Shielding, uranium

Nuclear Applications. Powder metallurgy is used in the fabrication of fuel elements as well as control, shielding, moderator, and other components of nuclear-power reactors (63) (see Nuclearreactors). The materials for fuel, moderator, and control parts of a reactor are thermodynamically unstable if heated to melting temperatures. These same materials are stable under P/M process conditions. It is possible, for example, to incorporate uranium or ceramic compounds in a metallic matrix, or to produce parts that are similar in the size and shape desired without effecting drastic changes in either the stmcture or surface conditions. OnlyHttle post-sintering treatment is necessary. 

The isotope molybdenum-99 is produced in large quantity as the precursor to technetium-99y, a radionucleide used in numerous medical imaging procedures such as those of bone and the heart (see Medical imaging technology). The molybdenum-99 is either recovered from the fission of uranium or made from lighter Mo isotopes by neutron capture. Typically, a Mo-99 cow consists of MoO adsorbed on a lead-shielded alumina column. The TcO formed upon the decay of Mo-99 by P-decay, = 66 h, has less affinity for the column and is eluted or milked and either used directly or appropriately chemically derivatized for the particular diagnostic test (100). 

A number of pool, also called swimming pool, reactors have been built at educational institutions and research laboratories. The core in these reactors is located at the bottom of a large pool of water, 6 m deep, suspended from a bridge. The water serves as moderator, coolant, and shield. An example is the Lord nuclear reactor at the University of Michigan, started in 1957. The core is composed of fuel elements, each having 18 aluminum-clad plates of 20% enriched uranium. It operates at 2 MW, giving a thermal flux of 3 x 10 (cm -s). The reactor operates almost continuously, using a variety of beam tubes, for research purposes. 

Uranium is the fourth element of the actinide (SJ series. In the actinide series the electrons are more effectively shielded by the Is and 7p electrons relative to the 4f electrons (shielded by 6s, 6p) in the lanthanide (4p series. Thus, there is a greater spatial extension of 5f orbitals for actinides than 4f orbitals for lanthanides. This results in a small energy difference between and 5/ 6d7s electronic configurations, and a wider range of oxidation states is... 

CP-1 was assembled in an approximately spherical shape with the purest graphite in the center. About 6 tons of luanium metal fuel was used, in addition to approximately 40.5 tons of uranium oxide fuel. The lowest point of the reactor rested on the floor and the periphery was supported on a wooden structure. The whole pile was surrounded by a tent of mbberized balloon fabric so that neutron absorbing air could be evacuated. About 75 layers of 10.48-cm (4.125-in.) graphite bricks would have been required to complete the 790-cm diameter sphere. However, criticality was achieved at layer 56 without the need to evacuate the air, and assembly was discontinued at layer 57. The core then had an ellipsoidal cross section, with a polar radius of 209 cm and an equatorial radius of309 cm [20]. CP-1 was operated at low power (0.5 W) for several days. Fortuitously, it was found that the nuclear chain reaction could be controlled with cadmium strips which were inserted into the reactor to absorb neutrons and hence reduce the value of k to considerably less than 1. The pile was then disassembled and rebuilt at what is now the site of Argonne National Laboratory, U.S.A, with a concrete biological shield. Designated CP-2, the pile eventually reached a power level of 100 kW [22]. 

The McArthur River Uranium Deposit lies in the eastern portion of the Athabasca Basin and within the Churchill Structural Province of the Canadian Shield. The deposit straddles the unconformity between the quartz arenite - rich Late Paleoproterozoic Athabasca Group and... 

The U.S. Department of Energy (DOE) found the cost to dispose of depleted uranium hexafluoride ranged from 4 to 12 billion. As an alternative to disposal, INEEL developed a concept of converting depleted uranium into an oxide aggregate material for use in cement. This cement material is known as Ducrete cement and is used as a shielding material (D202937, p. 1). 

Depleted uranium (DU) is used to reinforce armor shielding and increase penetrability of military munitions. Although the data are conflicting, DU has been invoked as a potential etiological factor in Gulf War syndrome.70 To control possible contamination of soldiers from the Gulf War... 

Unenriched uranium—which contains more than 99 percent of the nonfissionable isotope U-238—undergoes a chain reaction only if it is mixed with a moderator to slow down the neutrons. Uranium in ore is mixed with other substances that impede the reaction and has no moderator to slow down the neutrons, so no chain reaction occurs. 75- Nuclear fission is a poor prospect for powering automobiles primarily because of the massive shielding that would be required to protect the occupants and others from the radioactivity and the problem of radioactive waste disposal. 

Caution. The reaction of uranium metal with concentrated HN03 is exothermic, is accompanied by the liberation of toxic N02 gas, and should only be carried out in a well-ventilated hood. The nitric acid for this step must be concentrated. Acid-resistant gloves and a face shield are highly recommended safety additions. 

Experimental Methods of Investigation. All of the aclinide elements are radioactive and, except for thorium and uranium, special equipment and shielded facilities are usually necessary for their manipulation. 

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