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Isomer trans

CgHgO, PhCH = CHCOiH. Colourless crystals. Decarboxylales on prolonged heating. Oxidized by nitric acid to benzoic acid. Ordinary cinnamic acid is the trans-isomer, m.p. 135-136 C on irradiation with u.v. light it can be isomerized to the less stable cis-isomer, m.p. 42" C. [Pg.100]

Me0>2P(0)0CMe = CHC02Me. A trade name for a highly active systemic insecticide both CIS and trans isomers are active. [Pg.306]

The Cyclooctene Isomerization. A reaction that attracted some attention in recent years is the cis-trans isomerization of cyclooctene [84]. The cis isomer is much less strained than the trans, but the latter is readily fonned upon direct photolysis and also upon photosensitization. In this case, two enantiomeric trans isomers are formed. The appropriate loop is a variation of that shown in Figure 14, as shown in Figure 34. This is a phase inverting i -type loop, that... [Pg.367]

Stereoisomerism at double bonds is indicated in SMILES by / and . The characters specify the relative direction of the connected atoms at a double bond and act as a frame. The characters frame the atoms of a double bond in a parallel or an opposite direction. It is therefore only reasonable to use them on both sides Figure 2-78). There are other valid representations of cis/trans isomers, because the characters can be written in different ways. Further details are listed in Section 2,3.3, in the Handbook or in Ref, [22]. [Pg.84]

The same reference unit of Figure 2-86 is also used here for the determination of the permutation descriptor of the trans isomer. In the same manner as above, wc write down the permutation matrices of the two structures, and then determine the transpositions (Figure 2-87),... [Pg.89]

Now Ictu.s see how the de.scriptor.s bcltavc under rotation of the entire molecule. 1 f the trans isomer used before is rotated by 1and the descriptors are calculated again, a value of (-1 is obtained two times (right-hand side, bottom line of Figure 2-88). [Pg.90]

Figure 2-88. The permutation matrices of the fragments of the rotated trans Isomers. The rotated structure (right-hand side) has two descriptors of (-1) whereas the initial structure (left-hand side) had two values of (-r 1). The overall descriptor of both sides is obtained by multiplication (+1)(+1) = (41) and (-1)(-1) = (41),... Figure 2-88. The permutation matrices of the fragments of the rotated trans Isomers. The rotated structure (right-hand side) has two descriptors of (-1) whereas the initial structure (left-hand side) had two values of (-r 1). The overall descriptor of both sides is obtained by multiplication (+1)(+1) = (41) and (-1)(-1) = (41),...
The object of this part of the project is to determine the energy ("enthalpy) levels in each the three con formers and so to determine the composition of the equilibrium conformational mixture. That having been done for the cis isomer, the procedure is repeated for the trans isomer. [Pg.166]

Sketch the molecules on graph paper to help in determining the atomic coordinates. This is the first use of molecular geometry, a property that will become increasingly important as we go on. At this stage, the geometries are approximate the difference, for example, between cis and trans isomer s is ignored. [Pg.258]

The direct connection of rings A and D at C l cannot be achieved by enamine or sul> fide couplings. This reaction has been carried out in almost quantitative yield by electrocyclic reactions of A/D Secocorrinoid metal complexes and constitutes a magnificent application of the Woodward-Hoffmann rules. First an antarafacial hydrogen shift from C-19 to C-1 is induced by light (sigmatropic 18-electron rearrangement), and second, a conrotatory thermally allowed cyclization of the mesoionic 16 rc-electron intermediate occurs. Only the A -trans-isomer is formed (A. Eschenmoser, 1974 A. Pfaltz, 1977). [Pg.262]

The pair of isomers designated as and trans 2 butene have the same constitution both have an unbranched carbon chain with a double bond connecting C 2 and C 3 They differ from each other however m that the cis isomer has both of its methyl groups on the same side of the double bond but the methyl groups m the trans isomer are on oppo site sides of the double bond Recall from Section 3 11 that isomers that have the same constitution but differ m the arrangement of their atoms m space are classified as stereoisomers as 2 Butene and trans 2 butene are stereoisomers and the terms as and trans specify the configuration of the double bond... [Pg.192]

Further insight into the E2 mechanism comes from stereochemical studies One such experiment compares the rates of elimination of the cis and trans isomers of 4 tert butyl cyclohexyl bromide... [Pg.216]

A good thing to remember is that the cis and trans isomers of a particular compound are diastereomers of each other... [Pg.303]

The CIS and trans isomers of 4 methylcyclohexanol are stereoisomers but they are not related as an ob ject and its mirror image they are diastereomers... [Pg.315]

Disubstituted cyclohexanes can exist as cis-trans isomers as well as axiaEequatorial conformers. Two isomers are predicted for 1,4-dimethylcyclohexane (see Fig. 1.9). For the trans isomer the diequatorial conformer is the energetically favorable form. Only one cis isomer is observed, since the two conformers of the cis compound are identical. Interconversion takes place between the conformational (equatoriaEaxial) isomers but not configurational (cis-trans) isomers. [Pg.42]

FIGURE 1.9 Two isomers of 1,4-dimethylcyclohexane. (a) Trans isomer (b) cis isomer. [Pg.43]

When two different substituents are attached to each carbon atom of the double bond, cis-trans isomers can exist. In the case of c T-2-butene (Fig. 1.11a), both methyl groups are on the same side of the double bond. The other isomer has the methyl groups on opposite sides and is designated as rran5--2-butene (Fig. l.llb). Their physical properties are quite different. Geometric isomerism can also exist in ring systems examples were cited in the previous discussion on conformational isomers. [Pg.43]

When the asymmetric carbon atoms in a chiral compound are part of a ring, the isomerism is more complex than in acyclic compounds. A cyclic compound which has two different asymmetric carbons with different sets of substituent groups attached has a total of 2 = 4 optical isomers an enantiometric pair of cis isomers and an enantiometric pair of trans isomers. However, when the two asymmetric centers have the same set of substituent groups attached, the cis isomer is a meso compound and only the trans isomer is chiral. (See Fig. 1.15.)... [Pg.47]

FIGURE 1.15 Isomers of cyclopropane-1,2-dicarboxyUc acid, (a) Trans isomer b) meso isomer. [Pg.48]

Figure 1.3 shows several repeat units of cis-l,4-polyisoprene and trans-1,4-polyisoprene. Natural rubber is the cis isomer of 1,4-polyisoprene, and gutta-percha is the trans isomer. [Pg.28]

In the two polyisoprene isomers, the length of the repeat unit and the steric hindrance factor vary oppositely for the two isomers. The greater end-to-end distance in the trans isomer is the dominant influence on the order of 1q values. [Pg.62]

Hydrogenation of polybutadiene converts both cis and trans isomers to the same linear structure and vinyl groups to ethyl branches. A polybutadiene sample of molecular weight 168,000 was found by infrared spectroscopy to contain double bonds consisting of 47.2% cis, 44.9% trans, and 7.9% vinyl. After hydrogenation, what is the average number of backbone carbon atoms between ethyl side chains ... [Pg.67]

Examples of prolate near-symmetric rotors are the s-trans and s-cis isomers of crotonic acid, shown in Figure 5.8, the a axis straddling a chain of the heavier atoms in both species. The rotational term values for both isomers are given approximately by Equation (5.37) but, because A and B are different for each of them, their rotational transitions are not quite coincident. Figure 5.9 shows a part of a low-resolution microwave spectmm of crotonic acid in which the weaker series of lines is due to the less abundant s-cis isomer and the stronger series is due to the more abundant s-trans isomer. [Pg.117]

Ma.nufa.cture. Butenediol is manufactured by partial hydrogenation of butynediol. Although suitable conditions can lead to either cis or trans isomers (111), the commercial product contains almost exclusively iVj -2-butene-l,4-diol Trans isomer, available at one time by hydrolysis of l,4-dichloro-2-butene, is unsuitable for the major uses of butenediol involving Diels-Alder reactions. The Hquid-phase heat of hydrogenation of butynediol to butenediol is 156 kj/mol (37.28 kcal/mol) (112). [Pg.107]

The reaction has been extended to include carbanions generated from phosphonates. This is often referred to as the Horner-Wittig or Homer-Emmons reaction. The Horner-Emmons reaction has a number of advantages over the conventional Wittig reaction. It occurs with a wider variety of aldehydes and ketones under relatively mild conditions as a result of the higher nucleophilicity of the phosphonate carbanions. The separation of the olefinic product is easier due to the aqueous solubility of the phosphate by-product, and the phosphonates are readily available from the Arbusov reaction. Furthermore, although the reaction itself is not stereospecific, the majority favor the formation of the trans olefin and many produce the trans isomer as the sole product. [Pg.471]

Conditions of hydrogenation also determine the composition of the product. The rate of reaction is increased by increases in temperature, pressure, agitation, and catalyst concentration. Selectivity is increased by increasing temperature and negatively affected by increases in pressure, agitation, and catalyst. Double-bond isomerization is enhanced by a temperature increase but decreased with increasing pressure, agitation, and catalyst. Trans isomers may also be favored by use of reused (deactivated) catalyst or sulfur-poisoned catalyst. [Pg.126]

Cydohexanedimethanol, 1,4- dim ethyl o1 cycl oh exa n e, or 1,4-bis (hydroxymethyl) cyclohexane (8), is a white, waxy soHd. The commercial product consists of a mixture of cis and trans isomers (6). This diol is used in the manufacture of polyester fibers (qv) (64), high performance coatings, and unsaturated polyester molding and laminating resins (5). [Pg.374]

Selenourea [630-10-4] ]5k.e urea and thiomea can form channel inclusion compounds (87) with a variety of hydrocarbons. Though the difference in channel diameter between thiourea and selenourea is small, selenourea seems to be much more selective for the inclusion of certain guest molecules (eg, cis/trans isomers). [Pg.69]


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1,2-Cyclopentanediol trans isomer

1,3-Pentadiene, trans isomer

1,3-Pentadiene, trans isomer polymerization

1.3.5- Hexatriene cis-trans isomers

1.6- Dimethylcyclohexene trans isomer

2-Cyclohexenone trans isomer

3- Hexene trans isomer

4-tert-Butyl cyclohexyl bromide trans isomers

Absorption spectra of a cis-trans isomer pair

And cis/trans isomers

Azobenzene trans isomer

Cis and trans geometrical isomers

Cis to trans isomer

Cis-trans Isomers requirements for

Cis-trans isomer ratio in clomiphene citrate

Cis-trans isomers of alkenes

Cis-trans isomers of coordination compounds

Cis-trans isomers, of cycloalkanes

Cis/trans isomers

Cis/trans isomers, also

Configurations of cis-trans isomers

Conformation measurement trans isomer

Cyclopentane trans isomer

Cypermethrin trans isomers

Decalin trans isomer

Designating the Configuration of Cis-Trans Isomers

Diamminedichloroplatinum trans isomers

Diastereomers and cis/trans isomers

Fatty acids trans isomers

Geometric isomers trans

Isomers cis-trans isomerism

Nomenclature of cis-trans isomers

Polyacetylene trans isomer

Separation of the Cis and Trans Isomers

Shortening, trans isomers

Stereoisomers trans isomer

Synthesis of cis-trans isomers

The E-Z Convention for Cis- Trans Isomers

Trans isomer specific isomers

Trans isomers of 2-butene

Trans isomers of cycloalkanes

Trans isomers properties

Trans isomers, of alkenes

Trans- isomer Subject

Trans- isomer definition

Trans- s. Isomers

Trans- s. Isomers Rearrangement

Trans-isomers platinum complexes

Trans-isomers symmetry properties, 64

Trans-isomers, of lycopene

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