Thermodynamic properties of oxides

Brewer, L., Chem. Rev., 1952,52, 1 (a comprehensive survey of thermodynamic properties of oxides). 

ROG/KOZ] Rog, G., Kozlowska-R6g, A., Divalent ion-P"-alumina electrolytes for the study of thermodynamic properties of oxide systems, Z Phys. Chem. (Munich), 207, (1998), 83-92. Cited on pages 243, 244,436, 437. 

Brewer, L. Thermodynamic Properties of Oxides and Their Vaporization Processes, Chem. Revs., 52(1) 1 (1953). 

Tad/e 69. Phase Change Thermodynamic Properties OF Oxides (sheet 5 of 10)... 

Table 1. Physical and Thermodynamic Properties of Helium-Group Gas Fluorides, Oxofluorides, and Oxides...

E. A. Brandes and R. E. Flint, Manganese Phase Diagrams, The Manganese Centre, Paris, 1980 L. B. Pankratz, Thermodynamic Properties of Elements and Oxides, Bull. 672, U.S. Bureau of Mines, Washington, D.C., 1982. 

Thermodynamic. Thermodynamic properties of Pu metal, gaseous species, and the aqueous ions at 298 K are given in Table 8. Thermodynamic properties of elemental Pu (44), of alloys (68), and of the gaseous ions Pu", PuO", PuO" 27 PuO 2 (67) have been reviewed, as have those of aqueous ions (64), oxides (69), haUdes (70), hydrides (71), and most other compounds (65). 

The thermodynamic properties of sulfur trioxide, and of the oxidation reaction of sulfur dioxide are summarized in Tables 3 and 4, respectively. Thermodynamic data from Reference 49 are beheved to be more accurate than those of Reference 48 at temperatures below about 435°C. 

The physical and thermodynamic properties of elemental hydrogen and deuterium and of their respective oxides illustrate the effect of isotopic mass differences. 

The values given in the following table for the heats and free energies of formation of inorganic compounds are derived from a) Bichowsky and Rossini, Thermochemistry of the Chemical Substances, Reinhold, New York, 1936 (h) Latimer, Oxidation States of the Elements and Their Potentials in Aqueous Solution, Prentice-Hall, New York, 1938 (c) the tables of the American Petroleum Institute Research Project 44 at the National Bureau of Standards and (d) the tables of Selected Values of Chemical Thermodynamic Properties of the National Bureau of Standards. The reader is referred to the preceding books and tables for additional details as to methods of calculation, standard states, and so on. 

The thermodynamic properties of the solid silicates show the expected entropy change of formation from the constituent oxides of nearly zero, which is typical of the reaction type... 

The acid-base classificationd l turns essentially on the thermodynamic properties of hydroxides in aqueous solution, since oxides themselves are not soluble as such (p. 630). Oxides may be ... 

Wicks, C. E. and Block, F. E. "Thermodynamic Properties of 65 Elements - Their Oxides, Halides, Carbides, and Nitrides", Bureau of Mines, Bulletin 605, 1963. 

At present, intercalation compounds are used widely in various electrochemical devices (batteries, fuel cells, electrochromic devices, etc.). At the same time, many fundamental problems in this field do not yet have an explanation (e.g., the influence of ion solvation, the influence of defects in the host structure and/or in the host stoichiometry on the kinetic and thermodynamic properties of intercalation compounds). Optimization of the host stoichiometry of high-voltage intercalation compounds into oxide host materials is of prime importance for their practical application. Intercalation processes into organic polymer host materials are discussed in Chapter 26. 

When the metal can form a stable carbide, the product of the carbothermic reduction of its oxide may be a carbide instead of the metal itself. The question as to whether a carbide or the metal forms under standard conditions when the oxide is reduced by carbon is not answered by the Ellingham diagram. To obtain an answer to this question, a more detailed consideration of the thermodynamic properties of the system is necessary. 

Meyer RE, Arnold WD, Case FI, O Kelly GD (1988) Thermodynamic properties of Tc(IV) oxides solubilities and the electrode potential of the Tc(VII)/Tc(IV) oxides couple NUREG/CR-5108 ORNL-6480... 

NO reduction by CO, 28 162 olefin oxidation, 27 241,242 water-gas shift, 28 118,119 coordination number, 30 265 -copper alloy, 26 75 -copper alloy films thermodynamic properties of, 22 118 -copper oxide, 27 90,91 -manganese oxide, 27 91,92... 

Levitskii V. A., Golovanova Yu. G., Popov S. G., and Chentsov V. N. (1975). Thermodynamics of binary oxide system Thermodynamic properties of nickel orthosilicate. Russ. J. Phys. Chem., 49 971-974. 

Diakonov, G.G. (1998) Thermodynamic properties ofiron oxides and hydroxides. II. Estimation of the surface and bulk thermodynamic properties of ordered and disordered arrangements (y-Fe203). Eur. J. Min. 10 17-29... 

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