The measuring bridge

The Measuring Bridge.—This very commonly consists of a thin wire of platinum, platinum-iridium, or nickelin, stretched over a scale i metre long and graduated in millimetres (Fig. 59). A sliding contact, c, having a platinum 

Since it is possible, in most cases, to arrange that the reading on the bridge wire shall be less than 50-60 cm., the bridge can be made shorter, while the wire still remains the same length, the excess of wire being wound on a small drum below the end of the scale. 

The position of sound-minimum can be determined most sharply when the sliding contact is near the end of the bridge 

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For a PRT with R, = 100 O, a temperature resolution of 1 mK requires that Rt be measured with a precision of 4 X lO"" fl i.e., a random error <4 X 10 percent. Thus the measurement bridge and digital voltmeter must be high-precision instalments. In the case of the DVM, one needs at least six-digit resolution. It should be noted that, owing to decreasing sensitivity as T approaches 0 K, PRTs do not make attractive practical thermometers at very low temperatures. 

Fig. 1. Circuit diagram of the measuring bridge. Tip H. 2 Wagner auxiliary arm tl 3 H 4 Rv equivalent circuit Tlx measuring cell.

A common known method to get eddy-current informations about material flaws is the measurement of real- and imaginary part of the complex impedance of a coil in absolute circuit. The measurement, shown in this paper, are done with an impedance analyzer (HP4192A). The device measures the serial inductance L, and the serial resistance Rs of the complex impedance with an auto-balance bridge measurement circuit [5]. 

The measurement of pH using the operational ceU assumes that no residual Hquid-junction potential is present when a standard buffer is compared to a solution of unknown pH. Although this may never be stricdy tme, especially for complex matrices, the residual Hquid-junction potential can be minimised by the appropriate choice of a salt-bridge solution and caHbration buffer solutions. 

Reference Electrodes and Liquid Junctions. The electrical cincuit of the pH ceU is completed through a salt bridge that usually consists of a concentrated solution of potassium chloride [7447-40-7]. The solution makes contact at one end with the test solution and at the other with a reference electrode of constant potential. The Hquid junction is formed at the area of contact between the salt bridge and the test solution. The mercury—mercurous chloride electrode, the calomel electrode, provides a highly reproducible potential in the potassium chloride bridge solution and is the most widely used reference electrode. However, mercurous chloride is converted readily into mercuric ion and mercury when in contact with concentrated potassium chloride solutions above 80°C. This disproportionation reaction causes an unstable potential with calomel electrodes. Therefore, the silver—silver chloride electrode and the thallium amalgam—thallous chloride electrode often are preferred for measurements above 80°C. However, because silver chloride is relatively soluble in concentrated solutions of potassium chloride, the solution in the electrode chamber must be saturated with silver chloride. 

The use of CO is complicated by the fact that two forms of adsorption—linear and bridged—have been shown by infrared (IR) spectroscopy to occur on most metal surfaces. For both forms, the molecule usually remains intact (i.e., no dissociation occurs). In the linear form the carbon end is attached to one metal atom, while in the bridged form it is attached to two metal atoms. Hence, if independent IR studies on an identical catalyst, identically reduced, show that all of the CO is either in the linear or the bricked form, then the measurement of CO isotherms can be used to determine metal dispersions. A metal for which CO cannot be used is nickel, due to the rapid formation of nickel carbonyl on clean nickel surfaces. Although CO has a relatively low boiling point, at vet) low metal concentrations (e.g., 0.1% Rh) the amount of CO adsorbed on the support can be as much as 25% of that on the metal a procedure has been developed to accurately correct for this. Also, CO dissociates on some metal surfaces (e.g., W and Mo), on which the method cannot be used. 

The hot-wire anemometer sensor is a very fine wire with a diameter of few micrometers and length of few millimeters. This wire is connected to a measurement bridge and an electrical current is fed through the wire. The wire is heated to a temperature above the air temperature and the air velocity is determined by the cooling effect of the wire. The voltage over the wire, U, is a function not only of the velocity but also of the excess temperature and the fluid properties in the following way ... 

The ionic conductivity of a solvent is of critical importance in its selection for an electrochemical application. There are a variety of DC and AC methods available for the measurement of ionic conductivity. In the case of ionic liquids, however, the vast majority of data in the literature have been collected by one of two AC techniques the impedance bridge method or the complex impedance method [40]. Both of these methods employ simple two-electrode cells to measure the impedance of the ionic liquid (Z). This impedance arises from resistive (R) and capacitive contributions (C), and can be described by Equation (3.6-1) ... 

In its simplest form, the Wheatstone bridge is used on D.C. for the measurement of an unknown resistance in terms of three known resistors. Its accuracy depends on that of the known units and the sensitivity of the detector. It is also used for sensing the changes which occur in the output from resistance strain-gauge detectors. The latter instruments can be made portable and can detect variations of less than 0.05 per cent. 

The Kelvin double bridge is a more sophisticated variant used for the measurement of very low resistance such as ammeter shunts or short lengths of cable. This is also operated on D.C. In industrial terms the digital D.C. low-resistance instruments are more convenient although somewhat less accurate. 

It is often of interest also to measure both the external and internal resistances of the galvanic circuit by the use of appropriate resistance-measurement bridges or by even more elaborate techniques such as have been described by Pearson . 

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