Textiles Patents

Erom 1920 to 1931, after the expiration of the viscose patents, world output increased from 14,000 to 225,000 t per year, as more than 100 companies entered the ceUulose fiber field. In Europe, Vereinigte Glanstoff Eabriken (VGE, Germany), Enka (HoUand), I. G. Earben (Germany), Snia Viscosa (Italy), Comptoir des Textiles Artificiels (CTA, Erance), Rhodiaceta (Erance), Tubize (Belgium), and ChatiUon (Italy) were among the new starters. 

Phosphonium Salt—Urea Precondensate. A combination approach for producing flame-retardant cotton-synthetic blends has been developed based on the use of a phosphonium salt—urea precondensate (145). The precondensate is appUed to the blend fabric from aqueous solution. The fabric is dried, cured with ammonia gas, and then oxidized. This forms a flame-resistant polymer on and in the cotton fibers of the component. The synthetic component is then treated with either a cycUc phosphonate ester such as Antiblaze 19/ 19T, or hexabromocyclododecane. The result is a blended textile with good flame resistance. Another patent has appeared in which various modifications of the original process have been claimed (146). Although a few finishers have begun to use this process on blended textiles, it is too early to judge its impact on the industry. 

Goumanns. By treatment of flax with escuUn, a glucoside of esculetin [305-01-1] (10), a brightening effect is achieved however, this effect is not fast to washing and light. The use of P-methylumbeUiferone [90-33-5] (11) and similar compounds as brighteners for textiles and soap has been patented. 

Melamine resins were introduced about ten years after the Beetle molding compound. They were very similar to those based on urea but had superior quaHties. Henkel in Germany was issued a patent for a melamine resin in 1936 (7). Melamine resins rapidly supplanted urea resins and were soon used in molding, laminating, and bonding formulations, as well as for textile and paper treatments. The remarkable stabiHty of the symmetrical triazine ring made these products resistant to chemical change once the resin had been cured to the insoluble, cross-linked state. 

Tire Cord. Melamine resins are also used to improve the adhesion of mbber to reinforcing cord in tires. Textile cord is normally coated with a latex dip solution composed of a vinylpyridine—styrene—butadiene latex mbber containing resorcinol—formaldehyde resin.. The dip coat is cured prior to use. The dip coat improves the adhesion of the textile cord to mbber. Further improvement in adhesion is provided by adding resorcinol and hexa(methoxymethyl) melamine [3089-11 -0] (HMMM) to the mbber compound which is in contact with the textile cord. The HMMM resin and resorcinol cross-link during mbber vulcanization and cure to form an interpenetrating polymer within the mbber matrix which strengthens or reinforces the mbber and increases adhesion to the textile cord. Brass-coated steel cord is also widely used in tires for reinforcement. Steel belts and bead wire are common apphcations. Again, HMMM resins and resorcinol [108-46-3] are used in the mbber compound which is in contact with the steel cord to reinforce the mbber and increase the adhesion of the mbber to the steel cord. This use of melamine resins is described in the patent Hterature (49). 

There are a number of papers and patents on recycling dye and textile industry wastewater for reuse of dye, textile auxiUaries, and water (99,102,120,306—311). Recycling is considered a part of pollution prevention. 

The BASF patent from 1913 describes the manufacture of these products by the one-pot reaction of naphthalene, sulfuric acid, and formaldehyde. Quantitatively these polycondensates find their most important use in the textile industry. Although these compounds have been in use for many years, relatively little is known about their constitution. Extensive examinations of their systhesis and structures were recently carried out by Pochini [179,180]. 

N. V. Vvedenskii, A. E. Orekhova, and L. I. Sheveleva, USSR Patent SU 408,578 to Kirov, S. M., Institute of Textile and Light Industry, Leningrad From Otkrytiya, Izobret., Prom. Obraztsy, Tovarnye Znaki (1974). 

The selected patents do not distinguish between polymerization, processing, applications, analysis, etc. For example, polyamides include textile fibres. 

This concept later evolved into the Ucarsep membrane made of a layer of nonsintered ceramic oxide (including Zr02) deposited on a porous carbon or ceramic support, which was patented by Union Carbide in 1973 (Trulson and Litz 1973). Apparently, the prospects for a significant industrial development of these membranes were at the time rather limited. In 1978, Union Carbide sold to SPEC the worldwide licence for these membranes, except for a number of applications in the textile industry in the U.S. At that time, SPEC recognized the potential of inorganic membranes, but declassification of the inorganic membrane technology it had itself developed for uranium enrichment was not possible. 

Patent, 4,464,238, 1984. ASTM D726. Standard Test Methods for Identification of Fibers in Textiles. ASTM International. ASTM ... 

TABLE 9.2 Noncellulosic Textile Fibers Patent Names... 

Huizenga, R., Mantingh, J., Pomp-De Wit, F., (1998). Amylopectin potato starch products as sizing agents for textile yarns. World Intellectual Property Organization, International Patent Applieation PCT/NL98/00063. 

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