal compounds lead to allylation of the 

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