SODIUM CELLULOSATE

The resultant yellow sodium cellulose xanthate is dispersed in an aqueous caustic soda solution, where some hydrolysis occurs. This process is referred to as ripening and the solution as viscose . When the hydrolysis has proceeded sufficiently the solution it transferred to a hopper from which it emerges through a small slit on to a roller immersed in a tank of 10-15% sulphuric acid and 10-20% sodium sulphate at 35-40°C. The viscose is coagulated and by completion of the hydrolysis the cellulose is regenerated. The foil is subsequently washed, bleached, plasticised with ethylene glycol or glycerol and then dried. 

When ethanol is replaced by cellulose, sodium cellulose xanthate is obtained this dissolves in aqueous alkali to give a viscous solution (viscose) from which either viscose rayon or cellophane can be obtained by adding acid to regenerate the (reconstituted) cellulose. Trithiocarbonates (CS3 "), dithiocarbonates (COS2 "), xanthates (CS2OR ), difhiocarbamates (CS2NR2 ) and 1,2-dithiolates have an extensive coordination chemistry which has been reviewed. ... 

Sodium carboxymethyl cellulose (SS) Sodium cellulose sulfate (SS)... 

Polymer Media Alginate (Sodium) Cellulose Sulfate Carboxy- methyl Cellulose Xanthan Carrageenan (A) Gellan Gum Poly Glutamic Acid... 

Geometric effects coupled with diffusion and nucleation usually control the rates of all solids deposition phenomena. Such effects can be put to good use in the production of special products such as cellulose yarn (rayon), by the precipitation of cellulose in filament form as it emerges as sodium cellulose xanthate liquid from the spinnerets into a bath containing sulphuric acid, which extracts the sodium as sodium sulphate, and the carbon disulphide. In a similar manner, the fabrication of aromatic polyimide fibres is performed by dissolving the polymer in concentrated sulphuric acid and forcing the solution through spinnerets into water. 

Schwenkkr, R. F., and E. Pacsu Graft polymerization onto cellulose reactions of sodium cellulosate and alkali cellulose with vinyl monomers. Tappi 46, 665 (1963). 

CMC. Designation for Carboxymethy I-cellulose. Sodium Salt, known also as Sodium Cellulose Glycolate,... 

Methyl cellulose Ethyl cellulose Hydroxyethyl cellulose Hydroxypropyl cellulose Hydroxyethylmethyl cellulose Hydroxypropylmethyl cellulose Carboxymethyl cellulose sodium Cellulose acetate Cellulose acetate butyrate Cellulose acetate propionate Cellulose acetate phthalate Hydroxypropylmethyl cellulose phthalate... 

Cellulose xanthate, or more exactly, sodium cellulose xanthate or sodium cellulose dithiocar-bonate, is obtained by mixing the aged soda cellulose with carbon disulfide in a vapor-tight xanthating chum. Based upon weight of cellulose, the amount of carbon disulfide used will be in the range of 30 percent for regular rayon to 50-60 percent for modified varieties. 

Wu8) analyzed the distribution of substituted glucopyranose units in cellulose nitrate (CN) by H- and l3C-NMR methods. The values of sodium cellulose sulfate (NaCS)9), and sodium carboxymethylcellulose (NaCMQ 10) were determined using 13C-NMR by Kamide et al. 

FINE GUM HES GLIKOCEL TA KMTS 212 LOVOSA LUCEL (polysaccharide) MAJOLPLX MODOCOLL 1200 NACM-CELLULOSE SALT NYMCEL S POLYFIBRON 120 SANLOSE SN 20A SARCELL TEL S 75M SODIUM CELLULOSE GLYCOLATE SODIUM CMC SODIUM CM-CELLULOSE SODIUM SALT of CARBOXYMETHYL-CELLULOSE TYLOSE 666 UNISOL RH... 

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