Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Spectral signatures

To detect adulteration of wine. Bums et al. (2002) found that the ratios of acetylated to p-coumaroylated conjugates of nine characteristic anthocyanins served as useful parameters to determine grape cultivars for a type of wine. Our laboratory utilized mid-infrared spectroscopy combined with multivariate analysis to provide spectral signature profiles that allowed the chemically based classification of antho-cyanin-containing fruits juices and produced distinctive and reproducible chemical fingerprints, making it possible to discriminate different juices. " This new application of ATR-FTIR to detect adulteration in anthocyanin-containing juices and foods may be an effective and efficient method for manufacturers to assure product quality and authenticity. [Pg.497]

However, there is a critical lack of information on this system, mainly due to insufficient studies of its spectral signatures, which makes it difficult to insert this molecule with confidence in the astrochemical schemes. During these years, only a few experimental and theoretical studies were performed, aiming to the different spectra useful for interstellar identification and chemistry. Still a lot remains to do. [Pg.401]

Spano, F. C. 2009. Analysis of the UV/Vis and CD spectral line shapes of carotenoid assemblies Spectral signatures of chiral H-aggregates. J. Am. Soc. 131 4267-4278. [Pg.156]

The acidic character of 5A zeolite as a function of the calcium content has been explored by different techniques propylene adsorption experiments, ammonia thermodesorption followed by microgravimetry and FTIR spectroscopy. Propylene is chemisorbed and slowly transformed in carbonaceous compounds (coke) which remain trapped inside the zeolite pores. The coke quantities increase with the Ca2+ content. Olefin transformation results from an oligomerization catalytic process involving acidic adsorption sites. Ammonia thermodesorption studies as well as FTIR experiments have revealed the presence of acidic sites able to protonate NH3 molecules. This site number is also correlated to the Ca2+ ion content. As it has been observed for FAU zeolite exchanged with di- or trivalent metal cations, these sites are probably CaOH+ species whose vas(OH) mode have a spectral signature around 3567 cm"1. [Pg.105]

As displayed in Figure 4, basalt, gabbro, and peridotite has distinctly different spectral signature and shows texture variations between different rock types. [Pg.487]

Pranckeviciene et al.11 have assessed the NMR spectra of pathogenic fungi and of human biofluids, finding the spectral signature that comprises a set of attributes that serve to uniquely identify and characterize the sample. This use of GAs effectively reduces the dimensionality of the data, and it can speed up later processing as well as make it more reliable. [Pg.363]

Abstract Conjugated polymers have many unique photophysical properties that make them useful for a variety of applications within the fields of chemistry, molecular biology, and medicine, specifically their ability to produce a conformation-dependant spectral signature reflective of changes in their local environment. This physical property makes conjugated polymers an indispensible tool in the toolbox of fluorescent reporters, and within this chapter, their utilization as molecular probes for studying protein structure and conformation is emphasized. [Pg.389]

These features allow to assign the a and spectral signatures of Fig. 8 to two different sets of [C -M] complexes, where Cr is in a given conformation and acts as the hydrogen-bond donor to M and where the alkyl group of M maintains a specific... [Pg.186]

The effect of changing the nature of the chromophore has been investigated by comparing the R2PI spectra of diasteromeric [C -M] (M = 2-butanol or 2-hexanol) complexes with the corresponding spectra with (R)-(- -)-l-phenylethanol (E ) and (/ )-(—)-indanol as chromophores. As for [C M], the diastereomeric [E M] (M = 2-butanol) and (M = 2-hexanol) complexes exhibit spectral signatures... [Pg.190]

Figure 11.4 MS spectral signatures for selected explosives. Each compound gives a unique spectrum. Nitrate esters all have a common peak at m/z 62. Figure 11.4 MS spectral signatures for selected explosives. Each compound gives a unique spectrum. Nitrate esters all have a common peak at m/z 62.
A vital component of globular protein structure, yet one that is very hard to characterize, is the (3-turn. These have importance in folding the protein and are often recognition sites for interactions, but have many detailed structural variations that lead to a variety of spectral signatures. Several researchers have attempted to categorize turns by detection of bands at... [Pg.729]

Figure 9.9 Bergman cycloaromatization reactions for ltex-3-ett-l,5-diyne and its perfluorinated congener, as well as a photochemical reaction scheme for generating the perfluorinated diradical from an iodinated precursor. What spectral features would be expected to be most diagnostic of the different intermediates What levels of theory would be appropriate for predicting these spectral signatures (Note that equilibrium arrows of unequal length indicate which species predominates at equilibrium.)... Figure 9.9 Bergman cycloaromatization reactions for ltex-3-ett-l,5-diyne and its perfluorinated congener, as well as a photochemical reaction scheme for generating the perfluorinated diradical from an iodinated precursor. What spectral features would be expected to be most diagnostic of the different intermediates What levels of theory would be appropriate for predicting these spectral signatures (Note that equilibrium arrows of unequal length indicate which species predominates at equilibrium.)...
Ethylidyne occurs on the triangular threefold sites on fee (111) or hexagonal close-packed (hep) (0001) faces and is formed at lower temperatures on Pd(lll) and Pt(lll) in the presence of coadsorbed hydrogen. Its spectral signature also occurs on Ru(0001) at 330 K and on Ir(lll) at 300 K. Ni(lll) is exceptional in not giving spectroscopic evidence for the ethylidyne species derived from adsorbed ethyne (or from ethene, 1). [Pg.189]

This simple oxidoreduction reaction involves complex OH - water molecules interactions whose the spectral signatures are assigned to Charge-Transfer-To-Solvent states (CTTS states). Indeed, the anionic precursor of the hydrated OH radical represents an interesting system for the direct investigation of elementary redox events in a protic molecular solution. [Pg.233]

Beyond the binary systems. Spectroscopic signatures arising from more than just two interacting atoms or molecules were also discovered in the pioneering days of the collision-induced absorption studies. These involve a variation with pressure of the normalized profiles, a(a>)/n2, which are pressure invariant only in the low-pressure limit. For example, a splitting of induced Q branches was observed that increases with pressure the intercollisional dip. It was explained by van Kranendonk as a correlation of the dipoles induced in subsequent collisions [404]. An interference effect at very low (microwave) frequencies was similarly explained [318]. At densities near the onset of these interference effects, one may try to model these as a three-body, spectral signature , but we will refer to these processes as many-body intercollisional interference effects which they certainly are at low frequencies and also at condensed matter densities. [Pg.12]

Table 1.1 Spectral Signatures of Impurities from Stopcock Grease and Rubber and Plastic Items... Table 1.1 Spectral Signatures of Impurities from Stopcock Grease and Rubber and Plastic Items...

See other pages where Spectral signatures is mentioned: [Pg.90]    [Pg.135]    [Pg.463]    [Pg.169]    [Pg.381]    [Pg.383]    [Pg.118]    [Pg.124]    [Pg.951]    [Pg.500]    [Pg.385]    [Pg.409]    [Pg.410]    [Pg.412]    [Pg.414]    [Pg.414]    [Pg.32]    [Pg.15]    [Pg.261]    [Pg.400]    [Pg.121]    [Pg.6]    [Pg.231]    [Pg.231]    [Pg.382]    [Pg.36]    [Pg.228]    [Pg.187]    [Pg.501]    [Pg.437]    [Pg.438]    [Pg.454]    [Pg.564]    [Pg.105]   
See also in sourсe #XX -- [ Pg.47 ]




SEARCH



Signature

© 2024 chempedia.info