Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Supra-conductivity

It was possible to measure accurately the average metal particle size from the magnetization curve taken at 4.2 K with magnetic fields ranging from 0 up to 70 k. Oe (supra-conductive coil). [Pg.263]

When the temperature T decreases below the critical temperature Tc BEC starts at first only for a small fraction of all atoms in the magnetic trap, i.e. not all atoms are immediately transferred into the coherent state of BEC. With decreasing temperature the fraction of the condensed atoms increases (Fig. 9.35). The BEC-state is separated from the normal state with T > Tc by an energy gap similar to the energy gap between the Cooper pair state in supra-conductivity and the normal state. One therefore has to pump energy into the condensate in order to convert the assemble into the normal state. Also the energy distribution changes from a Maxwell-Boltzmann distribution above to a distribution... [Pg.513]

For Fermions the Pauli principle holds that any quantum state can be only occupied by at most one Fermion. Therefore a direct Bose-Einstein condensation of Fermions is not possible. However, two Fermions may couple to a Fermi-pair which is a Boson such as in supra-conductivity where two electrons couple to a Cooper pair and the condensation is realized by the Bosonic Fermi-pairs. Similar processes occur in supra-fluidity where two He atoms (Fermions) couple to a Boson. [Pg.517]

The question is now, whether such pairing can also happen for atoms in the gas phase, if the gas is cooled down to sufficiently low temperatures. The experimental possibilities of spectroscopic investigations of cold Fermi-pairs might elucidate many unclear aspects of supra-conductivity in solids or of supra-fluidity [1189]. [Pg.517]

Also the influence of magnetic flelds on the behaviour of trapped atoms has been studied. One example is the Meissner effect, which was first discovered for supra-conducting solids and has now been investigated for atoms in optical lattices in external magnetic fields [1205]. [Pg.521]

The authors conducted a similar investigation of precatalysts 7 and 11 using TiBA and trityl tetrakis(pentafluorophenyl)borate as the cocatalyst. They concluded that this material contained no fraction that could be characterized as blocky. It was therefore proposed that reversible chain transfer occurred only with MAO or TMA and not with TiBA. This stands in contrast to the work of Chien et al. [20] and Przybyla and Fink [22] (vida supra), who claim reversible chain transfer with TiBA in similar catalyst systems. Lieber and Brintzinger also investigated a mixture of isospecific 11 and syndiospecific 12 in attempts to prepare iPP/sPP block copolymers. Extraction of such similar polymers was acknowledged to be difficult and even preparative temperature rising elution fractionation (TREF) [26, 27] was only partially successful. [Pg.73]

G. Jager 26 gives the heat conductivity of 20 and 44 per cent, sodium nitrate soln. as 94"9 with 90 4 respectively—silver unity—and for 10 and 20 per cent. soln. of potassium nitrate, 97 2 and 92 2 respectively. According to C. C. Person, the latent heat of fusion of sodium nitrate is 5 355 Cals, per mol. at 310 5° and of potassium nitrate 4 79 Cals, per mol. at 339°. K. M. Goodwin and H. T. Kalmus value for potassium nitrate is 2 57 cals, at 333°. According to M. Bellati and R. Romanese, the heat of transition from the rhombohedral to the rhombic form is 11 89 cals. P. W. Bridgman, 11 6 cals.—vide supra. [Pg.814]

As an initial matter, we note that it is an open question whether federal courts ever have authority to recognize a necessity defense not provided by statute. A necessity defense traditionally covered the situation where physical forces beyond the actor s control rendered illegal conduct the lesser of two evils. United States v. Bailey, 444 U.S. 394, 410 (1980). Even at common law, the defense of necessity was somewhat controversial. See, e.g., Queen v. Dudley ir Stephens, 14 Q. B. 273 (1884). And under our constitutional system, in which federal crimes are defined by statute rather than by common law, see United States y. Hudson, 7 Cranch 32, 34 (1812), it is especially so. As we have stated Whether, as a policy matter, an exemption should be created is a question for legislative judgment, not judicial inference. United States. Rutherford, 442 U.S. 544, 559 (1979). Nonetheless, we recognize that this Court has discussed the possibility of a necessity defense without altogether rejecting it. See, e.g., Bailey, supra, at 415. [Pg.248]

The inversion from one form to the other was supposed to explain the maximum attained by the conductivity curve, Fig. 33. H. Gorke showed that there is no need for this hypothesis to explain the facts. The salt prepared at the low temp, may have a trace of impurity, say barium hydroxide, which accelerates the reduction, and that prepared at the higher temp, may be an acid salt or contain a trace of phosphoric acid which retards the reduction. H. Burgarth, H. Remy, and T. M. Lowry discussed the electronic structure of phosphorous acid—vide supra, phosphoric acid. [Pg.905]

The basicity of phosphoric acid appears different when it is neutralized with sodium hydroxide according to the indicator employed—vide supra—and the electrical conductivity data explain how the acid was once considered by M. Berthe-lot and W. Louguinine, A. Joly, D. Berthelot, P. Walden, and J. B. Senderens to... [Pg.960]

As we shall soon see in the case of Frank s, supra, even though a correction to such a patent can be made under 256, a finding of inequitable conduct can still invalidate a patent. [Pg.122]

Advances in supra-molecular chemistry have enabled the synthesis of a variety of tailor-made complex molecules, which have been designed to meet different requirements such as a high conductivity, the possibility of switching between two states triggered either by photons or electrons, a stiff rod-like structure and good solubility. [Pg.365]


See other pages where Supra-conductivity is mentioned: [Pg.1023]    [Pg.227]    [Pg.74]    [Pg.75]    [Pg.515]    [Pg.407]    [Pg.1023]    [Pg.227]    [Pg.74]    [Pg.75]    [Pg.515]    [Pg.407]    [Pg.110]    [Pg.35]    [Pg.73]    [Pg.462]    [Pg.216]    [Pg.429]    [Pg.429]    [Pg.403]    [Pg.312]    [Pg.598]    [Pg.8]    [Pg.253]    [Pg.264]    [Pg.302]    [Pg.493]    [Pg.661]    [Pg.895]    [Pg.1039]    [Pg.312]    [Pg.320]    [Pg.152]    [Pg.210]    [Pg.223]    [Pg.250]    [Pg.351]    [Pg.258]    [Pg.77]    [Pg.339]    [Pg.343]    [Pg.41]    [Pg.471]    [Pg.154]   
See also in sourсe #XX -- [ Pg.227 ]

See also in sourсe #XX -- [ Pg.288 ]




SEARCH



Supra

© 2024 chempedia.info