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Shell Higher Olefin Process alkene metathesis

Alkenes. At present alkene isomerization is an important step in the production of detergent alkylates (Shell higher olefin process see Sections 12.3 and 13.1.3).264 265 Ethylene oligomerization in the presence of a nickel(O) catalyst yields terminal olefins with a broad distribution range. C4-C6 and C2o+ alkenes, which are not suitable for direct alkylate production, are isomerized and subsequently undergo metathesis. Isomerization is presumably carried out over a MgO catalyst. [Pg.193]

The alkene metathesis reaction see Alkene Metathesis) exchanges alkylidene groups between different alkenes, and is catalyzed by a variety of high oxidation state, early transition metal species (equation 40). The reaction is of interest because it is the strongest bond in the alkene, the C=C bond, that is broken during the reaction. It is also commercially important in the Shell higher olefins process and in the polymerization of cycloalkenes. It is relevant to this article because carbenes are the key intermediates, and the best-known catalyst, (1), is a carbene complex. [Pg.5760]

It is still unclear how the initiation step in alkene metathesis occurs and how the initial carbene forms. Commercial applications of metathesis include the triolefin process, in which propylene is converted to ethylene and butene, the neohexene process, in which the dimer of isobutylene, Me3CCH=CMe2, is metathesized with ethylene to give Me3CCH=CH2, an intermediate in the manufacture of synthetic musk, and a 1,5-hexadiene synthesis from 1,5-cy-clooctadiene and ethylene. Two other applications, SHOP and ROMP (Shell higher olefins process and ring-opening metathesis polymerization), are discussed in the next section. [Pg.294]

In the Shell Higher Olefins Process (SHOP) a much more efficient catalyst based on transition metal compounds (probably nickel) is used to effect the oligomerization. Initially about 30% of the ethene is converted into the desired olefins. The remainder (C -Cj and above are isomerized to internal alkenes and then converted into more useful fractions by metathesis. [Pg.81]

Phosphine-modified cobalt hydroformylation is only used commercially by Shell. It is tightly coupled to Shell s Higher Olefins Process (SHOP, see Metathesis Polymerization Processes by Homogeneous Catalysis) that produces a C4 through C20 mixture of linear, internal alkenes for hydroformylation to detergent-grade alcohols. [Pg.663]


See other pages where Shell Higher Olefin Process alkene metathesis is mentioned: [Pg.123]    [Pg.182]    [Pg.338]    [Pg.137]    [Pg.497]    [Pg.733]    [Pg.1243]    [Pg.2682]    [Pg.1117]    [Pg.2681]    [Pg.400]    [Pg.755]    [Pg.1016]    [Pg.298]    [Pg.755]    [Pg.107]    [Pg.120]    [Pg.357]    [Pg.339]   
See also in sourсe #XX -- [ Pg.1117 ]

See also in sourсe #XX -- [ Pg.5 ]

See also in sourсe #XX -- [ Pg.1117 ]

See also in sourсe #XX -- [ Pg.5 ]




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Alkene metathesis

Alkenes Shell higher olefins process

Higher Shell process

Higher alkenes

Higher metathesis

Higher olefins

Metathesis Shell higher olefin process

Olefin metathesis

Olefine metathesis

Shell process

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