Solid for gas

A major point we emphasize is that, from a reaction engineering viewpoint, these are all essentially identical problems. The fluid may be a gas or a liquid, and the particle may be a liquid, gas, or a solid, but the geometries and the reactions are very similar. The interfaces may be gas-liquid, liquid-liquid, gas-soHd, or liquid-solid. For gas-Hquid problems we have drops and bubbles rather than particles, but the geometries are identical. These systems are the subject of Chapter 12. The applications are also quite different, but, once one realizes the similarities, the same ideas and equations unify all these problems. 

As we saw in Section 3.3, the concentration difference of one constituent of a gas or liquid solution at the surface of another phase is called adsorption. In other words, adsorption is the partitioning of a chemical species between a bulk phase and an interface. Desorption is the reverse of the adsorption process, showing that the molecules are leaving the interface towards the other phase. Adsorption is different from absorption where a species penetrates and is dissolved throughout the bulk phase of a liquid or a solid. For gas or liquid adsorption on solids, the solid material on which adsorption takes place is defined as the adsorbent the material in the adsorbed state (while bound to the solid surface) is called the adsorbate, and the gas, vapor or liquid molecule prior to being adsorbed is called the adsorptive. In this section, we will investigate only the principles and applications of gas adsorption on solids (see Section 9.4 for liquid adsorption on solids). 

What units do chemists normally use for density of liquids and solids For gas density Explain the difference ... 

Presents solubility data for gas-liquid, solid-solid, and liquid-liquid systems. 

Fixed-bed noncatalytic reactors. Fixed-bed reactors can be used to react a gas and a solid. For example, hydrogen sulfide can be removed from fuel gases by reaction with ferric oxide ... 

Fluidized bed noncatalytic reactors. Fluidized heds are also suited to gas-solid noncatalytic reactions. All the advantages described earlier for gas-solid catalytic reactions apply. As an example. 

The preceding definitions have been directed toward the treatment of the solid-liquid-gas contact angle. It is also quite possible to have a solid-liquid-liquid contact angle where two mutually immiscible liquids are involved. The same relationships apply, only now more care must be taken to specify the extent of mutual saturations. Thus for a solid and liquids A and B, Young s equation becomes... 

Various functional forms for / have been proposed either as a result of empirical observation or in terms of specific models. A particularly important example of the latter is that known as the Langmuir adsorption equation [2]. By analogy with the derivation for gas adsorption (see Section XVII-3), the Langmuir model assumes the surface to consist of adsorption sites, each having an area a. All adsorbed species interact only with a site and not with each other, and adsorption is thus limited to a monolayer. Related lattice models reduce to the Langmuir model under these assumptions [3,4]. In the case of adsorption from solution, however, it seems more plausible to consider an alternative phrasing of the model. Adsorption is still limited to a monolayer, but this layer is now regarded as an ideal two-dimensional solution of equal-size solute and solvent molecules of area a. Thus lateral interactions, absent in the site picture, cancel out in the ideal solution however, in the first version is a properly of the solid lattice, while in the second it is a properly of the adsorbed species. Both models attribute differences in adsorption behavior entirely to differences in adsorbate-solid interactions. Both present adsorption as a competition between solute and solvent. 

These concluding chapters deal with various aspects of a very important type of situation, namely, that in which some adsorbate species is distributed between a solid phase and a gaseous one. From the phenomenological point of view, one observes, on mechanically separating the solid and gas phases, that there is a certain distribution of the adsorbate between them. This may be expressed, for example, as ria, the moles adsorbed per gram of solid versus the pressure P. The distribution, in general, is temperature dependent, so the complete empirical description would be in terms of an adsorption function ria = f(P, T). 

The characterization of surfaces undergoing corrosion phenomena at liquid-solid and gas-solid interfaces remains a challenging task. The use of STM for in situ studies of corrosion reactions will continue to shape the atomic-level understanding of such surface reactions. 

Figure Bl.26.3. The lUPAC classification of adsorption isothemis for gas-solid equilibria (Sing K S W, Everett D H, Haul RAW, Mosoul L, Pierotti R A, Rouguerol J and Siemieiiiewska T 1985 Pure. Appl. Chem. 57 603-19).

To prepare the solid phenyldlazonlum chloride or sulphate, the reaction is conducted in the absence of water as far as possible. Thus the source of nitrous acid is one of its organic esters (e.g., amyl nitrite) and a solution of hydrogen chloride gas in absolute alcohol upon the addition of ether only the diazonium salt is precipitated as a crystalline solid, for example ... 

One way to model a solid is to use software designed for gas-phase molecular computations. A large enough piece of the solid can be modeled so that the region in the center for practical purposes describes the region at the center of an inhnite crystal. This is called a cluster calculation. 

A manual entitled Reporting Physisorption Data for Gas/Solid Systems with Special Reference to the Determination of Surface Area and Porosity has been prepared as a provisional publication by Commission 1.6 of the International Union of Pure and Applied Chemistry (lUPAC). The purpose of the manual is to draw attention to problems involved in reporting physisorption data and to provide guidance on the evaluation and interpretation of isotherm data. The general conclusions and recommendations are very similar to those contained in Chapter 6. 

Since an analyte and interferent are usually in the same phase, a separation often can be effected by inducing a change in one of their physical or chemical states. Changes in physical state that have been exploited for the purpose of a separation include liquid-to-gas and solid-to-gas phase transitions. Changes in chemical state involve one or more chemical reactions. 

Phofoelectron spectroscopy is a simple extension of the photoelectric effect involving the use of higher-energy incident photons and applied to the study not only of solid surfaces but also of samples in the gas phase. Equations (8.1) and (8.2) still apply buf, for gas-phase measuremenfs in particular, fhe work function is usually replaced by fhe ionization energy l so fhaf Equation (8.2) becomes... 

Density and Specific Gravity For binary or pseudobinary mixtures of hquids or gases or a solution of a solid or gas in a solvent, the density is a funcrion of the composition at a given temperature and pressure. Specific gravity is the ratio of the density of a noncompress-ible substance to the density of water at the same physical conditions. For nonideal solutions, empirical calibration will give the relationship between density and composition. Several types of measuring devices are described below. 

Segmental and eccentric orifices are frequently used for gas metering when there is a possibility that entrained liqiiids or solids would otherwise accumulate in front of a concentric circular orifice. This can be avoided if the opening is placed on the lower side of the pipe. For hquid flow with entrained gas, the opening is placed on the upper side. The pressure taps should be located on the opposite side of the pipe from the opening. 

Gas-Solid Mixtures Carlson, Frazier, and Engdahl [Trans. Am. Soc. Mech. Eng., 70, 65-79 (1948)] describe the use of a flow nozzle and a square-edged orifice in series for the measurement of both the gas rate and the solids rate in the flow of a finely divided solid-in-gas mixture. The nozzle differential is sensitive to the flow of both phases, whereas the orifice differential is not influenced by the sohds flow. 

Special designs of direct rotaiy dryers, such as the Renneburg DehydrO-Mat (Edward Renneburg Sons Co.), are constructed especially to provide lower retention during the falling-rate diy-ing period for the escape of internal moisture from the solids. The DehydrO-Mat is a cocurrent diyer employing a smaU-diameter shell at the feed end, where rapid evaporation of surface moisture in the stream of initially hot gas is accomplished with low holdup. At the solids- and gas-exit end, the shell diameter is increased to reduce gas velocities and provide increased holdup for the solids while they are exposed to the partially cooled gas stream. 

For proper use of the equations, the chamber shape must conform to the spray pattern. With cocurrent gas-spray flow, the angle of spread of single-fluid pressure nozzles and two-fluid pneumatic nozzles is such that wall impingement wiU occur at a distance approximately four chamber diameters below the nozzle therefore, chambers employing these atomizers should have vertical height-to-diameter ratios of at least 4 and, more usually, 5. The discharge cone below the vertical portion should have a slope of at least 60°, to minimize settling accumulations, and is used entirely to accelerate gas and solids for entty into the exit duct. 

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