Thermosets samples

Let us consider the case of tensile loading of a thermoset sample in the glassy state (typical Poisson s ratio v 0.40). Tension in the elastic domain leads to a small swelling that contributes to the free volume. The corresponding free volume fraction is... 

Phenol resins are generally identified by liberating phenol om ttie thermosetting sample by heat or hydrolysis and then applying rapid tests for it 24,9i) J ov, ever, detailed information about the presumed type of phenoplast can be obtained only by its thermal breakdown into the structural units and their separation and identification by or This led to the discovery fliat the pyrolysis... 

Sample Preparation Careful sample preparation is the first step to obtaining good data on thermosets. Sample preparation must account for the fact that these materials are reactive, and care must be taken to avoid... 

Softening and cure is examined with the help of a torsional pendulum modified with a braid (65), which supports thermosets such as phenoHcs and epoxies that change from a Hquid to a soHd on curing. Another method uses vibrating arms coupled to a scrim-supported sample to measure storage and loss moduH as a function of time and temperature. An isothermal analytical method for phenoHc resins provides data regarding rate constants and activation energies and allows prediction of cure characteristics under conditions of commercial use (47). 

The commercial possibiUties for epoxy resins were first recognized by DeTrey Emres in Switzerland and DeVoe and Raynolds in the United States (1,2). In 1936, DeTrey Emres produced a low melting bisphenol A-based epoxy resin that gave a thermoset composition with phthaUc anhydride. Apphcation of the hardened composition was foreseen in dental products, but initial attempts to market the resin were unsuccessful. The patents were hcensed to CIBA AG of Basel, Switzerland (now CIBA-GEIGY), and in 1946 the first epoxy adhesive was shown at the Swiss Industries Eair and samples of casting resin were offered to the electrical industry. 

Specification for 600/1000V and 1900/3300 V armoured electric cables having thermosetting insulation Fire resisting characteristics of electric cables Performance requirements, sample and lest conditions - BS 5467/1997... 

Description of samples tested, specific test methods used, exposure medium notes, solubility parameters, and other important details are provided. Emphasis is on providing all relevant information so the most informed conclusions and decisions can be made by the user. Over 60,000 individual entries (specific tests) are covered in the database. Classes of materials covered include thermosets, thermosetting elastomers, thermoplastics, and thermoplastic elastomers. Approximately 700 different trade name and grade combinations representing over 130 families of materials are included. Over 3300 exposure environments are represented. 

At constant conditions, different fluids will diffuse at different rates into a particular elastomer (with their rates raised proportionally by increasing the exposed area), and each will reach the far elastomer-sample surface proportionally more rapidly with decreasing specimen thickness. Small molecules usually diffuse through an elastomer more readily than larger molecules, so that, as viscosity rises, diffusion rate decreases. One fluid is likely to diffuse at different rates through different elastomers. Permeation rates are generally fast for gases and slow for liquids (and fast for elastomers and slow for thermoplastics and thermosets). 

For comparative isothermal aging studies, all the samples of pure BCB and dlcyanate monomers, as well as their 1 1 molar mixtures, were cured in a single batch at 200-220°C for 40 hours under nitrogen atmosphere. The cured samples of BADCy, METHYLCy, and THIOCy were all transparent and yellow/amber, and their blends with BCB were also transparent but dark red in color. The cured sample of BCB was translucent and yellow. The Tg s (cure) of the thermosets derived from the dlcyanate monomers are relatively high, 224°-261°C as determined by thermomechanical analysis (TMA). There Is an increase of 10-31°C in Tg (cure) values in their blends with BCB. The ITGA results of the cured samples of BCB,... 

This paper reports the results of a molecular-level investigation of the effects of flame retardant additives on the thermal dedompositlon of thermoset molding compounds used for encapsulation of IC devices, and their implications to the reliability of devices in molded plastic packages. In particular, semiconductor grade novolac epoxy and silicone-epoxy based resins and an electrical grade novolac epoxy formulation are compared. This work is an extension of a previous study of an epoxy encapsulant to flame retarded and non-flame retarded sample pairs of novolac epoxy and silicone-epoxy compounds. The results of this work are correlated with separate studies on device aglng2>3, where appropriate. 

Ethylbenzene has been shown to migrate at levels of < 6-34 pg/kg Ifom samples of thermoset polyester (containing up to 25 mg/kg ethylbenzene) into pork during cooking (Gramshaw Vandenburg, 1995). 

Differential Scanning Calorimetry (DSC) This is by far the widest utilized technique to obtain the degree and reaction rate of cure as well as the specific heat of thermosetting resins. It is based on the measurement of the differential voltage (converted into heat flow) necessary to obtain the thermal equilibrium between a sample (resin) and an inert reference, both placed into a calorimeter [143,144], As a result, a thermogram, as shown in Figure 2.7, is obtained [145]. In this curve, the area under the whole curve represents the total heat of reaction, AHR, and the shadowed area represents the enthalpy at a specific time. From Equations 2.5 and 2.6, the degree and rate of cure can be calculated. The DSC can operate under isothermal or non-isothermal conditions [146]. In the former mode, two different methods can be used [1] ... 

Thermal stability as measured by these ramped TGA experiments of the sort previously described are not the definitive test of a polymer s utility at elevated temperature. Rather, for a polymer to be useful at elevated temperatures, it must exhibit some significant retention of useful mechanical properties over a predetermined lifetime at the maximum temperature that will be encountered in its final end use application. While many of the bisbenzocyclobutene polymers have been reported in the literature, only a few have been studied in detail with regards to their thermal and mechanical performance at both room and elevated temperatures. Tables 7-10 show some of the preliminary mechanical data as well as some other physical properties of molded samples of polymers derived from amide monomer 32, ester monomer 40, diketone monomer 14 and polysiloxane monomer 13. The use of the term polyamide, ester etc. with these materials is not meant to imply that they are to be regarded as merely modified linear thermoplastics. Rather, these polymers are for the most part highly crosslinked thermosets. 

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