Temperature control vapor

The treatment of vapor film collapse used here was simply to increase the heat transfer coefficient when the pressure exceeded a certain value, since this models pressure-induced vapor film collapse. Because of the high initial temperature of the melt ( 2500 K) in situations of interest to us, temperature-controlled vapor film collapse was not considered to be important. We have performed scoping calculations that show that the exact criterion for vapor film collapse is unimportant, since increasing the heat transfer rate between the large particles and the water only changes the solution by a small amount. This is because the heat transfer surface area of the large melt particles is very small compared with that of the fragments. 

Figure 13.5 shows a flowsheet for the manufacture of phthalic anhydride by the oxidation of o-xylene. Air and o-xylene are heated and mixed in a Venturi, where the o-xylene vaporizes. The reaction mixture enters a tubular catalytic reactor. The heat of reaction is removed from the reactor by recirculation of molten salt. The temperature control in the reactor would be diflficult to maintain by methods other than molten salt. 

The catalytic vapor-phase oxidation of propylene is generally carried out in a fixed-bed multitube reactor at near atmospheric pressures and elevated temperatures (ca 350°C) molten salt is used for temperature control. Air is commonly used as the oxygen source and steam is added to suppress the formation of flammable gas mixtures. Operation can be single pass or a recycle stream may be employed. Recent interest has focused on improving process efficiency and minimizing process wastes by defining process improvements that use recycle of process gas streams and/or use of new reaction diluents (20-24). 

A humidification subsystem controls the temperature, flow rate, and relative humidity of the sweep stream. Air and water can be fed to a Hquid-gas packed contactor to produce the desired moisture level ia the vapor stream. The saturation temperature controls the water loading of the air which can be heated to give exactly the desired relative humidity. 

Condensing Organic Va.por, The eutectic mixture of diphenyl and diphenyl oxide is an excellent vapor medium for precise temperature control at temperatures higher than those practical using steam. This mixture can achieve 315°C while holding pressure at 304 kPa (3 atm) absolute. In contrast, steam would require 10.6 MPa (105 atm) pressure. 

These enable temperature control with built-in exchangers between the beds or with pumparound exchangers. Converters for ammonia, 80.3, cumene, and other processes may employ as many as five or six beds in series. The Sohio process for vapor-phase oxidation of propylene to acrylic acid uses hvo beds of bismuth molybdate at 20 to 30 atm (294 to 441 psi) and 290 to 400°C (554 to 752°F). Oxidation of ethylene to ethylene oxide also is done in two stages with supported... 

General. With simple instrumentation discussed here, it is not possible to satisfactorily control the temperature at both ends of a fractionation column. Therefore, the temperature is controlled either in the top or bottom section, depending upon which product specification is the most important. For refinery or gas plant distillation where extremely sharp cut points are probably not required, the temperature on the top of the column or the bottom is often controlled. For high purity operation, the temperature will possibly be controlled at an intermediate point in the column. The point where AT/AC is maximum is generally the best place to control temperature. Here, AT/AC is the rate of change of temperature with concentration of a key component. Control of temperature or vapor pressure is essentially the same. Manual set point adjustments are then made to hold the product at the other end of the column within a desired purity range. The technology does exist, however, to automatically control the purity of both products. 

Abnormal Heat Input From Reboiler - Reboilers are designed with a specified heat input. When they are new or recently cleaned, additional heat input above the normal design can occur. In the event of temperature control failure, vapor generation may exceed the process system s ability to condense or otherwise absorb the buildup of pressure, which may include noncondensibles due to overheating. 

Flare systems must be protected against any possibility of partial or complete blockage by ice, hydrates, solidification, etc. Seal Drums and Y-seals requiring winterizing should be provided with temperature-controlled steam injection to maintain the seal water temperature at 4 to 10 C. This limits the quantity of water vapor entering the flare stack. 

In the vacuum mixer, water evaporation is also used for the temperature control, since the evaporation rate can be influenced by the grade of the vacuum. The water vapor, however, does not escape from the mixer, but is condensed and returned into the mix, the composition of which is thus not changed. 

The reaction heat is removed by the vacuum evaporation of dilution water. The resulting water vapors allow complete degassing and stripping of any trace of undesired low boiling by products (i.e., 1,4-dioxane for ethoxy sulfates). The product temperature is accurately controlled with the vacuum level kept in the reactor and by the temperature control in the reactor jacket. The automatic control of the different process parameters, i.e., flow rate of reagents, vacuum degree, temperature of thermostatting water, also allows for accurate control of the product concentration. 

Tempered water at >60°C is circulated through the jacket for temperature control. Makeup HF mixed with nitrogen is added as the vapor on demand. Probes at four levels are used for HF control and safety ... 

The reactor operates with the effluent at about 166 C and 62% conversion. Temperature control is effected primarily by reflux cooling as indicated in Fig. 20 with the condensed vapors being returned to the upstream reactor compartment. 

If a large volume of gaseous HBr is available from the upstream bromination process, it may be fed directly to the preheater. In this case, steam is cofed to the reactor to provide temperature control. This simplifies the process design by eliminating the vaporizer. 

The parameters controlling the synthesis are the temperature, the vapor pressure of the alkali metal and the crystalline state of boron. The reactions are unaffected by the atomic ratio, M/B, provided it is much larger than the M/B ratios characteristic of the phases that are to be prepared values of, e.g., ca. 1 /2, 1 or 2, are satisfactory. 

Solution There are several theoretical ways of stabilizing the reactor, but temperature control is the normal choice. The reactor in Example 5.7 was adiabatic. Some form of heat exchange must be added. Possibilities are to control the inlet temperature, to control the pressure in the vapor space thereby allowing reflux of styrene monomer at the desired temperature, or to control the jacket or external heat exchanger temperature. The following example regulates the jacket temperature. Refer to Example 5.7. The component balance on styrene is unchanged from Equation (5.29) ... 

Cold shot. Injection of cold fresh feed for exothermic reactions or preheated feed for endothermic reactions to intermediate points in the reactor can be used to control the temperature in the reactor. Again, the heat integration characteristics are similar to adiabatic operation. The feed is a cold stream if it needs to be increased in temperature or vaporized and the product a hot stream if it needs to be decreased in temperature or condensed. If heat is provided to the cold shot or hot shot streams, these are additional cold streams. 

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