Solid/liquid separation membrane filtration

The solid-liquid separation of shinies containing particles below 10 pm is difficult by conventional filtration techniques. A conventional approach would be to use a slurry thickener in which the formation of a filter cake is restricted and the product is discharged continuously as concentrated slurry. Such filters use filter cloths as the filtration medium and are limited to concentrating particles above 5 xm in size. Dead end membrane microfiltration, in which the particle-containing fluid is pumped directly through a polymeric membrane, is used for the industrial clarification and sterilisation of liquids. Such process allows the removal of particles down to 0.1 xm or less, but is only suitable for feeds containing very low concentrations of particles as otherwise the membrane becomes too rapidly clogged.2,4,8... 

MF may be used to remove these heavy metals provided pretreatment chemicals are added to precipitate the metals to particles of filterable size. The chemical pretreatment step is crucial since it will affect the performance of the membrane and the resultant sludge volume as well as the contaminant removal efficiency. Reduction/oxidation, absorption/oxidation, and/or catalytic reactions are utilized along with pH adjustment to provide the optimum precipitation. Although conventional methods of waste water treatment may use a similar pretreatment chemistry, the final solid/liquid separation by gravity settling is usually not as effective as membrane filtration. 

Hollow-fibre membrane modules are similar to the capillary type described above, but with fibres of outside diameters ranging from 80 to 500 pm. It is usual to pack a hollow-fibre module with many hundreds or thousands of these fibres, thus membrane area per unit volume is extremely hi. It should be apparent that filtration using hollow-fibre modules is only realistic with process fluids prefiltered to prevent fibre blockage fins limits the technology and it is applied mainly in UF. Also used in uhrafiltration is a spiral-wound membrane module which is often compared to a Swiss roD. The membrane and a spacer are wound round a former, with an appropriate permeate spacer flow is introduced and removed from the ends. This module design is not appropriate for solid-liquid separation, even when filtering colloids, because of the possibility of flow channel blockage and so it will not be discussed any finther. 

Belfor G. Fluid mechanics and cross-flow membrane filtration. In Muralidhara HS, ed. Advanees in Solid Liquid Separation. Columbus Battelle Press, 1986, pp 182 183. 

Chemistry on soluble polymer matrices has recently emerged as a viable alternative to solid-phase organic synthesis (SPOS) involving insoluble cross-linked polymer supports. Separation of the functionalized matrix is achieved by solvent or heat precipitation, membrane filtration, or size-exclusion chromatography. Suitable soluble polymers for liquid phase synthesis should be crystalline at room temperature, with functional groups on terminal ends or side chains, but must not be not cross-linked they are therefore soluble in several organic solvents. 

This part, on applications, covers the following unit operations 8. Evaporation 9. Drying of Process Materials 10. Stage and Continuous Gas-Liquid Separation Processes (humidification, absorption) 11. Vapor-Liquid Separation Processes (distillation) 12. Liquid—Liquid and Fluid-Solid Separation Processes (adsorption, ion exchange, extraction, leaching, crystallization) 13. Membrane Separation Processes (dialysis, gas separation, reverse osmosis, ultrafiltration) 14. Mechanical-Physical Separation Processes (filtration, settling, centrifugal separation, mechanical size reduction). 

---