Thermal Finishing

Textile substrates are coated in two process steps. First a liquid, tenacious viscous, molten, or powder mass of plastic is applied on a substrate. Subsequently, a consolidation of the plastic coat takes place into a closed film, which forms a permanently bonded material with the substrate. Coating plants therefore consist of the segment s unroll stand, application device, drying or gelling channel, and take-up unit with a possible preceding cooling device (Fig. 9.10). 

The coating mass can be applied directly on the substrate (direct coating) or is transferred by means of an intermediate substrate (transfer coating or reversal process). The decision of which coating process to use depends on the require- 

In the continuous process, for example, special coating plants with blade or doctor knife systems provide the backs of high-quality web carpets with a plastic film. For automobile upholstery the fabric covers are laminated with foam material by heating up the foam and pressing the upholstery fabric against it. During the production of textile wallpapers the fabric lamination takes place, for example, as the decoration fabric is pasted automatically with a paper layer so that it can be attached by paste on walls. 

---

Finishing. AH acetal resins contain various stabilizers introduced by the suppHer in a finishing extmsion (compounding) step. The particular stabilizers used and the exact method of their incorporation are generally not revealed. Thermal oxidative and photooxidative stabilizers have already been mentioned. These must be carefully chosen and tested so that they do not aggravate more degradation (eg, by acidolysis) than they mitigate. 

Replacement of Labile Chlorines. When PVC is manufactured, competing reactions to the normal head-to-tail free-radical polymerization can sometimes take place. These side reactions are few ia number yet their presence ia the finished resin can be devastating. These abnormal stmctures have weakened carbon—chlorine bonds and are more susceptible to certain displacement reactions than are the normal PVC carbon—chlorine bonds. Carboxylate and mercaptide salts of certain metals, particularly organotin, zinc, cadmium, and antimony, attack these labile chlorine sites and replace them with a more thermally stable C—O or C—S bound ligand. These electrophilic metal centers can readily coordinate with the electronegative polarized chlorine atoms found at sites similar to stmctures (3—6). 

Operating parameters of this German plant, on the basis of one cubic meter of raw gas, iaclude 0.139 m O2, 0.9 kg briquettes, 1.15 kg steam, 1.10 kg feed water, 0.016 kWh, and 1.30 kg gas Hquor produced. Gasifier output is 1850 m /h and gas yield is 1465 m /t dry, ash-free coal. The coal briquettes have a 19% moisture content, 7.8% ash content (dry basis), and ash melting poiat of 1270°C. Thermal efficiency of the gas production process is about 60%, limited by the quaHty and ash melting characteristics of the coal. Overall efficiency from raw coal to finished products is less than 50%. 

Smooth surfaces are normally estabflshed by calendering, a process which subjects the fabric at the nip point(s) of two or more roUs to the influence of controlled time, temperature, and pressure. When calendering is used as a thermal-bonding process, the roUs are of the same dimension and composition and are independently driven. However, when calendering is used as a fabric finishing operation, the roUs are frequently of different dimensions and composition and are not always independently driven. 

Copper-based thermal stabilizers are also effective photostabilizers for nylon. They can be added before polymerization, or the soluble salts (eg, CuSO can be appHed to fibers as part of the finish or to fabrics as post-treatments. The effectiveness of the copper salt—alkah haUde system added to prepolymer in retarding phototendering and photoyeUowing of the resulting spun yam is illustrated in Figure 5. 

The dehydrogenation of the mixture of m- and -ethyltoluenes is similar to that of ethylbenzene, but more dilution steam is required to prevent rapid coking on the catalyst. The recovery and purification of vinyltoluene monomer is considerably more difficult than for styrene owing to the high boiling point and high rate of thermal polymerization of the former and the complexity of the reactor effluent, which contains a large number of by-products. Pressures as low as 2.7 kPa (20 mm Hg) are used to keep distillation temperatures low even in the presence of polymerization inhibitor. The finished vinyltoluene monomer typically has an assay of 99.6%. 

Cordierite [12182-53-5] Mg Al Si O g, is a ceramic made from talc (25%), kaolin (65%), and Al O (10%). It has the lowest thermal expansion coefficient of any commercial ceramic and thus tremendous thermal shock resistance. It has traditionally been used for kiln furniture and mote recently for automotive exhaust catalyst substrates. In the latter, the cordierite taw materials ate mixed as a wet paste, extmded into the honeycomb shape, then dried and fired. The finished part is coated with transition-metal catalysts in a separate process. 

---