Temperature dependence moisture effects

The packaging (qv) requirements for shipping and storage of thermoplastic resins depend on the moisture that can be absorbed by the resin and its effect when the material is heated to processing temperatures. Excess moisture may result in undesirable degradation during melt processing and inferior properties. Condensation polymers such as nylons and polyesters need to be specially predried to very low moisture levels (3,4), ie, less than 0.2% for nylon-6,6 and as low as 0.005% for poly(ethylene terephthalate) which hydrolyzes faster. 

Removal of water from gases may be by physical or chemical means, and is commonly by adsorption on to a drying agent in a low-temperature trap. The effectiveness of drying agents depends on the vapour pressure of the hydrated compound - the lower the vapour pressure the less the remaining moisture in the gas. 

Likewise, a further term can be added to cover the effect of moisture, which will also be temperature dependent. 

Sugarcane Sower initiation is dependent on day length, temperature, age, moisture, and variety, and can be prevented by chemical applications at, or very close to, the date of floral initiation. The effective chemicals have been of two types (a) photosynthetic inhibitors, such as 3-(p-chlorophenyl)-1,1-dimethylurea (monuron), or (b) leaf-burning, contact chemicals. The very effective bipyridylium herbicides 6,7-dihydrodipyrido[l,2-a 2, r-c]pyrazidinium dibromide (diquat) and 1, l -dimethyl-4,4 -bipyridinium bis (methyl sulfate) (paraquat) combine the two properties, although the... 

In terms of improving our ability to predict soil C turnover, we identify five priorities for research (1) The interactive effects of temperature and moisture on microbial decomposition rates, because soils will experience novel and transient conditions (2) the mechanisms governing protection of OM through interactions with mineral surfaces and due to spatial structure (3) the mechanisms leading to slower OM turnover times with depth (4) the potential for nonlinear responses of decomposition to C availability—for example, the role of labile C inputs in stimulating decomposition of less labile OM (i.e., priming) and density-dependent microbial behavior and (5) how the chemical characteristics of organic compounds, as inputs from different plant species, charred (black) carbon, or microbial cell walls and by-products, influence mechanisms of stabilization and turnover. 

Saturated salt solutions and sulfuric acid solutions establish relative humidity by reducing the vapor pressure above an aqueous solution (a colligative effect). Saturated salt solutions at controlled temperature maintain a constant relative humidity as long as excess salt and bulk solution are present. As water is added or removed from the solution, moisture from the head-space will either condense or evaporate (as appropriate), with subsequent dissolution or precipitation of salt to maintain the equilibrium vapor pressure. Because the degree of vapor pressure depression is dependent on the number of species in solution and, further, since the solubility of most salts is somewhat dependent on temperature, the relative humidity generated is also temperature dependent. Hence, use of the same salt at different temperatures can result in different relative humidities. Refs. can be consulted for specific saturated salt solutions that result in defined relative humidities as a function of... 

The purpose of this work was to model and simulate the dehydration of vegetables, particularly red pepper, in batch and continuous dryers. The models used for the simulation took into account the shrinkage of particles during drying as well as the moisture and temperature-dependent properties of the product. Effects of several parameters such as temperature and velocity of air, bed thickness, and recycle ratio on drying time, process efficiency, and final product quality were studied. 

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