Tolu amide

Kelly MG et al Comparative carcinogenic-ity of -isopropyl- -(2 -methylhydrazino)-p-tolu-amide HCl (procarbazine hydrochloride), its degradation products, other hydrazines, and isonicotinic acid hydrazide. J Natl Cancer Inst 42 337-344, 1969... 

Baynes, R.E., Hailing, K.B., Riviere, J.E, 1997. The influence of diethyl-m-tolu-amide (DEET) on the percutaneous absorption of permethrin and carbaryl. Toxicol. Appl. Pharmacol. 144, 332-339. 

Amine B.P. M.P. Acetamide Benz- amide Benzene- sulphon- amlde /)-Tolu- enesul- phon- amlde Benzal Derivative Pi crate 3-Nltro- phthal- Imlde 2 4- Dlnltro- phenyl Derivative Formyl Derivative Phenyl thio- urea... 

Bento amide Benzene- sulphon- amide p-Tolu- enesul- phon- amide Plcrate Formyl Derivative Other Derivatives... 

Upon warming with 10-20 per cent, sodium or potassium hydroxide solution, no ammonia is evolved (distinction from primary amides). The base, however, is usually liberated upon fusion with soda lime (see experimental details in Section IV,175) and at the same time the acyl group yields a hydrocarbon. Thus benz-p-toluidide affords p-tolu-idine and benzene. 

Benzoic acid in the free state, or in the form of simple derivatives such as salts, esters, and amides, is widely distributed in nature. Gum benzoin (from styrax ben in) may contain as much as 20% benzoic acid in the free state or in combinations easily broken up by heating. Acaroid resin (from anthorrhoca haslilis) contains from 4.5 to 7%. Smaller amounts of the free acid are found in natural products including the scent glands of the beaver, the bark of the black cherry tree, cranberries, pmnes, ripe cloves, and oil of anise seed. Pern and Tolu balsams contain benzyl benzoate the latter contains free benzoic acid as well. The urine of herbivorous animals contains a small proportion of the glycine derivative of benzoic acid, hippuric acid [495-69-2] (CgH CONHCH2COOH). So-called natural benzoic acid is not known to be available as an item of commerce. 

N-Substituted quinoxalines are obtained from N-substituted o-phenylenediamines. Thus methyl 2,3-dibromopropionate condenses with (V,A -bis(/7-toluenesulfonyl)-o-phenylenediamine to give l,4-bis(p-tolu-enesulfonyl)-2-methoxycarbonyl-1,2,3,4-tetrahydroquinoxaline (20).25 AVV -Disubstituted cyclohexane-1,2-diamines with suitable a/7-dihalides yield decahydroquinoxalines.26 Condensation of cyclohexane- 1,2-diones with glycine amide gives 2-oxo-5,6,7,8-tetrahydroquinoxalines.27... 

P-HYDROXY amides (S)-(—)-Menthyl p-tolu-cnesulfinate. (R)-(a-p-Tolylsulfinyl)-N,N-dimethylamide. 

Isomerization, see also NaphthaIene-2,6-dicarboxylic acid, preparation Aldqximes — Amides Nickel acetate tetrahydrate. Dienes Phenylpotassium. Epoxides Lithium diethylamide. Magnesium bromide etherate. Nonconjuoateo enones p-Tolu iesulfonic acid. Olefins (cis-trans)-. Iodine. Selenium. Olefins (bond migration) N-Lithioethylenediamine. Lithium diethylamide. Potassium l-butoxide. Sodium tetrafluoroboric s d. Thioglycolic acid. Polyenes Sulfur dioxide. 

Reaction of A-aminopyridinium salts with cyclopropenones (but not diphenylcyclopropenone) <75JOC2985>, or A-(/7-toluenesulfonyl)diphenylcyclopropenimine, afforded 3-oxo- and 3-(Al-/ -tolu-enesulfonylimino)-4// derivatives of (9) <78JOC2892, 84H(22)1709>. Similar reaction from iso-quinolinium A-amides gave derivatives of the 5,6-benzologue of (9) <83JOC1084>. 

No Name Mcliing poinl C Sulfonic acid Amide Anilide S Bcn/yl ihiu p-Tolui dme Aniline 0-Tolu< dine Miscellaneous... 

CAS 80-39-7 1077-56-1 EINECS/ELINCS 201-275-1 214-073-3 Synonyms N-Ethyl-p-methylbenzene sulfonamide N-Ethyltoluene-2-sul-fonamide Ethyl p-toluenesulfonamide Ethyl to amide (INCI) p-Tolu-ene ethylsulfonamide N-Tosyl ethylamine Classification Mixture of isomers of aromatic amides En firical CsHnNOjS Formula C2H5NHS02CeH,CH,... 

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