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Solvent effects reagents

The efficiency ranking of desiccants in drying air is not always the same as that observed in drying other materials. Other materials may interact with the desiccants to reduce drying effectiveness. From a study of the efficiency of some 25 desiccants for drying several families of laboratory solvents and reagents it was concluded that molecular sieves are the desiccants of choice in most cases (9—17). [Pg.509]

The importance of solvent effects in the preparation of perfluoroalkyzinc reagents is further illustrated in the reaction of perfluoroalkyl iodides with zinc-copper couple. In DMSO, DMF, and HMPA, the main products are the fluo-roolefins The formation of the fluoroolefin is facilitated when the reaction is carried out in the presence of potassium thiocyanate [30] (equation 21)... [Pg.675]

Another issue important to the success of this chiral titanium reagent 31 was the discovery of a marked solvent effect. When the fumaric acid derivative is reacted with isoprene in the presence of 10 mol% of the titanium reagent 31 in toluene, poor optical purity results (36-68% ee). Interestingly the optical purity of the adduct greatly increased in the order benzene, toluene, xylenes, and mesitylene, with 92% ee obtained in the last. Mesitylene is difficult to remove, because of its high boiling point, and other solvents were screened in detail. As a result, the mixed solvent system toluene petroleum ether (1 1) was discovered to be very effective. [Pg.36]

In order to obtain good yields, it is important to use dry solvent and reagents. The commercially available t-butyl hydroperoxide contains about 30% water for stabilization. For the use in a Sharpless epoxidation reaction the water has to be removed first. The effect of water present in the reaction mixture has for example been investigated by Sharpless et al. for the epoxidation of (E)-a-phenylcinnamyl alcohol, the addition of one equivalent of water led to a decrease in enantioselectivity from 99% e.e. to 48% e.e. [Pg.256]

A) solvent effects on the fluorescence emission, and (5) the effects of additional reagents and catalysts normally encountered in HPLC assays. [Pg.140]

The conformational preference of the monosulfoxides of 1,2-, 1,3- and 1,4-dithianes (179-181) were determined by NMR experiments which included variable-temperature studies, double irradiation, solvent effects and the inhuence of lanthanide shift reagents For 179 and 181, the axial conformers were the dominant species in CDjOD, but for 180 the equatorial conformer was in excess. [Pg.87]


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See also in sourсe #XX -- [ Pg.608 ]




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