Sizing blocked discharge

A vessel may be subject to more than one condition under different failure scenarios. For example, a low pressure separator may be subject to blocked discharge, gas blowby from the high pressure separator, and fire. Only one of these failures is assumed to happen at any time. The relief valve size needs to be calculated for each pertinent relieving rate... 

A vessel can only be overpressured if the upstream vessel has a higher pressure than the vessel in question. A compressor scrubber with a MAWP of 285 that gets flow from a 285 MAWP separator does not need to have a relief valve sized for blocked discharge. The upstream relief valve will keep the upstream separator pressure from going higher than 285, so there is no way it can oveipressure the downstream scrubber. The scrubber PSV only needs to be sized for fire. 

Relief valves are often seen to be undersized for the required relieving rate, due either to poor initial design or changes in the process conditions which occurred during design. The most common system problem is that the relief valve was adequately sized for blocked discharge but not sized for the flowrate that could occur as a result of a failure in the open position of an upstream control valve (i.e., gas blowby). See Chapter 13. 

The material balance is presented on a block flow sheet so that the reader can graphically visualize what is happening. An example is given in Figure 4E- 1. Each major operation appears as a block. No attempt is made to identify the specific pieces of equipment or to size them. The blocks are interconnected with flow lines, which indicate for each substance where it enters the process, what path it follows, and where it is eventually discharged. These flow lines are keyed to a chart that gives the composition and amount of each stream in the form of a unit ratio material balance. A material balance should be given for each product made by a multipurpose plant. 

For application in flow reactors the nanocarbons need to be immobilized to ensure ideal flow conditions and to prevent material discharge. Similar to activated carbon, the material can be pelletized or extruded into millimeter-sized mechanically stable and abrasion-resistant particles. Such a material based on CNTs or CNFs is already commercially available [17]. Adversely, besides a substantial loss of macroporosity, the use of an (organic) binder is often required. This material inevitably leaves an amorphous carbon overlayer on the outer nanocarbon surface after calcination, which can block the intended nanocarbon surface properties from being fully exploited. Here, the more elegant strategy is the growth of nanocarbon structures on a mechanically stable porous support such as carbon felt [15] or directly within the channels of a microreactor [14,18] (Fig. 15.3(a),(b)), which could find application in the continuous production of fine chemicals. Pre-shaped bodies and surfaces can be... 

Next, it will be valuable to consider the discharge behavior when the electrodes are not of equal size. A simplified analysis of this situation can be made15 if we make a number of approximations. Consider a geometry such as shown in Figure 6, where a blocking capacitor is used between the power supply and electrode 1. The function of the blocking capacitor is to allow a DC bias to exist between the DC plasma potential and the electrode adjacent to the capacitor. 

Relief devices Emergencies Process isolation Instruments Adequacy, vent size, discharge, drain and support Dump, drown, inhibit and dilute Block valves, fire-valves and purging Air quality, time lag, reset wind-up and materials of construction... 

The screening action depends not only on the size of the substituted ammonium ion, but also on the characteristics of the discharging particle. For example, if, in the case of Cr04 discharge, the blocking of the surface with the (nBu)4N ion is pronounced, hydrogen evolution in the barrierless dis-... 

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