Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Sommerfeld parameters

The spherical coordinates of the ejected electron momentum k are k, 0, and < ), where 0 = cos-1 (k v). Because the impact velocity lies along the Z axis, then v v Z. The three Sommerfeld parameters are defined by... [Pg.317]

For 1, de Broglie s wavelength is small enough compared to the classical collision radius b so that a wave packet can be constructed which, approximately, follows the classical Coulomb trajectory [3]. The opposite limit, where the Sommerfeld parameter Zie hv<, denotes the case of weak Coulomb interaction where the Born approximation may be expected to be valid. [Pg.96]

More recent measurements have shown (61)(62) that the problem with the experiment was that the thermal effect at Tc is actually very small. In fact, after the true heat had been determined, research was (and still is) directed toward finding out why the Tc is so high (63). The Sommerfeld parameter or electronic specific heat parameter appears to be identical (1.5mJ/mol K2) in BaPbj B Og... [Pg.362]

Fig. 57. Specific heat contribution y(H) of the vortex core electrons in the mixed state (normalized by the Sommerfeld parameter /n) of the Yj[Lu jrNi2B2C samples from fig. 56 as function of the applied magnetic field (normalized by //c2(0)). The straight line y(H) Fig. 57. Specific heat contribution y(H) of the vortex core electrons in the mixed state (normalized by the Sommerfeld parameter /n) of the Yj[Lu jrNi2B2C samples from fig. 56 as function of the applied magnetic field (normalized by //c2(0)). The straight line y(H)<x H corresponds to the usual s-wave behaviour in the dirty...
Fig. 58. Composition dependence of the density of states N(E ) at the Fermi level ( ) of Y Lui-xl I C calculated by CPA, experimental data for the Sommerfeld parameter /n end the phenomenologically extracted values of the electron-phonon coupling constant Ae. ph (in this article usually written as Apt,), using eq. (9). Fig. 58. Composition dependence of the density of states N(E ) at the Fermi level ( ) of Y Lui-xl I C calculated by CPA, experimental data for the Sommerfeld parameter /n end the phenomenologically extracted values of the electron-phonon coupling constant Ae. ph (in this article usually written as Apt,), using eq. (9).
At this stage only measurements at the maximum load point have been recorded. The minimum film thickness in the bearing occurs at some position around the circumference in the direction of rotation. For this kind of steady state hydrodynamic bearing, lubricated with a Newtonian fluid, it is possible to determine the film thickness (and bearing attitude angle) for a numerical solution of Reynolds equation (see for example 7). Look-up tables and charts are available relating the Sommerfeld parameter to the bearing eccentricity ratio. [Pg.476]

Sink (in graph theory), 258 "Slack variables, 294 Slightly-ionized gases, 46 "Slow time, 362 Small parameter methods, 350 S-matrix, 599,649,692 Smirnova, T. S., 726 Smoluchowski, R., 745 Sokolov, A. V., 768 Sommerfeld, C. M., 722 Sonine polynomials, 25 Source (in graph theory), 258 Space group... [Pg.783]

The simplest model of metals is the Sommerfeld theory of free-electron metals (Ashcroft and Mermin 1985, Chapter 2), where a metal is described by a single parameter, the conduction electron density n. A widely used measure of... [Pg.92]

In the bulk, the charge density of electrons n equals in magnitude the charge density of the uniform positive charge background +, thus to preserve charge neutrality. The only parameter in the jellium model, r,, is the same as in the Sommerfeld theory of free-electron metals. [Pg.93]

Sommerfeld modified the Drude theory by introducing the laws of quantum mechanics. According to quantum mechanics, electrons are associated with a wave character, the wavelength A being given by A = /i/p where p is the momentum, mv. It is convenient to introduce a parameter, k, called the wave vector, to specify free electrons in metals the magnitude of the wave vector is given by... [Pg.10]

Fig. 60. Concentration dependence of various properties of polycrystalline Y(Ni xPt )2B2C obtained by specific heat measurements transition temperature Tc exponent a and parameter Hc2 from eq. (6) upper critical field Hc2(0) at T =0, where the dotted line schematically describes the dirty limit corresponding to the isotropic single band case (in reality there is a finite intersection with the field-axis for the dotted asymptotic line, see Shulga and Drechsler 2002) exponent fi of eq. (8) for the curvature of the electronic specific heat in the mixed state and Sommerfeld constant xn (after Lipp et al. 2001). Fig. 60. Concentration dependence of various properties of polycrystalline Y(Ni xPt )2B2C obtained by specific heat measurements transition temperature Tc exponent a and parameter Hc2 from eq. (6) upper critical field Hc2(0) at T =0, where the dotted line schematically describes the dirty limit corresponding to the isotropic single band case (in reality there is a finite intersection with the field-axis for the dotted asymptotic line, see Shulga and Drechsler 2002) exponent fi of eq. (8) for the curvature of the electronic specific heat in the mixed state and Sommerfeld constant xn (after Lipp et al. 2001).
Figure 2. Effect of the frequency < > of the perturbation by the core on an electron moving in a Bohr-Sommerfeld orbit of high eccentricity (low angular momentum). Plotted vs. the angle u, which varies by 2ir over one orbit. Note that the perturbation is localized near the core. In the inverse Bom-Oppenheimer limit (x 1) the perturbation oscillates many times during one orbit of the electron. (For further details and the formalism that describes the motion at high x as diffusive-like (see Refs. 3c and S.) For higher angular momentum / the effective adiabaticity parameter is x(l - e) xfl/2, where e is the eccentricity of the Bohr-Sommerfeld orbit. States of high / are thus effectively decoupled from the core. Figure 2. Effect of the frequency < > of the perturbation by the core on an electron moving in a Bohr-Sommerfeld orbit of high eccentricity (low angular momentum). Plotted vs. the angle u, which varies by 2ir over one orbit. Note that the perturbation is localized near the core. In the inverse Bom-Oppenheimer limit (x 1) the perturbation oscillates many times during one orbit of the electron. (For further details and the formalism that describes the motion at high x as diffusive-like (see Refs. 3c and S.) For higher angular momentum / the effective adiabaticity parameter is x(l - e) xfl/2, where e is the eccentricity of the Bohr-Sommerfeld orbit. States of high / are thus effectively decoupled from the core.
The Bolution of this difficulty is due to Pauli and Sommerfeld (1927), who pointed out that the laws of classical statistics ought not to be applied to the electron gas within a metal, since it is bound to behave as a degenerate gas. Thus, since the mass of the electron is 1840 times smaller than that of the hydrogen atom, it follows that, at room temperature T = 300°) and an electronic density oi n 3T0 , corresponding to a gas density at a pressure of 1 atmosphere, the value of the degeneracy parameter for the electron is... [Pg.218]

Thus, the unperturbed H atom becomes the unique example of perfectly regular quantisation for atoms. For many-electron atoms, complete separability cannot be assumed, and Bohr-Sommerfeld quantisation cannot apply exactly. In the semiclassical limit, one may expect to find at least some situations where the corresponding classical system will exhibit chaos, at least in some domain of parameter space, and where, for the quantum system, some related complications due to this breakdown will persist. [Pg.370]

At the initial part of integration function F slightly depends on parameter t. The second multiplier e ( + 2) /(t - -iX2) is the integrand of the Sommerfeld integral describing the field in a uniform medium with the resistivity of the formation. [Pg.241]

In this work we apply anisotropic Glnzburg-Landau (GL) theory [22], previously extended by us to include coupled s-wave and d-wave superconducting order parameters [23], to qualitatively analyze the single-crystal and oriented-film data on the 214- and 123-materials. In particular we think that the large.Sommerfeld coefficients 7 - S mJ/mol [4,24,25] and 9 mj/mol [18,20] for the 40 K and 90 K... [Pg.19]

Because thermionic emission is based on the synergistic effect of temperature and electric field, these two key parameters of electron emission can be just reasonably high enough to provide a significant emission current. Results of calculations of the thermionic field emission are also presented in Table 2-12. The thermionic field emission dominates over other mechanisms at T = 3000 K and > 8 10 V/cm. We should note that at high temperatures but lower electric fields < 5- 10 V/cm, electrons of the third group usually dominate the emission. The Sommerfeld relation in this case includes the work function diminished by the Schottky effect. [Pg.45]

Sl-Sommerfeld units are used throughout this book, since it is essentially addressed to newcomers to magnetism. It is expected that the SI unit system will eventually be fully adopted by the magnetism research community. The definitions of the basic parameters and the conversion factors are given in Tables 4.6-4.S. [Pg.324]

With respect to the magnetic and thermal Gruneisen parameters ilj. (sect. 4.4) it has recently been shown that ilg > ilj for transition-metal compounds with strong Stoner enhancement, (Kaiser and Fulde 1988). Since the Sommerfeld-Wilson ratio,... [Pg.328]

Antennas over ground can be modeled by several methods. The simplest is to assume a perfectly conducting Earth. This would be an excellent approximation for some situations, such as an antenna above sea water. For this case the method of images can be used. If Earth parameters do not warrant the perfectly conducting approximation, then the Fresnel reflection coefficients can be used to compute the ground reflected wave, which is superimposed with the direct wave. For antennas very close to Earth the Sommerfeld/Norton solution is used. This method uses the exact solution for fields in the presence of Earth. The NEC code discussed earher uses this method as an option, although computations require more time to complete. [Pg.1495]

Non-dlmenslonal speed-load parameter as a function of non-dlmenslonal minimum film thickness (Half-Sommerfeld boundary condition). [Pg.456]

The effect of Incorporating the Reynolds rupture boundary condition upon load capacity, other paramters remaining fixed, may be seen from Figures 3 and 4. As would be expected there is an enhancement of load capacity In comparison with the value determined with the half-Sommerfeld boundary condition. The formulae for film thickness with the two rupture conditions (18 and 19) may straightforwardly be rearranged to render expressions with the speed-load parameter as the subject. For the Reynolds condition this is. [Pg.459]

Figure 10 Ratio of non-dimensional mlnlnum film thickness calculated according to Che Reynolds and half-Sommerfeld boundary conditions as a function of the speed-load parameter. Figure 10 Ratio of non-dimensional mlnlnum film thickness calculated according to Che Reynolds and half-Sommerfeld boundary conditions as a function of the speed-load parameter.

See other pages where Sommerfeld parameters is mentioned: [Pg.348]    [Pg.304]    [Pg.476]    [Pg.348]    [Pg.304]    [Pg.476]    [Pg.249]    [Pg.240]    [Pg.280]    [Pg.287]    [Pg.633]    [Pg.92]    [Pg.240]    [Pg.297]    [Pg.37]    [Pg.85]    [Pg.201]    [Pg.77]    [Pg.21]    [Pg.155]    [Pg.342]    [Pg.346]    [Pg.206]    [Pg.216]   
See also in sourсe #XX -- [ Pg.96 ]




SEARCH



© 2024 chempedia.info