Solids thermoelastic stress

The explosive character of the photoinduced solid-state chlorination reaction of MCH was first described in ref. 31, the phenomenon being interpreted on the assumption of a decrease in the chain-growth activation energy due to the thermoelastic stresses induced in the sample. A possible role of brittle fracture was not considered in that case. However, it would be of interest also to take account of that effect under the conditions used in ref. 31, the more so in that the evaluated values of stresses required to reduce the activation energy markedly are far above the thresholds of brittle fracture of the corresponding matrices (for details, see Section XII). 

Solid-state elastic constants fill many needs. Engineering design calculations require them for estimating load-deflection and thermoelastic stress. Derived from fundamental interatomic forces, elastic constants index both cohesion and strength. They relate to other physical properties such as specific heat and thermal expansion, all of which help define a solid s equation of state. 

Finally, we turn from solutions to the bulk state of amorphous polymers, specifically the thermoelastic properties of the rubbery state. The contrasting behavior of rubber, as compared with other solids, such as the temperature decrease upon adiabatic extension, the contraction upon heating under load, and the positive temperature coefficient of stress under constant elongation, had been observed in the nineteenth century by Gough and Joule. The latter was able to interpret these experiments in terms of the second law of thermodynamics, which revealed the connection between the different phenomena observed. One could conclude the primary effect to be a reduction of entropy... 

In an ideal elastic solid, a one-to-one relationship between stress and strain is expected. In practice, however, there are often small deviations. These are termed anelastic effects and result from internal friction in the material. Part of the strain develops over a period of time. One source of anelasticity is thermoelasticity, in which the volume of a body can be changed by both temperature and applied stress. The interaction will depend on whether a material has time to equilibrate with the surroundings. For example, if a body is rapidly dilated, the sudden... 

In many materials, the mechanical response can show both elastic and viscous types of behavior the combination is known as viscoelasticity. In elastic solids, the strain and stress are considered to occur simultaneously, whereas viscosity leads to time-dependent strain effects. Viscoelastic effects are exhibited in many different forms and for a variety of structural reasons. For example, the thermoelastic effect was shown earlier to give rise to a delayed strain, though recovery of the strain was complete on unloading. This delayed elasticity is termed anelastic-ity and can result from various time-dependent mechanisms (internal friction). Figure 5.9 shows an example of the behavior that occurs for a material that has a combination of elastic and anelastic behavior. The material is subjected to a constant stress for a time, t. The elastic strain occurs instantaneously but, then, an additional time-dependent strain appears. On unloading, the elastic strain is recovered immediately but the anelastic strain takes some time before it disappears. Viscoelasticity is also important in creep but, in this case, the time-dependent strain becomes permanent (Fig. 5.10). In other cases, a strain can be applied to a material and a viscous flow process allows stress relaxation (Fig. 5.11). 

In order to get the stress- and displacement states in the uncracked and cracked two-phase solids, respectively, as well as fracture mechanical data governing the propagation behaviour of the arising branched thermal crack systems the following, boundary value problems of the plane thermoelasticity have to be solved. 

By introducing a special nomenclature [13] according to Fig,2 of the different model geometries of the composite structures considered the following boundary value problems of the plane thermoelasticity have to be solved by assuming the existence of plane stress states in the self-stressed two-phase solids [11]... 

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