Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

STEM, analytical method

Improvements in the resolution and versatility of microscopic techniques have come about rapidly. TEM, STEM, and high-resolution electron microscopy have helped the catalytic chemist to analyze the effects of metal-support interactions and particle-size effects—developments that will probably lead to improvements in commercial technologies. Several novel analytical methods, arising from very clever experimentation, were discussed at the... [Pg.7]

Although molalities are simple experimental quantities (recall that the molality of a solute is given by the amount of substance dissolved in 1 kg of solvent) and have the additional advantage of being temperature-independent, most second law thermochemical data reported in the literature rely on equilibrium concentrations. This often stems from the fact that many analytical methods use laws that relate the measured physical parameters with concentrations, rather than molalities, as for example the Lambert-Beer law (see following discussion). As explained in section 2.9, the equilibrium constant defined in terms of concentrations (Kc) is related to Km by equation 14.3, which assumes that the solutes are present in very small amounts, so their concentrations (q) are proportional to their molalities nr, = q/p (p is the density of the solution). [Pg.207]

Both the detection limit and the limit of quantification, as defined, are often not very stable characteristics of an analytical method, because the blank signal and the signal generated by the very low concentrations of the analyte are frequently dependent on certain analytical parameters, including the purity of reagents, sample matrices, environmental conditions, instrumentation, and the analysts themselves. Sensitivity is a measure of the ability of an analytical method to discriminate between small differences in analyte concentration. It is defined as the analyte signal per unit concentration of the analyte. Despite the apparent simplicity of the sensitivity concept, a degree of confusion surrounds its use. This confusion stems from the perception that the sensitivity of a method is the same as the limit of detection. [Pg.759]

Perry NB, van Klink JW, Burgess EJ and Par-menter GA (1997) Alkamide levels in Echinacea purpurea a rapid analytical method revealing differences among roots, rhizomes, stems, leaves and flowers. Planta Med 63, 58-62. [Pg.118]

The widespread use of biomonitoring, as evidenced by reports citing chemical concentrations in human blood samples (CBRC 2005 IC Wales 2005 WWF 2002, 2003) or in initiatives for developing biomonitoring programs in such states as California and Minnesota (OMB Watch 2005 Risk Policy Report 2005), stems from improvement in analytic methods and laboratory techniques. It is possible to measure smaller concentrations of chemicals in the body and to do so with smaller quantities of biologic samples (such as blood and urine). [Pg.42]

Exploratory data analysis (EDA). This analysis, also called pretreatment of data , is essential to avoid wrong or obvious conclusions. The EDA objective is to obtain the maximum useful information from each piece of chemico-physical data because the perception and experience of a researcher cannot be sufficient to single out all the significant information. This step comprises descriptive univariate statistical algorithms (e.g. mean, normality assumption, skewness, kurtosis, variance, coefficient of variation), detection of outliers, cleansing of data matrix, measures of the analytical method quality (e.g. precision, sensibility, robustness, uncertainty, traceability) (Eurachem, 1998) and the use of basic algorithms such as box-and-whisker, stem-and-leaf, etc. [Pg.157]

Hitchings interest in nucleic acids stemmed from his work at Harvard with Cyrus J. Fiske who had discovered ATP in muscle. The development of micro-analytical methods for the purine bases to follow the metabolism of ATP was the theme of Hitchings doctoral thesis. After completion of his PhD in 1933, during the depths of the depression, he experienced a nine-year period of impermanence both financial and intellectual with short appointments at Harvard s C. P. Huntington Laboratories in cancer... [Pg.133]

Ma, whereas ion microprobe analyses yielded 934 4 Ma. Zhu et al. (1998) explores potential matrix effects during monazite ion microprobe analysis, but analytical methods outlined in their paper preclude conclusive interpretations. Stem and Sanborn (1998) report that the use of high-Th monazite standards may lead to errors in measuring ages of low-Th grains, and suggest the use of compositionally matched standards and unknowns. [Pg.538]

High variability can be found in the results of lead analyses. This is partly due to limited trueness and precision of analytical methods. Variability in the results of lead analyses also stems from the different pre-treatment methods that are used. [Pg.74]

X-Ray fluorescence is widely used in the analysis of modern refractories, including boron nitride, together with standard analytical methods [48]. Radiation-induced products in a-BN can be studied with scanning transmission electron microscopy (STEM) [49]. Transmission electron microscopy using bright field and dark field imaging and selected area electron diffraction was used to study a-BN ceramics formed by pyrolysis of organyl-substituted amino-borazine precursors. These ceramics are mainly amorphous with pockets of microfibrils or microcrystallites [50]. [Pg.55]

A 2-acetamido-2-deoxy-P-D-glucopyranosyl moiety, rarely found as a plant component, is a constituent of a saponin from Albizzia julibrissin stem bark. Kedarcidin, a new chromoprotein anti-tiunour fermentation product of the enediyne class contains the novel amino sugar kedarosamine (2,4,6-trideoxy-4-dimethylamino-L-arflh/no-hexopyranose), isolated as its methyl glycoside. A microscale chromatographic analytical method for A-acetylneuraminic acid in glycoproteins is covered in Chapter 23. [Pg.108]


See other pages where STEM, analytical method is mentioned: [Pg.456]    [Pg.928]    [Pg.247]    [Pg.78]    [Pg.364]    [Pg.307]    [Pg.113]    [Pg.320]    [Pg.107]    [Pg.46]    [Pg.199]    [Pg.51]    [Pg.84]    [Pg.606]    [Pg.322]    [Pg.703]    [Pg.44]    [Pg.36]    [Pg.51]    [Pg.3139]    [Pg.129]    [Pg.269]    [Pg.39]    [Pg.198]    [Pg.114]    [Pg.343]    [Pg.631]    [Pg.631]    [Pg.161]    [Pg.64]    [Pg.36]    [Pg.51]    [Pg.76]    [Pg.2108]    [Pg.36]    [Pg.51]   
See also in sourсe #XX -- [ Pg.497 ]




SEARCH



STEM, analytical method Applications

© 2024 chempedia.info