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Strain formation

The improvement of the CLA snpply of humans can be achieved via CLA-pro-ducing strains. Formation of CLA can be accomplished during the preparation of the food product via dairy cultures, but this process could also be amplified in the human gastrointestinal tract with the administration of probiotics. Recently, a number of... [Pg.86]

The following data ( fable 1) for niolcctilcs, including hydrocarbon s, strained ring system s. molecn les with heieroatom s, radicals, and ions conies from a review by Stewart. For most organic molecules,, YM 1 reports heals of formation accurate to within a few kilocalories per rn ol. bor soni e molecules (particularly inorgari ic compoun ds wdth several halogens, such as perch loryl fluoride, even the best sem i-em pineal method fails completely. [Pg.130]

HEAT OF FORMATION AND STRAIN ENERGY CALCULATIONS (UNIT=KCAUMOLE)... [Pg.145]

PC Model has some features that are not found in many other molecular mechanics programs. This is one of the few programs that outputs the energy given by the force field and the heat of formation and a strain energy. Atom types for describing transition structures in the MMX force field are included. There is a metal coordination option for setting up calculations with metal atoms. There are also molecular similarity and conformation search functions. [Pg.347]

In contrast to the 4-hydroxy isomers, the thermally stable 5-hydroxy-THISs add to the C=C bond of cyclopropenylidenes (4. 18, 27. 28). The adducts eliminate carbonyl sulfide, and the strained bond breaks resulting in ring-expansion with formation of pyridin-4-ones. -thiones, or -imines. or 4-alkylidenedihydropvridines (20, X = 0. S.NR. or CRR ) (Scheme 19). [Pg.10]

The difference m energy between the staggered and eclipsed forms is due almost entirely to the torsional strain m the eclipsed conformation At any instant almost all the molecules of ethane reside m the staggered con formation... [Pg.133]

The stmcture of DPXN was determined in 1953 from x-ray diffraction studies (22). There is considerable strain energy in the buckled aromatic rings and distorted bond angles. The strain has been experimentally quantified at 130 kj/mol (31 kcal/mol) by careful determination of the formation enthalpy through heat of combustion measurements (23). The release of this strain energy is doubtiess the principal reason for success in the particularly convenient preparation of monomer in the parylene process. [Pg.431]

Bismuth Subsalicylate. (2-Hydroxybenzoato-0 )-oxobismuth [14882-18-9] (Pepto-Bismol) maybe made by the process described in Reference 10. Bismuth subsaHcylate has been shown to bind toxins produced by several bacterial strains. It may also act as a result of its saHcylate component on prostaglandin formation and have specific intestinal antisecretory activity. It has been found to be effective in the prevention and therapy of... [Pg.202]

In experimental animals and in vitro, DHBs show a variety of biological effects including binding of metaboHtes to various proteins. Clastogenic effects have been observed in vitro and in some in vivo studies with the three compounds. No reproductive effects have been shown by conventional studies with either hydroquinone, catechol, or resorcinol (122). Hydroquinone has been shown to induce nephrotoxicity and kidney tumors at very high doses in some strains of rat (123) catechol induces glandular stomach tumors at very high dose (124). Repeated dermal appHcation of resorcinol did not induce cancer formation (125). [Pg.494]


See other pages where Strain formation is mentioned: [Pg.297]    [Pg.144]    [Pg.250]    [Pg.145]    [Pg.229]    [Pg.98]    [Pg.318]    [Pg.242]    [Pg.67]    [Pg.340]    [Pg.297]    [Pg.144]    [Pg.250]    [Pg.145]    [Pg.229]    [Pg.98]    [Pg.318]    [Pg.242]    [Pg.67]    [Pg.340]    [Pg.370]    [Pg.137]    [Pg.244]    [Pg.146]    [Pg.53]    [Pg.74]    [Pg.481]    [Pg.116]    [Pg.117]    [Pg.122]    [Pg.472]    [Pg.681]    [Pg.939]    [Pg.431]    [Pg.530]    [Pg.64]    [Pg.112]    [Pg.248]    [Pg.340]    [Pg.65]    [Pg.111]    [Pg.3]    [Pg.184]    [Pg.299]    [Pg.477]    [Pg.231]    [Pg.234]    [Pg.265]    [Pg.296]    [Pg.297]   
See also in sourсe #XX -- [ Pg.1262 ]




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Heat of formation and strain energy

Steric strain formation

Strain relaxation due to dislocation formation

Strained siloxane bridges, formation

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