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Thermodynamics polymer

Higaki, Y Otsuka, H. Takahara, A. A thermodynamic polymer cross-linking system based on radically exchangeable covalent bonds. Macromolecules 2006, 39, 2121-2125. [Pg.259]

Chemical process rate equations involve the quantity related to concentration fluctuations as a kinetic parameter called chemical relaxation. The stochastic theory of chemical kinetics investigates concentration fluctuations (Malyshev, 2005). For diffusion of polymers, flows through porous media, and the description liquid helium, Fick s and Fourier s laws are generally not applicable, since these laws are based on linear flow-force relations. A general formalism with the aim to go beyond the linear flow-force relations is the extended nonequilibrium thermodynamics. Polymer solutions are highly relevant systems for analyses beyond the local equilibrium theory. [Pg.680]

Extensive databases for thermodynamic polymer properties are now available ... [Pg.698]

According to the second law of thermodynamics, polymer pairs will be miscible if the Gibbs free energy of mixing AG is negative. The AG may be described by the following three contributions [9-11] ... [Pg.353]

Converted and interpolated from Thermodynamic Polymers Limited, 1993. Reproduced by permission. Ty-= bubble-point temperature T. 233.15 K =-40 °C. [Pg.326]

Several topics that illustrate the relationships between thermodynamics, polymer structure and polymer crystalline are given below. [Pg.155]

Nishio, Y., Hratani, T., Takahashi, T., and Manley, R- S., 1989, Cellulose/Poly(vinyl alcohol) blends an estimation of thermodynamic polymer-polymer interaction by melting point depression analysis Macromolecules. 22 2547-2549... [Pg.99]

In 2004, a comprehensive volume was edited by Utracki that provides a thorough description of the thermodynamics, polymer mechanics, and composite mechanics of clay-containing polymer nanocomposites [69]. In 2012, Woodhead Publishing led by editor Gao published an extensive review of recent advances in polymer nanocomposites [80]. Chapter 11 of that book describes in detail the progress made in the manufacture and characterization of thermoplastic... [Pg.330]

Consider now polymer-based materials from the point of view of a materials user. A user can be an industrialist who buys truckloads of polymer-based components for his plant, a housewife, a little girl playing with a plastic doll—in fact anybody. The user typically has no interest (and little knowledge) of chemical synthesis of polymers, thermodynamics, polymer processing—in fact of any... [Pg.4398]

Enel Cells, Principles and Thermodynamics Polymer Electrolyte Fuel Cells,... [Pg.1683]

Spectroscopic Methods.—Nuclear Magnetic Resonance (n.m.r.). Cohen-Addad and Ruby comment that thermodynamic polymer-solvent interaction parameters obtained from n.m.r. data should be contrasted with those obtained from other methods in the sense that the former are defined on a molecular scale only. That is, nuclear spins are local probes, sensitive to magnetic interactions averaged over volumes of molecular size. N.m.r. methods, therefore, usefully complement other methods in studying underlying statistical mechanical models for polymer-solvent mixtures at equilibrium a comment which has been amplified in relation to polymer blends. ... [Pg.316]

The same as classic thermodynamics, polymer thermodynamics is function of pressure, temperature and composite. But in many cases, pressure effects on polymer thermodynamics was neglected, because polymer thermodynamics were often studied under atmosphere. The classic theory of polymer thermodynamics is Flory-Huggins hard lattice theory. In this theory, the hard lattice is incompressible. A rigorously incompressible system should be unaffected by pressure. However, since experimental results show that the critical temperature for polymer demixing system is strongly affected by pressure, it is clear that polymer containing systems show significant departures from this ideal limit. We wish... [Pg.219]


See other pages where Thermodynamics polymer is mentioned: [Pg.83]    [Pg.249]    [Pg.76]    [Pg.648]    [Pg.4]    [Pg.12]    [Pg.10]    [Pg.280]    [Pg.376]   
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See also in sourсe #XX -- [ Pg.364 ]

See also in sourсe #XX -- [ Pg.132 ]




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Approaches to Polymer Solution Thermodynamics

Blended polymers miscibility studies, thermodynamics

Calorimetry polymer thermodynamics

Ceiling temperature polymer thermodynamics

Chain polymerization polymer thermodynamics

Chemical reaction polymer thermodynamics

Differential scanning calorimetry polymer thermodynamics

Dilute polymer solutions thermodynamics

Endothermic reaction, polymer thermodynamics

Enthalpy polymer thermodynamics

Entropy polymer thermodynamics

Equations polymer thermodynamics

First-order transitions polymer thermodynamics

Flory-Huggins interaction parameter blended polymer thermodynamics

Flory-Huggins interaction parameter polymer solution thermodynamics

Flory-Huggins theory polymer thermodynamics, crystalline

Free enthalpy, polymer thermodynamics

Gibbs function, polymer thermodynamics

Glassy polymers, thermodynamic

Heat capacity polymer thermodynamics

Interaction parameters, miscibility, blended polymer thermodynamics

Intermolecular interactions, miscibility, blended polymer thermodynamics

Interpenetrating polymer network thermodynamics

Kinetics polymer thermodynamics

Liquid Polymers surface thermodynamics

Melting-transition temperature polymer thermodynamics, first-order

Molecularly imprinted polymers thermodynamic considerations

Multicomponent polymers thermodynamics

Multiscale Modeling and Coarse Graining of Polymer Dynamics Simulations Guided by Statistical Beyond-Equilibrium Thermodynamics

Non-equilibrium Thermodynamics of Polymer Crystallization

Nucleation, polymer crystallization thermodynamics

Of polymers, thermodynamics

Phase equilibrium thermodynamics, polymer

Physical properties, polymer thermodynamics

Polymer HPLC thermodynamics

Polymer Solutions and Thermodynamics

Polymer blends phase separation thermodynamics

Polymer blends thermodynamics

Polymer brushes thermodynamic properties

Polymer catalyst thermodynamic properties

Polymer fluids Wertheim thermodynamic perturbation

Polymer fluids first-order thermodynamic perturbation

Polymer solubility, thermodynamic models

Polymer solution thermodynamics binodal curve

Polymer solution thermodynamics enthalpy

Polymer solution thermodynamics entropy

Polymer solution thermodynamics phase diagrams

Polymer solution thermodynamics solubility parameters

Polymer solution thermodynamics spinodal curve

Polymer solution thermodynamics spinodal decomposition

Polymer thermodynamic

Polymer thermodynamic modelling

Polymer-micelle complexes Thermodynamics

Polymers miscibility, solution thermodynamics

Polymers thermodynamic aspects

Polymers thermodynamic “state

Polymers thermodynamically immiscible

Polymers, dissolution Thermodynamics

Polymers, formaldehyde Thermodynamic

Polymers, thermodynamic crosslinking

Pressure polymer thermodynamics

Ring opening metathesis polymerization polymer thermodynamics

Semicrystalline polymers thermodynamics

Simha-Somcynsky theory, polymer thermodynamics

Solubility of polymers thermodynamics

Statistical thermodynamics of associating polymers

Statistical thermodynamics of polymer

Statistical thermodynamics of polymer crystallization

Surface Thermodynamics of Liquid Polymers

Temperature dependence polymer thermodynamics

The Mesoscopic Non-Equilibrium Thermodynamics Approach to Polymer Crystallization

The Thermodynamic Basis of Polymer Solubility

The Thermodynamics of Polymers Dissolution

The thermodynamics of polymer solutions

Thermodynamic Relations for Dilute Polymer Solutions

Thermodynamic behavior of polymer

Thermodynamic behavior of polymer solutions

Thermodynamic diffusion coefficient, polymer

Thermodynamic diffusion coefficient, polymer transport properties

Thermodynamic equilibrium melting temperature of polymer crystals

Thermodynamic interaction between polymer and surface

Thermodynamic model, polymer solution

Thermodynamic parameters polymer catalysts

Thermodynamic properties Polymer-solvent interactions

Thermodynamic properties polymers

Thermodynamic view, adsorption polymers

Thermodynamics and Kinetics of Polymer Crystallization

Thermodynamics high temperature polymer blends

Thermodynamics liquid crystal polymer blends

Thermodynamics of Flexible and Rigid Rod Polymer Blends

Thermodynamics of Heterogeneous Flexible Chain Polymer Solutions

Thermodynamics of Polymer Crystallization

Thermodynamics of Polymer Solutions Flexible Chains

Thermodynamics of Semidilute Polymer Solutions

Thermodynamics of high temperature polymer blends

Thermodynamics of polymer mixtures

Thermodynamics of polymer solutions

Thermodynamics of polymer-clay interactions

Thermodynamics of rodlike polymer solutions

Thermodynamics polymer adsorption

Thermodynamics polymer glass formation

Thermodynamics polymer systems

Thermodynamics, of polymer blends

Thermodynamics, polymer crystal nucleation

Thermodynamics, polymer phase separations

Thermodynamics, polymer solution

Transition properties polymer thermodynamics

Volume polymer thermodynamics

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