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Spectral matching system

Heller, S. R., and Milne, G. W. EPA/NIH Mass Spectral Search System (MSSS), A Division of CIS. Washington, DC U.S. Government Printing Office. An interactive computer searching system containing the spectra of over 32,000 compounds. These can be searched on the basis of peak intensities as well as by Biemann and probability matching techniques. [Pg.40]

As with PDA detection and the construction of UV libraries, computerized data systems are used for data collection and processing with mass spectral detection. Unlike UV spectra, however, mass spectra are much less dependent on experimental conditions. Thus, it is possible to purchase commercial libraries of mass spectra for spectral matching. Mass spectral data systems range from systems that record the spectra and produce conventional relative abundance bar charts for subsequent analysis to those... [Pg.220]

Several who joined the program were contributors others did not have the requisite background and in spite of enthusiasms were of little value. Dr. Robert L. Cohen was one of the contributors he had the job of selecting a HABI that was most effective with the commercially available filters that would be useful with our dual-response imaging system. He found the best spectral match was with CDM-HABI. [Pg.160]

Considering the full scope of many applications, traditional color matching has not provided a total solution for color matching. With the addition of the many-flux theory, and spectral matching, contemporary color-matching systems are the next step in providing a total solution for color formulation. [Pg.59]

Peak identification is based on the comparison of normalized spectra representative for the peak with spectra of one or several standard compounds run in the same separation system and stored in a spectral library [107,116]. This approach is less powerful than for mass or infrared spectral searches due to the rather broad and featureless bands that typify absorption spectra. Absorption spectra of similar compounds and compounds with a chromophore well separated from the variation in molecular structure are often virtually identical. Also, spectral changes dependent on the experimental conditions (pH, mobile phase composition, temperature, etc.) occur frequently. For this reason user prepared local libraries tend to predominate over general libraries, in contrast to common practices in infrared and mass spectral searches. A favorable spectral match for an absorption spectrum by itself is not acceptable for absolute identification. [Pg.462]

The characteristic distances for FRET can be reliably calculated from the spectral properties of the donor (D) and acceptor (A). Importantly, FRET can be reliably predicted to occur for any D-Apair, so that the system can be wavelength-adjusted to match the wavelengths of laser diode sources. The extent of FRET depends on the proximity of the donor and acceptor. [Pg.11]


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